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4,4'-DIMETHOXYDIPHENYLAMINE

CAS No.
101-70-2
Chemical Name:
4,4'-DIMETHOXYDIPHENYLAMINE
Synonyms
BIS(4-METHOXYPHENYL)AMINE;K0353;Termofleks A;DI-P-ANISYLAMINE;BIS(P-ANISYL)AMINE;Di-P-Methoxyphenyl;4,4'-DIMETHOXYDIPHEN;4,4'-DIMETHOXYDIPHENYL;Di-p-methoxyphenylamine;-DIMETHOXYDIPHENYLAMINE
CBNumber:
CB3167108
Molecular Formula:
C14H15NO2
Molecular Weight:
229.27
MDL Number:
MFCD00014895
MOL File:
101-70-2.mol
MSDS File:
SDS
Last updated:2026-06-24 18:39:39
Product description Number Pack Size Price
4,4′-Dimethoxydiphenylamine 99% 767905 5g $818
4,4′-Dimethoxydiphenylamine 99% 767905 1g $190
4,4'-Dimethoxydiphenylamine >98.0%(GC)(T) D0632 1g $32
4,4'-Dimethoxydiphenylamine >98.0%(GC)(T) D0632 5g $96
4,4'-Dimethoxydiphenylamine TRC-D461065-5G 5g $256
More product size

4,4'-DIMETHOXYDIPHENYLAMINE Properties

Melting point 101-102°C
Boiling point 371.18°C (rough estimate)
Density 1.0955 (rough estimate)
refractive index 1.5300 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
pka 2.16±0.40(Predicted)
color Off-White to Light Brown
Water Solubility Soluble in methanol. Insoluble in water.
Sensitive Air Sensitive
BRN 2214262
Stability Stability Combustible. Incompatible with strong oxidizing agents.
InChI 1S/C14H15NO2/c1-16-13-7-3-11(4-8-13)15-12-5-9-14(17-2)10-6-12/h3-10,15H,1-2H3
InChIKey VCOONNWIINSFBA-UHFFFAOYSA-N
SMILES COc1ccc(Nc2ccc(OC)cc2)cc1
FDA 21 CFR 177.2600
Indirect Additives used in Food Contact Substances 4,4'-DIMETHOXYDIPHENYLAMINE
CAS DataBase Reference 101-70-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII I912MLM9XT
NIST Chemistry Reference Di-(4-methoxy phenyl) amine(101-70-2)
EPA Substance Registry System 4,4'-Dimethoxydiphenylamine (101-70-2)
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Warning
Hazard statements  H315-H319-H335-H351
Precautionary statements  P201-P302+P352-P305+P351+P338-P308+P313
target organs Respiratory system
Hazard Codes  Xn
Risk Statements  68-40-36/37/38
Safety Statements  22-36/37/39-36/37-26-53
WGK Germany  3
RTECS  DU9085000
TSCA  TSCA listed
HS Code  29222990
Storage Class 11 - Combustible Solids
Hazard Classifications Carc. 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Toxicity mouse,LD50,oral,2500mg/kg (2500mg/kg),BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)BEHAVIORAL: TREMORLUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,Kauchuk i Rezina. Crude and Vulcanized Rubber. Vol. 26(9), Pg. 28, 1967.
NFPA 704
0
2 0

4,4'-DIMETHOXYDIPHENYLAMINE price More Price(59)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 767905 4,4′-Dimethoxydiphenylamine 99% 101-70-2 5g $818 2026-04-30 Buy
Sigma-Aldrich 767905 4,4′-Dimethoxydiphenylamine 99% 101-70-2 1g $190 2023-06-20 Buy
TCI Chemical D0632 4,4'-Dimethoxydiphenylamine >98.0%(GC)(T) 101-70-2 1g $32 2026-04-30 Buy
TCI Chemical D0632 4,4'-Dimethoxydiphenylamine >98.0%(GC)(T) 101-70-2 5g $96 2026-04-30 Buy
TRC TRC-D461065-5G 4,4'-Dimethoxydiphenylamine 101-70-2 5g $256 2026-06-03 Buy
Product number Packaging Price Buy
767905 5g $818 Buy
767905 1g $190 Buy
D0632 1g $32 Buy
D0632 5g $96 Buy
TRC-D461065-5G 5g $256 Buy

4,4'-DIMETHOXYDIPHENYLAMINE Chemical Properties,Uses,Production

Description

4,4'-Dimethoxydiphenylamine is a diphenylamine containing electron-donating substituents that exhibits antioxidant activity. When present as an antioxidant, it is consumed to generate nitroso radicals, which in turn exert antioxidant effects [1]. It can also be used in the synthesis of 9,9′-bis(fluorenylidene) (KR216) hole-transporting materials. When applied in perovskite solar cells, it achieves a power conversion efficiency of 17.8% [2].

Chemical Properties

silver-grey crystalline solid

Uses

4,4'-Dimethoxydiphenylamine is a diphenylamine derivative used as a chemical additive for cured rubber. It is used in the synthesis of amine electron donating groups in organic donor-bridge-acceptor dyads in Dye Sensitized Solar Cells (DSSC). 4,4-Dimethoxydiphenylamine is an electron donor and used in the synthesis of organic nonlinear optical (NLO) chromophores which exhibit high thermal and chemical stability, high degree of non-linearity and transparency. They are used in high performance photonic devices.

General Description

Fine very light gray to silver-gray crystalline solid.

Air & Water Reactions

4,4'-DIMETHOXYDIPHENYLAMINE may be sensitive to prolonged exposure to air. Slowly oxidized. Insoluble in water.

Reactivity Profile

4,4'-DIMETHOXYDIPHENYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: 4,4'-DIMETHOXYDIPHENYLAMINE can produce extremely irritating fumes when exposed to air or fire.

Fire Hazard

Flash point data for 4,4'-DIMETHOXYDIPHENYLAMINE are not available. 4,4'-DIMETHOXYDIPHENYLAMINE is probably combustible.

References

[1] Mareyuki Takahashi, E. N., J. Tsuchiya. (1989). Oxidation of lipids. XVI. Inhibition of autoxidation of methyl linoleate by diarylamines. Bulletin of the Chemical Society of Japan, 62 1, 1880–1884. https://doi.org/10.1246/bcsj.62.1880
[2] Kasparas Rakstys. (2016). Highly Efficient Perovskite Solar Cells Employing an Easily Attainable Bifluorenylidene-Based Hole-Transporting Material. Angewandte Chemie International Edition, 55 26, 7464–7468. https://doi.org/10.1002/anie.201602545

696-62-8
104-94-9
101-70-2
Synthesis of 4,4'-DIMETHOXYDIPHENYLAMINE from 4-Iodoanisole and p-Anisidine

4,4'-DIMETHOXYDIPHENYLAMINE Preparation Products And Raw materials

Global( 252)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Rlavie Technology Co ltd
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+86-18930848214 +86-021-56762820 sales@myuchem.com China 8898 58
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Beijing Green Guardee Technology Co., Ltd
86-010-69706062 sales2@greenguardee.com CHINA 650 58
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View Lastest Price from 4,4'-DIMETHOXYDIPHENYLAMINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-dimethoxydiphenylamine pictures 2026-08-18 4,4'-dimethoxydiphenylamine
101-70-2
$49.00-333.00 1g 0.98 25kg Shanghai UCHEM Inc.
4-Biphenylamine pictures 2026-05-28 4-Biphenylamine
101-70-2
$10.50 1KG 99% 10 ton Hebei Chuanghai Biotechnology Co,.LTD
4,4'-DIMETHOXYDIPHENYLAMINE pictures 2026-03-20 4,4'-DIMETHOXYDIPHENYLAMINE
101-70-2
$19.90 100ASSAYS 99.5% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
4,4’-dimethoxy-4-biphenylamin 4-Biphenylamine, 4,4'-dimethoxy- 4-Methoxy-N-(4-methoxyphenyl)aniline 4-methoxy-n-(4-methoxyphenyl)-benzenamin Benzenamine, 4-methoxy-N-(4-methoxyphenyl)- Bis(4-methoxyphenyl)-amin Bis(p-methoxyphenyl)amine Di-p-methoxyphenylamine p,p’-dimethoxydiphenylamine p,p'-Dimethoxydiphenylamine Termofleks A DI-P-ANISYLAMINE BIS(P-ANISYL)AMINE 4,4'-DIMETHOXYDIPHENYLAMINE N-(4-methoxyphenyl)-p-anisidine 4-Methoxy-N-(4-methoxyphenyl)benzamide 4,4''-DIMETHOXYDIPHENYLAMINE 98% 4-Methoxyphenyl(4-methoxyphenyl)amine Di-P-Methoxyphenyl Di-p-anisylamine Bis(4-methoxyphenyl)amine 4,4'-DIMETHOXYDIPHEN N,N-Bis(4-Methoxyphenyl)amine Benzenamine,4-methoxy-N-(4-methoxypheny)- 4,4'-DIMETHOXYDIPHENYL -DIMETHOXYDIPHENYLAMINE K0353 4,4'-Dimethoxydiphenylamine > 4,4'-DIMETHOXYDIPHENYLAMINE ISO 9001:2015 REACH 2-ACETYL-5-CHLORO-296-METHYLTHIANAPHTHENE 4,4''-Dimethoxydiphenylamine BIS(4-METHOXYPHENYL)AMINE 101-70-2 Reagent for High-Performance Polymer Research Diphenylamines (for High-Performance Polymer Research) Diphenylamines (for High-Performance Polymer Research) Functional Materials Reagent for High-Performance Polymer Research OLED