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Nickel(II) nitrate hexahydrate

CAS No.
13478-00-7
Chemical Name:
Nickel(II) nitrate hexahydrate
Synonyms
NICKEL NITRATE;NICKEL NITRATE HEXAHYDRATE;NICKEL(II) NITRATE;Nitric acid nickel(II) salt hexahydrate;Nickel (II) nitrate hexahydrate≥ 97% (Titration);NickelNitrateAr;Nickelousnitrate,N;Nickel Nitrate (Ous);NICKEL (OUS) NITRATE;NICKEL NITRATE, HYDROUS
CBNumber:
CB3115275
Molecular Formula:
H12N2NiO12
Molecular Weight:
290.79
MDL Number:
MFCD00149805
MOL File:
13478-00-7.mol
MSDS File:
SDS
Last updated:2024-03-28 16:55:20

Nickel(II) nitrate hexahydrate Properties

Melting point 56 °C(lit.)
Boiling point 137 °C
Density 2.05 g/mL at 25 °C(lit.)
Flash point 137°C
storage temp. Store at +5°C to +30°C.
solubility 940g/l
form flakes
color Green to blue
Specific Gravity 2.05
PH 5 (50g/l, H2O, 20℃)
Water Solubility 238.5 g/100 mL (20 ºC)
Sensitive Hygroscopic
Merck 14,6513
Exposure limits ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability Stable. Strong oxidizer. Incompatible with reducing agents.
InChIKey AOPCKOPZYFFEDA-UHFFFAOYSA-N
CAS DataBase Reference 13478-00-7(CAS DataBase Reference)
FDA UNII XBT61WLT1J

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS03,GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H272-H302+H332-H315-H317-H318-H334-H341-H350-H360-H372-H410
Precautionary statements  P201-P210-P273-P280-P305+P351+P338+P310-P308+P313
Hazard Codes  O,T,Xi,Xn,N
Risk Statements  45-8-22-43-40-68-50/53-48/23-42/43-41-38-20/22-61-49
Safety Statements  53-17-36/37-45-61-60
RIDADR  UN 2725 5.1/PG 3
WGK Germany  3
RTECS  QR7300000
TSCA  Yes
HS Code  2834 29 20
HazardClass  5.1
PackingGroup  III
Toxicity LD50 orally in Rabbit: 1620 mg/kg
NFPA 704
0
1 0

Nickel(II) nitrate hexahydrate price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 203874 Nickel(II) nitrate hexahydrate 99.999% trace metals basis 13478-00-7 20g $66.7 2024-03-01 Buy
Sigma-Aldrich 203874 Nickel(II) nitrate hexahydrate 99.999% trace metals basis 13478-00-7 100g $222 2024-03-01 Buy
Sigma-Aldrich 1.06721 Nickel(II) nitrate hexahydrate for analysis EMSURE? ACS 13478-00-7 100g $84.3 2024-03-01 Buy
Sigma-Aldrich 1.06721 Nickel(II) nitrate hexahydrate for analysis EMSURE? ACS 13478-00-7 250g $112 2024-03-01 Buy
Sigma-Aldrich 1.06721 Nickel(II) nitrate hexahydrate for analysis EMSURE? ACS 13478-00-7 1kg $281 2024-03-01 Buy
Product number Packaging Price Buy
203874 20g $66.7 Buy
203874 100g $222 Buy
1.06721 100g $84.3 Buy
1.06721 250g $112 Buy
1.06721 1kg $281 Buy

Nickel(II) nitrate hexahydrate Chemical Properties,Uses,Production

Description

Nickel (II) nitrate hexahydrate is the hexahydrate form of the nickel (II) nitrate. Nickel nitrate (chemical formula: Ni(NO3)2) is manufactured by the reaction of nickel oxide with nitric acid. The nickel (II) nitrate hexahydrate can be used as a precursor during the manufacturing of other nickel salts and supported nickel catalysts. For example, it is the precursor for the manufacturing of nickel sulfide-reduced graphene oxide (RGO) composite powders. It can also be used for the manufacturing of nickel and nickel oxide nanocrystals impregnated O-MWCNTs which is useful in semiconductor industries. Moreover, it can also be used in electroplating and as a mordent in textile dyeing. Finally, it can be used to improve the cycling stability and rate capability o Li2MnO2.

Preparation

Nickel nitrate hexahydrate may be prepared by several methods based on the reaction of dilute nitric acid on nickel powder, nickel oxide or nickel carbonate. The reaction is exothermic and requires controlled cooling during production. The hexahydrate can be dehydrated to anhydrous salt by treatment with fuming nitric acid.

References

https://www.alfa.com/en/catalog/A15540/
https://en.wikipedia.org/wiki/Nickel(II)_nitrate

Description

Nickel (II) nitrate hexahydrate appears as green crystals and substantially soluble in water. It is stable, a strong oxidiser, and incompatible with reducing agents. It has wide industrial applications in nickel plating as catalysts and is indirectly associated with other industries of nickel alloy manufacturers, nickel miners, smelters and refiners, nickel platers, and exposure to alloys, for example, in coinage.

Chemical Properties

Green crystal

Uses

Nickel(II) nitrate hexahydrate may be used as a precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders, Ni(II) oxide aerogels and crystalline nickel complexes, [Ni(C6H7N3O)2(NO3)2] and [Ni(C6H7N3O)3](NO3)2·H2O.

Uses

Nickel plating, manufacturing of ceramic colorsNickel(II) nitrate hexahydrate is used as a precursor in the manufacturing of other nickel salts and supported nickel catalysts. It finds use as a catalyst in organic synthesis. Further it is used in electroplating and as a mordent in textile dyeing. It is a precursor for preparing nickel sulfide-reduced graphene oxide (RGO) composite powders with high initial capacities and good cycling performance. It can be employed in the preparation of nickel and nickel oxide nanocrystals impregnated O-MWCNTs (oxygen-functionalized multi-walled carbon nanotubes) with potential applications in semiconductor industries. It finds use in improving cycling stability ad rate capability of Li2MnO3.

Preparation

Emerald green crystals of the hexahydrate Ni(N03)2?6H20 crystallize from aqueous solutions at room temperature. These are isomorphous with the corresponding cobalt(II) salt containing the regular octahedral [Ni(H20)6]2+ ions with Ni-O distances = 2.03 A. The tetrahydrate crystallize above 54° and the dihydrate above 85.4°. The pale green anhydrous nitrate can be obtained by dehydration of the hydrate with dinitrogen pentoxide in fuming nitric acid or by the liquid phase reaction of dinitrogen tetroxide with nickel carbonyl [the gas phase reaction gives the nitrite Ni(N02)2]
Ni(CO)4+2N2O4 -* Ni(N03)2+2NO+4CO
The first product of this latter rather violent reaction is the adduct Ni(NO3)2N2O4 from which the nitrogen tetroxide is removed by heating in vacuo. It can also be prepared by the reaction of dinitrogen tetroxide-ethyl acetate mixtures with nickel(II) chloride. The infrared spectrum shows it to be a typical covalent nitrate. It is involatile and decomposes upon heating in nitrogen to give the nitrite Ni(NO2)2 above 260°.

General Description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.

Safety Profile

Confirmed carcinogen. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also NICKEL(II) NITRATE.

Purification Methods

Crystallise it from water (3.3g/mL) by partial evaporation in a desiccator. Store it in a desiccator as it is deliquescent.

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View Lastest Price from Nickel(II) nitrate hexahydrate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Nickel(II) nitrate hexahydrate pictures 2024-03-28 Nickel(II) nitrate hexahydrate
13478-00-7
US $5.00-0.10 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Nickel(II) nitrate hexahydrate pictures 2023-08-31 Nickel(II) nitrate hexahydrate
13478-00-7
US $100.00 / bag 1bag 99 5000 Hebei Fengqiang Trading Co., LTD
Nickel Nitrate Hexahydrate  pictures 2023-01-31 Nickel Nitrate Hexahydrate
13478-00-7
US $30.00 / Kg/Bag 25KG 99.99% 200ton Hebei Mojin Biotechnology Co., Ltd

Nickel(II) nitrate hexahydrate Spectrum

Nickel(II) nitrate hexahydrate, 99.995% trace metals basis Nickel (II) nitrate hexahydrate≥ 98.5% (Titration) Nickel (II) nitrate hexahydrate≥99.99% Nickel Nitrate (Ous) NICKEL NITRATE, HYDROUS nickel(2+)dinitratehexahydrate nickel(ii)nitrate,hexahydrate(1:2:6) nickeldinitratehexahydrate nitricacid,nickel(2+)salt,hexahydrate Nickel(II) nitrate hexahydrate, tech., Ni 19.8% min Nickel(II) nitrate hexahydrate, Puratronic(R), 99.9985% (metals basis) Nickel(II) nitrate hexahydrate, Puratronic, 99.9985% (metals basis) Nickel (II) nitrate hexayhydrate Nickel(II) nitrate hexahydrate,99% Nickel(II) nitrate hexahydrate, Puratronic (metals basis) Nickel(II) nitrate hexahydrate, extra pure NICKEL NITRATE HEXAHYDRATE (OUS) Nickel(II) nitrate hexahydrate 99.999% trace Metals basis Nickel(II) nitrate hexahydrate, Puratronic, 99.9985% (Metals basis), 99.9985% Nickel(Ⅱ) nitrate hexahydrate Nickel(Ⅱ) nitrate hexahydrate, ACS reagent Nickel(II) Nitrate Hexahydrate 99.995% Nickel(II) nitrate hexahydrate purum p.a., crystallized, >=97.0% (KT) NICKEL (II) NITRATE 6H2O,EX.CO Nickel(II) nitrate hexahydrate, technical NICKEL(II) NITRATE HEXAHYDRATE, CRYSTALL IZED NICKEL(II) NITRATE HEXAHYDRATE FLAKE NICKEL(II) NITRATE HEXAHYDRATE, CRYSTAL NICKEL(II) NITRATE HEXAHYDRATE, 99.999% NICKEL NITRATE-6-HYDRATE EXTRA PURE NickelNitrateAr NickelNitrateGr(Hexahydrate) NickelNitrateExtraPure(Hexahydrate) Nickel(II) nitrate hexahydrate crystals or chunks Nickel(II) nitrate hexahydrate puriss. p.a., >=98.5% (KT) NICKEL(+2)NITRATE HEXAHYDRATE NICKEL(II) NITRATE 6-HYDRATE NICKEL(II) NITRATE HEXAHYDRATE NICKEL (OUS) NITRATE NICKELOUS NITRATE, 6-HYDRATE NICKELOUS NITRATE, HEXAHYDRATE NICKEL NITRATE-6-HYDRATE NICKEL NITRATE, HEXAHYDRATE REAGENT NICKEL NITRATE, HEXAHYDRATE REAGENT (ACS) Nickel(II)nitratehexahydrate(99.9+%-Ni) Nickel(II)nitratehexahydrate(99.9985%-Ni)PURATREM nickel(ii) nitrate hexahydrate, puratronic nickel(ii) nitrate hexahydrate, tech. NICKELNITRATE,CRYSTAL,REAGENT nitric acid, nickel salt, hexahydrate NICKEL(II) NITRATE 6 H2O NICKEL NITRATE, HEXAHYDRATE 99.999+% NICKEL(II) NITRATE HEXAHYDRATE: 99.9985% Nickelnitrate,Nickelousnitrate,Nickelousnitrate NICKEL NITRATE, HEXAHYDRATE, 99.999+%NICKEL NITRATE, HEXAHYDRATE, 99.999+%NICKEL NITRATE, HEXAHYDRATE, 99.999+%NICKEL NITRATE, HEXAHYDRATE, 99.999+% NICKEL NITRATE, HEXAHYDRATE, REAGENT (ACS)NICKEL NITRATE, HEXAHYDRATE, REAGENT (ACS)NICKEL NITRATE, HEXAHYDRATE, REAGENT (ACS)NICKEL NITRATE, HEXAHYDRATE, REAGENT (ACS) NICKEL NITRATE, HEXAHYDRATE, REAGENTNICKEL NITRATE, HEXAHYDRATE, REAGENTNICKEL NITRATE, HEXAHYDRATE, REAGENTNICKEL NITRATE, HEXAHYDRATE, REAGENT Nickelousnitrate,Nickelousnitrate,Nickelnitrate