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Nickel(II) nitrate hexahydrate

Description Preparation References
Nickel(II) nitrate hexahydrate
Nickel(II) nitrate hexahydrate
CAS No.
13478-00-7
Chemical Name:
Nickel(II) nitrate hexahydrate
Synonyms
NICKEL NITRATE;NickelNitrateAr;NICKEL(II) NITRATE;Nickel Nitrate (Ous);NICKEL (OUS) NITRATE;NICKEL NITRATE, HYDROUS;NICKEL(II) NITRATE 6 H2O;NICKEL NITRATE-6-HYDRATE;nickeldinitratehexahydrate;NICKEL NITRATE HEXAHYDRATE
CBNumber:
CB3115275
Molecular Formula:
H12N2NiO12
Formula Weight:
290.79
MOL File:
13478-00-7.mol

Nickel(II) nitrate hexahydrate Properties

Melting point:
56 °C(lit.)
Boiling point:
137 °C
Density 
2.05 g/mL at 25 °C(lit.)
Flash point:
137°C
storage temp. 
Store at +5°C to +30°C.
solubility 
940g/l
form 
flakes
color 
Green to blue
Specific Gravity
2.05
PH
5 (50g/l, H2O, 20℃)
Water Solubility 
238.5 g/100 mL (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,6513
Stability:
Stable. Strong oxidizer. Incompatible with reducing agents.
CAS DataBase Reference
13478-00-7(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  O,T,Xi,Xn,N
Risk Statements  45-8-22-43-40-68-50/53-48/23-42/43-41-38-20/22-61-49
Safety Statements  53-17-36/37-45-61-60
RIDADR  UN 2725 5.1/PG 3
WGK Germany  3
RTECS  QR7300000
TSCA  Yes
HS Code  2834 29 20
HazardClass  5.1
PackingGroup  III
Toxicity LD50 orally in Rabbit: 1620 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
P210, P220, P221P280, P370+P378,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P221 Take any precaution to avoid mixing with combustibles/…
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Nickel(II) nitrate hexahydrate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 203874 Nickel(II) nitrate hexahydrate 99.999% trace metals basis 13478-00-7 20g $52.3 2018-11-13 Buy
Sigma-Aldrich 203874 Nickel(II) nitrate hexahydrate 99.999% trace metals basis 13478-00-7 100g $174 2018-11-13 Buy
Alfa Aesar 010816 Nickel(II) nitrate hexahydrate, Puratronic?, 99.9985% (metals basis) 13478-00-7 5g $49.2 2018-11-16 Buy
Alfa Aesar 010816 Nickel(II) nitrate hexahydrate, Puratronic?, 99.9985% (metals basis) 13478-00-7 50g $70.7 2018-11-16 Buy
Strem Chemicals 28-1440 Nickel(II) nitrate hexahydrate (99.9985%-Ni) PURATREM 13478-00-7 100g $114 2018-11-13 Buy

Nickel(II) nitrate hexahydrate Chemical Properties,Uses,Production

Description

Nickel (II) nitrate hexahydrate is the hexahydrate form of the nickel (II) nitrate. Nickel nitrate (chemical formula: Ni(NO3)2) is manufactured by the reaction of nickel oxide with nitric acid. The nickel (II) nitrate hexahydrate can be used as a precursor during the manufacturing of other nickel salts and supported nickel catalysts. For example, it is the precursor for the manufacturing of nickel sulfide-reduced graphene oxide (RGO) composite powders. It can also be used for the manufacturing of nickel and nickel oxide nanocrystals impregnated O-MWCNTs which is useful in semiconductor industries. Moreover, it can also be used in electroplating and as a mordent in textile dyeing. Finally, it can be used to improve the cycling stability and rate capability o Li2MnO2.

Preparation

Nickel nitrate hexahydrate may be prepared by several methods based on the reaction of dilute nitric acid on nickel powder, nickel oxide or nickel carbonate. The reaction is exothermic and requires controlled cooling during production. The hexahydrate can be dehydrated to anhydrous salt by treatment with fuming nitric acid.

References

https://www.alfa.com/en/catalog/A15540/
https://en.wikipedia.org/wiki/Nickel(II)_nitrate

Description

Nickel (II) nitrate hexahydrate appears as green crystals and substantially soluble in water. It is stable, a strong oxidiser, and incompatible with reducing agents. It has wide industrial applications in nickel plating as catalysts and is indirectly associated with other industries of nickel alloy manufacturers, nickel miners, smelters and refiners, nickel platers, and exposure to alloys, for example, in coinage.

Chemical Properties

Green crystal

Safety Profile

Confirmed carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also NICKEL(II) NITRATE.

Purification Methods

Crystallise it from water (3.3g/mL) by partial evaporation in a desiccator. Store it in a desiccator as it is deliquescent.

Nickel(II) nitrate hexahydrate Preparation Products And Raw materials

Raw materials

Preparation Products


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Nickel(II) nitrate hexahydrate Spectrum


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