BISMUTH(III) FLUORIDE
- CAS No.
- 7787-61-3
- Chemical Name:
- BISMUTH(III) FLUORIDE
- Synonyms
- BISMUTH TRIFLUORIDE;Bismuthfluoride1;BISMUTH FLUORIDE;trifluoro-bismuthin;trifluorobismuthane;trifluoro-Bismuthine;Bismuth(Ⅲ) Fluoride;BISMUTH(III) FLUORIDE;Bismuthine, trifluoro-;BISMUTH(III) TRIFLUORIDE
- CBNumber:
- CB3196539
- Molecular Formula:
- BiF3
Lewis structure
- Molecular Weight:
- 265.98
- MDL Number:
- MFCD00010893
- MOL File:
- 7787-61-3.mol
- MSDS File:
- SDS
| Melting point | 727 °C | ||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Boiling point | 900°C | ||||||||||||||
| Density | 8.3 g/mL at 25 °C(lit.) | ||||||||||||||
| refractive index | 1.74 | ||||||||||||||
| solubility | H2O: insoluble(lit.) | ||||||||||||||
| form | Powder | ||||||||||||||
| Specific Gravity | 5.32 | ||||||||||||||
| color | white-gray cubic crystals, crystalline | ||||||||||||||
| Water Solubility | Insoluble in water. Soluble in HF. | ||||||||||||||
| Crystal Structure | YF3 type | ||||||||||||||
| Sensitive | Hygroscopic | ||||||||||||||
| Merck | 14,1265 | ||||||||||||||
| crystal system | Nogata | ||||||||||||||
| Space group | Pnma | ||||||||||||||
| Lattice constant |
|
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| Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3 |
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| CAS DataBase Reference | 7787-61-3(CAS DataBase Reference) | ||||||||||||||
| FDA UNII | 6I46O71A7B | ||||||||||||||
| EPA Substance Registry System | Bismuthine, trifluoro- (7787-61-3) | ||||||||||||||
| UNSPSC Code | 12352302 | ||||||||||||||
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28261990 | |||||||||
| NFPA 704 |
|
BISMUTH(III) FLUORIDE price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 401528 | Bismuth(III) fluoride ≥99.99% trace metals basis | 7787-61-3 | 5g | $84.7 | 2024-03-01 | Buy |
| Alfa Aesar | 013075 | Bismuth(III) fluoride, anhydrous, 99% | 7787-61-3 | 100g | $117.65 | 2024-03-01 | Buy |
| Alfa Aesar | 013075 | Bismuth(III) fluoride, anhydrous, 99% | 7787-61-3 | 25g | $50.1 | 2023-06-20 | Buy |
| Strem Chemicals | 83-3000 | Bismuth(III) fluoride (99.99+%-Bi) PURATREM | 7787-61-3 | 10g | $71 | 2024-03-01 | Buy |
| Strem Chemicals | 83-3000 | Bismuth(III) fluoride (99.99+%-Bi) PURATREM | 7787-61-3 | 50g | $282 | 2024-03-01 | Buy |
BISMUTH(III) FLUORIDE Chemical Properties,Uses,Production
Chemical Properties
White Crystal or crystalline powder
Physical properties
Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).
Uses
In the preparation of bismuth pentafluoride, q.v.
Uses
Bismuth fluoride is used in the manufacturing of bismuth pentafluoride. It is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography.
Preparation
The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.
reaction suitability
reagent type: catalyst
core: bismuth
BISMUTH(III) FLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 8670 | 58 |
| GLR Innovations | +91 9891111994 | info@glrgroup.in | India | 4535 | 58 |
| LEAP CHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 24727 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18137 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. | +8618950047208 | ellena@amitychem.com | China | 43416 | 58 |