ChemicalBook >> CAS DataBase List >>Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

CAS No.
220114-38-5
Chemical Name:
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
Synonyms
(R) -DM-BINAP RUCL2 (R.R)-DPEN;RuCl2[(R)-xylbinap][(R,R)-dpen];RuCl2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G;Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl};-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(;Dichloro[(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(R,R)-1,2-diphenylethylenediamine]ruthenium(II);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II);DICHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(;Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
CBNumber:
CB31181071
Molecular Formula:
C66H64Cl2N2P2Ru
Molecular Weight:
1119.17
MDL Number:
MFCD09753028
MOL File:
220114-38-5.mol
Last updated:2023-06-08 17:06:34

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Properties

storage temp. 2-8°C
form Powder
color yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
HS Code  2843.90.0000

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692301 RuCl2[(R)?DM?BINAP][(R,R)?DPEN] 220114-38-5 50mg $33.8 2024-03-01 Buy
Sigma-Aldrich 692301 RuCl2[(R)?DM?BINAP][(R,R)?DPEN] 220114-38-5 100mg $48.6 2023-06-20 Buy
TCI Chemical R0135 RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 200mg $75 2024-03-01 Buy
TCI Chemical R0135 RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 1g $253 2024-03-01 Buy
Strem Chemicals 44-0226 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 250mg $64 2024-03-01 Buy
Product number Packaging Price Buy
692301 50mg $33.8 Buy
692301 100mg $48.6 Buy
R0135 200mg $75 Buy
R0135 1g $253 Buy
44-0226 250mg $64 Buy

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Chemical Properties,Uses,Production

Uses

RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.

General Description

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Suppliers

Global( 30)Suppliers
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career henan chemical co
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Chongqing Chemdad Co., Ltd
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changzhou huayang technology co., ltd
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Alfa Chemistry
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Shaoxin Catsyn Co., Ltd.
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J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
BeiJing Hwrk Chemicals Limted 0757-86329057 18934348241 sales4.gd@hwrkchemical.com China 14067 55
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340 307593986@qq.com China 475 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28398 80

View Lastest Price from Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) pictures 2019-08-09 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
220114-38-5
US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(R)-xylbinap][(R,R)-dpen] Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen] -binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[( RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G DICHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[( Dichloro[(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(R,R)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} (R) -DM-BINAP RUCL2 (R.R)-DPEN 220114-38-5 C66H64Cl2N2P2Ru Ru