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(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS structure

CAS No.: 210169-54-3

Chemical Name:: (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS

Synonyms: (S)-(-)-SEGPHOS;(S)-SEGPHOS(R);(S)-SEGPHOS(R) >=94%;(S)-(-)-SEGPHOS(regR);(S)-(-)-SEGPHOS(S)-(-)-SEGPHOS;-bi-1,3-benzodioxole,(S)-(-)-SEGPHOS;(S)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzodioxole;(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole;(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,98%;(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%

CBNumber:: CB31180993

Molecular Formula:: C38H28O4P2

Molecular Weight:: 610.57

MDL Number:: MFCD09753005

MOL File:: 210169-54-3.mol

MSDS File:: SDS

Last updated:2023-06-08 17:06:34

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(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Properties

Melting point	231-235 °C
Boiling point	715.4±60.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
form	Powder
color	off-white
optical activity	[α]20/D -11°, c = 0.5 in chloroform
InChIKey	RZZDRSHFIVOQAF-UHFFFAOYSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
WGK Germany	3
HS Code	2932.99.7000

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS price More Price(22)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	693006	(S)-SEGPHOS? ≥94%	210169-54-3	100mg	$49.3	2024-03-01	Buy
Sigma-Aldrich	693006	(S)-SEGPHOS? ≥94%	210169-54-3	50mg	$31.6	2023-06-20	Buy
TCI Chemical	S0929	(S)-(-)-SEGPHOS[R] >99.0%(HPLC)	210169-54-3	200mg	$60	2024-03-01	Buy
TCI Chemical	S0929	(S)-(-)-SEGPHOS[R] >99.0%(HPLC)	210169-54-3	1g	$177	2024-03-01	Buy
Strem Chemicals	15-0137	(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (S)-(-)-SEGPHOS(R)	210169-54-3	250mg	$48	2024-03-01	Buy

Product number	Packaging	Price	Buy
693006	100mg	$49.3	Buy
693006	50mg	$31.6	Buy
S0929	200mg	$60	Buy
S0929	1g	$177	Buy
15-0137	250mg	$48	Buy

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Chemical Properties,Uses,Production

Reaction

Biaryl bisphosphine ligand with narrow dihedral angle. The SEGPHOS® ligand has been applied to a variety of metal catalyzed reactions. In many cases, yields and enantioselectivities, exceed results obtained earlier using BINAP.
As ruthenium complex, SEGPHOS® generally gives higher levels of chiral induction in asymmetric hydrogenations of α,β,and γ-functionalized ketones. See ruthenium complexes 44-0096, 44-0518, 44-0168.
Used in Rh-catalyzed transformations such as: (a) 1,4-addition of boronic acids to coumarins,4 (b) addition of titanium reagents to imines, (c) cotrimerization of alkenes and acetylenes, (d) double [2+2+2] cycloaddition,11 (e) indanone formation.12a,b
Used in Pd-catalyzed transformations such as: (a) cycloaddition of 1,6-enyne, (b) arylative cyclization of allenyl aldehydes with boronic acids,13 (c) synthesis of chromans.
Used in Cu-catalyzed transformations such as: (a) nitroso Diels-Alder, (b) reductive aldol condensation, (c) conjugate reduction of unsaturated sulfones,15 and phophonates.
Iridium-catalyzed asymmetric hydrogenation of quinolines activated by chloroformates.

Uses

(S)-(-)-SEGPHOS? is a chelating ligand used to prepare coordination complex catalysts, such as its use in Pd catalysts for the enantioselective synthesis of spiro- or benzofused hetereocycles with exocyclic olefins via enantioselective intramolecular dearomative Heck reaction of indoles, benzofurans, pyrroles and furans.

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Suppliers

Global( 106)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	399	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58
Jinan Honest Pharm Co., Ltd	+8615318812076	zpy8217@163.com	China	286	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
CR Corporation Lomited		fred.wen@crcorporation.cn	CHINA	12069	58
CD Chemical Group Limited	+8615986615575	info@codchem.com	China	20356	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
Richest Group Ltd	58
Jinan Honest Pharm Co., Ltd	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
CR Corporation Lomited	58
CD Chemical Group Limited	58

View Lastest Price from (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-07-27	(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS 210169-54-3	US $0.00-0.00 / KG	1KG	0.99	500kg	XINXIANG RUNYU MATERIAL CO., LTD.
	2019-07-11	(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS 210169-54-3	US $3.00 / KG	1KG	99%	100kg	Career Henan Chemical Co

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
210169-54-3
US $0.00-0.00 / KG
0.99
XINXIANG RUNYU MATERIAL CO., LTD.

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
210169-54-3
US $3.00 / KG
99%
Career Henan Chemical Co

210169-54-3((S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS)Related Search:

(R)-SEGPHOS N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2 Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-DIFLUORPHOS(TM) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) (S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DM-SEGPHOS

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)

Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride

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(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Phosphine,1,1'-[(4S)-[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenyl- (S)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzodioxole (S)-SEGPHOS(R) (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,(S)-(-)-SEGPHOS (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,98% -bi-1,3-benzodioxole,(S)-(-)-SEGPHOS (S)-(-)-SEGPHOS(regR) (S)-SEGPHOS(R) >=94% (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (S)-(-)-4,4'-Bis(diphenylphosphino)-3,3'-bi(1,2-methylenedioxybenzene) (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (S)-(-)-SEGPHOS(R) (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min,(S)-SEGPHOS 1,1'-[(4S)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenylphosphine] (S)-(-)-SEGPHOS(S)-(-)-SEGPHOS (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98% (S)-(-)-SEGPHOS (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole 210169-54-3 C38H28O4P2 Chiral Phosphine Segphos Series