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(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS Structure
(R)-C3-TUNEPHOS structure
CAS No.
301847-89-2
Chemical Name:
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TunaPhos;-C3-TunaPhos;(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (R)-C3-TUNEPHOS;Phosphine, 1,1'-[(13aR)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
CBNumber:
CB3139370
Molecular Formula:
C39H32O2P2
Molecular Weight:
594.62
MDL Number:
MFCD06658115
MOL File:
301847-89-2.mol
Last updated:2023-05-15 10:42:54
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(R)-C3-TUNEPHOS Properties

Melting point 153-161 °C(lit.)
Boiling point 709.9±60.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form Powder
color white
optical activity [α]20/D -252±5°, c = 1 in chloroform
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3

(R)-C3-TUNEPHOS price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 301847-89-2 100mg $124 2024-03-01 Buy
Strem Chemicals 15-0175 R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS 301847-89-2 500mg $495 2024-03-01 Buy
AK Scientific B605 (R)-C3-TunePhos 301847-89-2 500mg $584 2021-12-16 Buy
Matrix Scientific 098006 (R)-C3-TunaPhos 95+% 301847-89-2 1g $588 2021-12-16 Buy
AK Scientific B605 (R)-C3-TunePhos 301847-89-2 100mg $184 2021-12-16 Buy
Product number Packaging Price Buy
15-0175 100mg $124 Buy
15-0175 500mg $495 Buy
B605 500mg $584 Buy
098006 1g $588 Buy
B605 100mg $184 Buy

(R)-C3-TUNEPHOS Chemical Properties,Uses,Production

Reaction

  1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
  2. Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
  3. Rh-catalyzed hydroformylation of cyclopropenes.
Reactions of 301847-89-2

Uses

1,1''-[(13aR)-7,8-Dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenylphosphine] is used in the process of preparation of cyclohexyl ethers via ketal hydrogenation.

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Ligand used in:

  • Redox-neutral domino reaction of arylethynylbenzylidenearylpentynones catalyzed by gold catalyst
  • Asymmetric allylic O-alkylation
  • Asymmetric alkylation of racemic secondary phosphines catalyzed by ruthenium chiral diphosphine hydride complexes
  • Stereoselective preparation of cyclopropylcarboxaldehydes via Rh-catalyzed asymmetric hydroformylation of cyclopropenes
  • Rhodium-catalyzed asymmetric hydrogenations

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-C3-TUNEPHOS Suppliers

Global( 30)Suppliers
Supplier Tel Email Country ProdList Advantage
Suzhou Origin Specialty Chemicals Co., Ltd. 		+86-512-68662322 +86-17312436797 hanqun@origsc.com China 776 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076 3007432263@qq.com China 10001 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-0371-65511006 18625597674 sales@kingorgchem.com China 950 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Supplier Advantage
Suzhou Origin Specialty Chemicals Co., Ltd. 		58
Aladdin Scientific 		58
Guangdong wengjiang Chemical Reagent Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58

301847-89-2((R)-C3-TUNEPHOS)Related Search:

Phosphine (R)-C3-TUNEPHOS R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-C3-TUNEPHOS [CHLORO(R)-C3-TUNEPHOS)(P-CYMENE)RUTHENIUM(II)] CHLORIDE,(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX
(S)-C3-TUNEPHOS (R)-C3-TUNEPHOS (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,97%(R)-C3-TUNEPHOS R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (R)-C3-TUNEPHOS -C3-TunaPhos Phosphine, 1,1'-[(13aR)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- (R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (R)-C3-TunaPhos 301847-89-2 Privileged Ligands ChiralQuest Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand