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SILVER TRIFLUOROMETHANESULFONATE

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SILVER TRIFLUOROMETHANESULFONATE
SILVER TRIFLUOROMETHANESULFONATE structure
CAS No.
2923-28-6
Chemical Name:
SILVER TRIFLUOROMETHANESULFONATE
Synonyms
AGOTF;SILVER TRIFLATE;Silver(I)triflate;Indiumtrifluorometha;SILVER TRIFLUOROMETHANESULFOTE;LVER TRIFLUOROMETHANESULFONATE;Silver trifluormethanesulfonate;SILVER TRIFLUOROMETANESULFONATE;TRIFLUOROMETHYLSULFONYLOXYSILVER;SILVER TRIFLUOROMETHANESULFONATE
CBNumber:
CB3157655
Molecular Formula:
CAgF3O3S
Formula Weight:
256.94
MOL File:
2923-28-6.mol

SILVER TRIFLUOROMETHANESULFONATE Properties

Melting point:
286 °C(lit.)
storage temp. 
2-8°C
form 
Powder
color 
White to light beige
Water Solubility 
Soluble in water and also in most organic solvents.
Sensitive 
Light Sensitive
BRN 
3598402
Stability:
Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.
InChIKey
QRUBYZBWAOOHSV-UHFFFAOYSA-M
CAS DataBase Reference
2923-28-6(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,C
Risk Statements  36/37/38-50-34
Safety Statements  26-36-61-45-36/37/39
RIDADR  3260
WGK Germany  3
8
Hazard Note  Corrosive
TSCA  Yes
HazardClass  CORROSIVE
HazardClass  8
HS Code  28432900
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

SILVER TRIFLUOROMETHANESULFONATE price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 176435 Silver trifluoromethanesulfonate ≥99% 2923-28-6 1g $24.1 2018-11-13 Buy
Sigma-Aldrich 176435 Silver trifluoromethanesulfonate ≥99% 2923-28-6 10g $92.9 2018-11-13 Buy
TCI Chemical T1331 Silver Trifluoromethanesulfonate >98.0%(T) 2923-28-6 1g $22 2018-11-22 Buy
TCI Chemical T1331 Silver Trifluoromethanesulfonate >98.0%(T) 2923-28-6 10g $97 2018-11-22 Buy
Alfa Aesar 088722 Silver trifluoromethanesulfonate, 98% 2923-28-6 2g $18 2018-11-16 Buy

SILVER TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production

Reactions

  1. Silver precatalyst for the asymmetric allylation of aldehydes
  2. Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
  3. Silver catalyst for the fluorination of boronic acids
  4. Silver catalyst for the fluorination of functionalized aryl stannanes
  5. Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
  6. Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate

Chemical Properties

light beige crystalline powder

Purification Methods

Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.]

SILVER TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products


SILVER TRIFLUOROMETHANESULFONATE Suppliers

Global( 231)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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Mainchem Co., Ltd.
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Nanjing ChemLin Chemical Industry Co., Ltd.
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ATK CHEMICAL COMPANY LIMITED
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Nanjing Pharmaluxury Co., Ltd. 025-8372-6959 ;025- 8666-0986 ;158-5181-6062
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BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807
010-87653215;0757-86311057;021-55236763 sales@hwrkchemical.com China 14615 55
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30291 84

SILVER TRIFLUOROMETHANESULFONATE Spectrum


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