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(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS Structure
(R)-C3-TUNEPHOS structure
CAS No.
301847-89-2
Chemical Name:
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TunaPhos;-C3-TunaPhos;(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(R)-C3-TunePhos;1,13-bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
CBNumber:
CB3139370
Molecular Formula:
C39H32O2P2
Molecular Weight:
594.62
MDL Number:
MFCD06658115
MOL File:
301847-89-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:59:02
Product description Number Pack Size Price
R-(-)-1,13-Bis(diphenyl­phosphino)-7,8-di­hydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C₃-TUNEPHOS 97% 15-0175 100mg $130
R-(-)-1,13-Bis(diphenyl­phosphino)-7,8-di­hydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C₃-TUNEPHOS 97% 15-0175 500mg $516
R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 15-0175 100mg $124
R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 15-0175 500mg $495
(R)-C3-TunaPhos 098006 250.00mg $265
Request For Quotation

(R)-C3-TUNEPHOS Properties

Melting point 153-161 °C(lit.)
Boiling point 709.9±60.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form Powder
color white
optical activity [α]20/D -252±5°, c = 1 in chloroform
Sensitive air sensitive
InChIKey GTIXSUJKFAATAE-UHFFFAOYSA-N
SMILES C12=C(C=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1)OCCCOC1C=CC=C(P(C3C=CC=CC=3)C3C=CC=CC=3)C2=1
UNSPSC Code 12352005

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  3
Storage Class 13 - Non Combustible Solids

(R)-C3-TUNEPHOS price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenyl­phosphino)-7,8-di­hydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C₃-TUNEPHOS 97% 301847-89-2 100mg $130 2026-04-30 Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenyl­phosphino)-7,8-di­hydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C₃-TUNEPHOS 97% 301847-89-2 500mg $516 2026-04-30 Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 301847-89-2 100mg $124 2024-03-01 Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 301847-89-2 500mg $495 2024-03-01 Buy
Matrix Scientific 098006 (R)-C3-TunaPhos 301847-89-2 250.00mg $265 2026-05-18 Buy
Product number Packaging Price Buy
15-0175 100mg $130 Buy
15-0175 500mg $516 Buy
15-0175 100mg $124 Buy
15-0175 500mg $495 Buy
098006 250.00mg $265 Buy

(R)-C3-TUNEPHOS Chemical Properties,Uses,Production

Reaction

  1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
  2. Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
  3. Rh-catalyzed hydroformylation of cyclopropenes.
Reactions of 301847-89-2

Uses

1,1''-[(13aR)-7,8-Dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenylphosphine] is used in the process of preparation of cyclohexyl ethers via ketal hydrogenation.

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Ligand used in:

  • Redox-neutral domino reaction of arylethynylbenzylidenearylpentynones catalyzed by gold catalyst
  • Asymmetric allylic O-alkylation
  • Asymmetric alkylation of racemic secondary phosphines catalyzed by ruthenium chiral diphosphine hydride complexes
  • Stereoselective preparation of cyclopropylcarboxaldehydes via Rh-catalyzed asymmetric hydroformylation of cyclopropenes
  • Rhodium-catalyzed asymmetric hydrogenations

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-C3-TUNEPHOS Suppliers

Global( 40)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16513 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13902 58
XINXIANG RUNYU MATERIAL CO., LTD. 		+86-13592593621; +8613592593621 sales@runvmat.com China 457 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
Soochow Chirally Material Science and Technology Co.,Ltd 		+86-51266834346 +86-17751128648 sales@krl-tech.com China 1050 58
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076 3007432263@qq.com China 9954 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 18018851262; 420970979@qq.com China 5951 58
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
J & K SCIENTIFIC LTD. 18210857532; 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40228 62
Supplier Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
XINXIANG RUNYU MATERIAL CO., LTD. 		58
Aladdin Scientific 		58
Soochow Chirally Material Science and Technology Co.,Ltd 		58
Guangdong wengjiang Chemical Reagent Co., Ltd. 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Xinxiang Runyu Material Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62

View Lastest Price from (R)-C3-TUNEPHOS manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-C3-TUNEPHOS pictures 2026-04-17 (R)-C3-TUNEPHOS
301847-89-2
 US $2.00-5.00 / kg 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
(R)-C3-TUNEPHOS pictures 2025-12-23 (R)-C3-TUNEPHOS
301847-89-2
 US $0.00-0.00 / G 1G 99% 500G XINXIANG RUNYU MATERIAL CO., LTD.
  • (R)-C3-TUNEPHOS pictures
  • (R)-C3-TUNEPHOS
    301847-89-2
  • US $2.00-5.00 / kg
  • 99%
  • ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
  • (R)-C3-TUNEPHOS pictures
  • (R)-C3-TUNEPHOS
    301847-89-2
  • US $0.00-0.00 / G
  • 99%
  • XINXIANG RUNYU MATERIAL CO., LTD.

301847-89-2((R)-C3-TUNEPHOS)Related Search:

Phosphine (R)-C3-TUNEPHOS R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-C3-TUNEPHOS [CHLORO(R)-C3-TUNEPHOS)(P-CYMENE)RUTHENIUM(II)] CHLORIDE,(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX
(S)-C3-TUNEPHOS (R)-C3-TUNEPHOS (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,97%(R)-C3-TUNEPHOS R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (R)-C3-TUNEPHOS -C3-TunaPhos Phosphine, 1,1'-[(13aR)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- (R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (R)-C3-TunaPhos 1,13-bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (R)-C3-TunePhos 301847-89-2 Privileged Ligands ChiralQuest Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand