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4-Nitrophenylboronic acid

4-Nitrophenylboronic acid Structure
4-Nitrophenylboronic acid structure
CAS No.
24067-17-2
Chemical Name:
4-Nitrophenylboronic acid
Synonyms
RARECHEM AH PB 0141;4-Borononitrobenzene;4-nitrophenylboric acid;P-NITROPHENYLBORONIC ACID;4-NITROPHENYLBORONIC ACID;(4-Nitrophenyl)boronicaci;4-NITROBENZENEBORONIC ACID;p-nitro-benzeneboronic acid;B-(4-nitrophenyl)boronic acid;4-Nitrophenylboronic acid ,97%
CBNumber:
CB3116883
Molecular Formula:
C6H6BNO4
Molecular Weight:
166.93
MDL Number:
MFCD00161360
MOL File:
24067-17-2.mol
MSDS File:
SDS
Last updated:2023-12-25 13:23:17
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4-Nitrophenylboronic acid Properties

Melting point 285-290°C (dec.)
Boiling point 373.7±44.0 °C(Predicted)
Density 1.40±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility DMF: 15 mg/ml; DMSO: 15 mg/ml; Ethanol: 15 mg/ml; Ethanol:PBS (pH 7.2) (1:5): 0.16 mg/ml
pka 7.04±0.10(Predicted)
form Crystalline Powder
color White to yellow
Water Solubility Slightly soluble in water.
InChIKey NSFJAFZHYOAMHL-UHFFFAOYSA-N
CAS DataBase Reference 24067-17-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335-H302
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xn
Risk Statements  22
Safety Statements  26-36/37/39-24/25
WGK Germany  3
Hazard Note  Harmful
HS Code  29319090
NFPA 704
1
2 0

4-Nitrophenylboronic acid price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 673854 4-Nitrophenylboronic acid ≥95.0% 24067-17-2 1g $83.1 2024-03-01 Buy
Sigma-Aldrich 673854 4-Nitrophenylboronic acid ≥95.0% 24067-17-2 5g $191 2024-03-01 Buy
TCI Chemical N0812 4-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 24067-17-2 1g $28 2024-03-01 Buy
TCI Chemical N0812 4-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 24067-17-2 5g $110 2024-03-01 Buy
Alfa Aesar H27767 4-Nitrobenzeneboronic acid, 95% 24067-17-2 1g $63.65 2024-03-01 Buy
Product number Packaging Price Buy
673854 1g $83.1 Buy
673854 5g $191 Buy
N0812 1g $28 Buy
N0812 5g $110 Buy
H27767 1g $63.65 Buy

4-Nitrophenylboronic acid Chemical Properties,Uses,Production

Description

4-Nitrobenzeneboronic acid is an arylboronic acid building block that has been used in the synthesis of phenols.

Chemical Properties

White to brown powder or crystal

Uses

Reagent used for

  • Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings
  • Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines
  • Diels-Alder or C-H activation reactions
  • Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations
  • N-arylation of phenylurea using copper acetylacetonate catalyst
  • Environmentally benign one-pot synthesis through a double arylation process
  • Copper-mediated cyanations
  • copper-catalyzed arylations
  • Regioselective glycosylations
  • Suzuki couplings followed by arylations
  • X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins

Reagent used in Preparation of
  • Combretastatin analogs as potential antitumor agents
  • Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses

Uses

suzuki reaction

Uses

4-Nitrophenylboronic Acid is a useful synthetic intermediate. It is a reagent used for ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings, Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines and Diels-Alder or C-H activation reactions.

4-Nitrophenylboronic acid synthesis

67-56-1
55124-35-1
586-78-7
24067-17-2
Synthesis of 4-Nitrophenylboronic acid from Methanol and BORANE-DIISOPROPYLAMINE and 1-Bromo-4-nitrobenzene

4-Nitrophenylboronic acid Preparation Products And Raw materials

Raw materials

1-Bromo-4-nitrobenzene [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Cuprous iodide Toluene Bis(pinacolato)diboron
Tetrahydrofuran Hydrochloric acid Triisopropyl borate Sodium periodate Potassium Acetate
n-Butyllithium 1-Iodo-4-nitrobenzene

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Preparation Products

4-Nitrophenylboronic acid pinacol ester 4-Nitrobiphenyl 5-(4-NITRO-PHENYL)-2H-TETRAZOLE

4-Nitrophenylboronic acid Suppliers

Global( 271)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Xinsheng New Material Technology Co., LTD. 		+86-16632316109 xinshengkeji@xsmaterial.com China 1100 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7534 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Supplier Advantage
Hebei Xinsheng New Material Technology Co., LTD. 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Accela ChemBio Inc. 		58
Hubei xin bonus chemical co. LTD 		58
Chongqing Chemdad Co., Ltd 		58

View Lastest Price from 4-Nitrophenylboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Nitrophenylboronic acid pictures 2023-12-26 4-Nitrophenylboronic acid
24067-17-2
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-Nitrophenylboronic acid pictures 2023-12-02 4-Nitrophenylboronic acid
24067-17-2
 US $0.00-0.00 / kg 1kg 99.9% 30000 Kg Hebei Xinsheng New Material Technology Co., LTD.
4-Nitrophenylboronic acid pictures 2023-10-31 4-Nitrophenylboronic acid
24067-17-2
 US $35.00-25.00 / kg 1kg 99% 20 Ton Hebei Xinsheng New Material Technology Co., LTD.

24067-17-2(4-Nitrophenylboronic acid)Related Search:

Zinc borate Phenylboronic acid 3-(CYCLOHEXYLCARBAMOYL)-5-NITROPHENYLBORONIC ACID 3-(N,N-DIETHYLAMINOCARBONYL)-5-NITROPHENYLBORONIC ACID 3-NITROPHENYLBORONIC ACID,M-NITROPHENYLBORONIC ACID
3-NITROPHENYLBORONIC ACID, PINACOL ESTER 4-METHOXY-3-NITROPHENYLBORONIC ACID, PINACOL ESTER 4-METHOXY-3-NITROPHENYLBORONIC ACID Nitromethane 4-NITROPHENYLBORONIC ACID PINACOL ESTER
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Boronic acid, B-(4-nitrophenyl)- p-nitro-benzeneboronic acid 4-Nitrophenylboronic acid >=95.0% B-(4-nitrophenyl)boronic acid 4-NITROPHENYLBORONIC ACID 4-NITROBENZENEBORONIC ACID RARECHEM AH PB 0141 P-NITROPHENYLBORONIC ACID 4-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 4-Nitrophenylboronic acid ,97% 4-Borononitrobenzene VLOOKUP(C11,[1]Export!$D:$H,5,0) (4-Nitrophenyl)boronicaci 4-Nitrophenylboronic acid ISO 9001：2015 REACH 4-nitrophenylboric acid 24067-17-2 171634-83-3 4067-17-2 Aryl Boronic Acids and Derivatives Boronic Acids Organometallic Reagents Boronate Ester Boronic Acid Potassium Trifluoroborate blocks BoronicAcids B (Classes of Boron Compounds) Aryl Boronic Acids Boronic Acids and Derivatives Substituted Boronic Acids Boronic acids