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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

Reaction
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) structure
CAS No.
132071-87-5
Chemical Name:
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms
Dichloro [(R);-2,2'-bis(diphenylphosphino);-1,1'-binaphathyl] ruthenium(II);Dichlorobisdiphenylphosphinobinaphthylruthenium;(R)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororutheniuM;(R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 95%;Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ);[(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride;[(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride;DICHLORO[(S)-(-)-,2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
CBNumber:
CB3114506
Molecular Formula:
C44H32Cl2P2Ru
Formula Weight:
794.65
MOL File:
132071-87-5.mol

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Properties

Melting point:
>300 ºC
form 
Powder
color 
orange
Sensitive 
air sensitive
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36/37
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B3067 [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride 132071-87-5 250mg $286 2018-11-22 Buy
Strem Chemicals 44-0248 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 132071-87-5 100mg $68 2018-11-13 Buy
Strem Chemicals 44-0248 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 132071-87-5 500mg $154 2018-11-13 Buy
Strem Chemicals 44-0248 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 132071-87-5 2g $462 2018-11-13 Buy

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Uses,Production

Reaction

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products


DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Suppliers

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132071-87-5(DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II))Related Search:

Dichloro(p-cymene)ruthenium(II) dimer [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II),DICHLORO[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER,DICHLORO[(S)-(-)-,2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II),DICHLORO[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER,Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),min.95%,Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% DICHLORO[RAC-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'BINAPHTYL](P-CYMENE)RUTHENIUM(II) CHLORIDE DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R,R)-1,2-DIPHENYLETHANE DIAMINE]RUTHENIUM(II)

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