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Allylthiourea

Allylthiourea
Allylthiourea
CAS No.
109-57-9
Chemical Name:
Allylthiourea
Synonyms
u19571;U 19571;AMINOSIN;Rhodalin;Rhodallin;RHODALLINE;Thiosinamin;Tiosinamine;ThiosnaMine;THIOSINAMINE
CBNumber:
CB3145441
Molecular Formula:
C4H8N2S
Formula Weight:
116.18
MOL File:
109-57-9.mol

Allylthiourea Properties

Melting point:
70-72 °C(lit.)
Density 
1.11 g/mL at 25 °C(lit.)
refractive index 
1.5936 (estimate)
storage temp. 
Store below +30°C.
solubility 
H2O: soluble30 parts
form 
Powder, Crystals, Granules or Chunks
color 
White to light beige
Water Solubility 
67 g/L (20 ºC)
Merck 
14,9362
BRN 
1071470
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
HTKFORQRBXIQHD-UHFFFAOYSA-N
CAS DataBase Reference
109-57-9(CAS DataBase Reference)
NIST Chemistry Reference
Allylthiourea(109-57-9)
EPA Substance Registry System
Thiourea, 2-propenyl-(109-57-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T
Risk Statements  25
Safety Statements  45-24/25
RIDADR  UN 2811 6.1/PG 3
WGK Germany  2
RTECS  YR8050000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29309070
Toxicity LD50 orally in rats: 200 mg/kg (Dieke)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…

Allylthiourea price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 108804 N-Allylthiourea 98% 109-57-9 50g $41.5 2018-11-13 Buy
Sigma-Aldrich 108804 N-Allylthiourea 98% 109-57-9 250g $149 2018-11-13 Buy
TCI Chemical A0220 1-Allyl-2-thiourea >98.0%(T) 109-57-9 25g $28 2017-11-08 Buy
TCI Chemical A0220 1-Allyl-2-thiourea >98.0%(T) 109-57-9 100g $76 2017-11-08 Buy
Alfa Aesar L03377 N-Allylthiourea, 98% 109-57-9 100g $70 2018-11-13 Buy

Allylthiourea Chemical Properties,Uses,Production

Chemical Properties

white crystals or powder

Uses

chelating agent

Definition

ChEBI: A thiourea with a prop-2-enyl group attached to one of the amines.

General Description

White crystalline solid with a slight garlic odor.

Air & Water Reactions

Soluble in water.

Reactivity Profile

Allylthiourea may react vigorously with strong oxidizing agents. Can react exothermically with reducing agents (such as alkali metals and hydrides) to release gaseous hydrogen. May react exothermically with both acids and bases. May generate flammable gases in combination with aldehydes, nitrides, and hydrides. Incompatible with peroxides and acid halides.

Health Hazard

SYMPTOMS: Contact eczema due to sensitization in humans has been reported.

Fire Hazard

Flash point data are not available for Allylthiourea, but Allylthiourea is probably combustible.

Purification Methods

Recrystallise it from H2O. It is soluble in 30 parts of cold H2O, and it is soluble in EtOH but insoluble in *C6H6. It has also been recrystallised from acetone, EtOH or ethyl acetate, after decolorising with charcoal. The white crystals have a bitter taste with a slight garlic odour and are TOXIC. An unstable crystalline form is obtained by recrystallising from the melt. [McCrone et al. Anal Chem 21 421 1949, Beilstein 4 IV 1072.]

Allylthiourea Preparation Products And Raw materials

Raw materials

Preparation Products


Allylthiourea Suppliers

Global( 162)Suppliers
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