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Dimethylphenylsilane

CAS No.
766-77-8
Chemical Name:
Dimethylphenylsilane
Synonyms
ACETATE BUFFER;BUFFER SOLUTION;SODIUM ACETATE BUFFER;PHENYLDIMETHYLSILANE;BUFFER PH7.20;BUFFER PH 4.65;DK894;DK391;FEMA 3900;BUFFER ACETATE
CBNumber:
CB2854276
Molecular Formula:
C8H12Si
Molecular Weight:
136.27
MDL Number:
MFCD00008257
MOL File:
766-77-8.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Dimethylphenylsilane Properties

Melting point 323-329 °C(lit.)
Boiling point 157 °C744 mm Hg(lit.)
Density 0.889 g/mL at 25 °C(lit.)
refractive index n20/D 1.497(lit.)
Flash point 95 °F
storage temp. Inert atmosphere,2-8°C
solubility sol common organic solvent such as chloroform, 1,2- dichloroethane, benzene, ether, acetone, dioxane, THF; insol H2O.
form solid
color Colorless to Almost colorless
Specific Gravity 0.889
Water Solubility Not miscible in water.
Hydrolytic Sensitivity 3: reacts with aqueous base
BRN 2204906
InChIKey ZISUALSZTAEPJH-UHFFFAOYSA-N
CAS DataBase Reference 766-77-8(CAS DataBase Reference)
EPA Substance Registry System Silane, dimethylphenyl- (766-77-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  Xi
Risk Statements  10-36
Safety Statements  26-36/39-24/25
RIDADR  UN 1993 3/PG 3
WGK Germany  1
RTECS  AJ4375000
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29319090
NFPA 704
3
1 0

Dimethylphenylsilane price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 235016 Dimethylphenylsilane ≥98% 766-77-8 5g $46.8 2024-03-01 Buy
Sigma-Aldrich 235016 Dimethylphenylsilane ≥98% 766-77-8 25g $129 2024-03-01 Buy
TCI Chemical D2196 Dimethylphenylsilane >97.0%(GC) 766-77-8 5mL $38 2024-03-01 Buy
TCI Chemical D2196 Dimethylphenylsilane >97.0%(GC) 766-77-8 25mL $128 2024-03-01 Buy
Alfa Aesar L04558 Dimethylphenylsilane, 97% 766-77-8 10g $53.8 2024-03-01 Buy
Product number Packaging Price Buy
235016 5g $46.8 Buy
235016 25g $129 Buy
D2196 5mL $38 Buy
D2196 25mL $128 Buy
L04558 10g $53.8 Buy

Dimethylphenylsilane Chemical Properties,Uses,Production

Chemical Properties

Clear colorless liquid

Physical properties

bp 157 °C/744 mmHg; d 0.889 g cm?3.

Uses

Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan.

Uses

Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the hydrosilane adds to carbon–carbon double or triple bonds to give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid or F?).

Application

Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines.

Global( 187)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd
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Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58

View Lastest Price from Dimethylphenylsilane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dimethylphenylsilane pictures 2022-10-01 Dimethylphenylsilane
766-77-8
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
Dimethylphenylsilane pictures 2020-01-01 Dimethylphenylsilane
766-77-8
US $7.00 / KG 1KG 99% 100KG Career Henan Chemical Co
SODIUM ACETATE ACETIC ACID SODIUM ACETATE ACETIC ACID BUFFER ACETATE BUFFER SOLUTION TYPE 'C' ACETATE BUFFER TS ACETATE BUFFER SOLUTION R-455 FEMA 3900 DIMETHYLPHENYLSILANE BUFFER SOLUTION, PH 4.63 BUFFER SOLUTION, PH 4.0, ACETATE BUFFER, PH 4.63 BUFFER SOLUTION (ACETATE), PH 4.0-4.5 BUFFER SOLUTION (ACETATE), PH 4.00 BUFFER ACETATE BUFFER ACETATE, PH 4.00 DIMETHYLPHENYLSILANE, 98+% Dimethylphenylsilane,97% dimethylphenyl-silan (Dimethylsilyl)benzene ACETATE BUFFER REAGENT ACETATE BUFFER, PH 6.0 ACETATE BUFFER, PH 3.5 ACETATE BUFFER, PH 4.0 ACETATE BUFFER, PH 4.5 ACETIC ACID - SODIUM ACETATE Dimethylphenylsilane> Benzene, (dimethylsilyl)- SODIUM ACETATE BUFFER PHENYLDIMETHYLSILANE BUFFER PH7.20 BUFFER PH 4.65 BUFFER SOLUTION ACETATE BUFFER DK894 DK391 766-77-8 76-77-8 768-77-8 C6H5SiHCH32 C8H11Si Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Reduction Si-H Compounds Organosilicon Others Molecular Biology Molecular Biology Reagents Organometallic Reagents Organic Building Blocks Alphabetic Analytical Chromatography Product Catalog Alkenes Acyclic BioChemical Building Blocks Analytical Standards Reduction Si (Classes of Silicon Compounds)