4'-Hydroxy-3'-methoxypropiophenone
- CAS No.
- 1835-14-9
- Chemical Name:
- 4'-Hydroxy-3'-methoxypropiophenone
- Synonyms
- Propioguaiacone;PROPIOVANILLONE;Eugenol Impurity 21;4-HYDROXY-3-METHOXYPROPIOPHENONE;3-METHOXY-4-HYDROXYPROPIOPHENONE;4'-hydroxy-3'-methoxypropiophenone;Propiophenone, 4'-hydroxy-3'-methoxy;1-(4-hydroxy-3-methoxyphenyl)-1-propanone;1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)-;1-(4-HYDROXY-3-METHOXY-PHENYL)-PROPAN-1-ONE
- CBNumber:
- CB3205110
- Molecular Formula:
- C10H12O3
- Molecular Weight:
- 180.2
- MDL Number:
- MFCD00482070
- MOL File:
- 1835-14-9.mol
- MSDS File:
- SDS
Melting point | 61-62 °C |
---|---|
Boiling point | 180-185 °C(Press: 15 Torr) |
Density | 1.126±0.06 g/cm3(Predicted) |
storage temp. | Sealed in dry,Room Temperature |
solubility | DMSO (Slightly), Methanol (Slightly) |
form | Solid |
pka | 8.92±0.31(Predicted) |
color | White to Dark Beige |
LogP | 2.020 (est) |
CAS DataBase Reference | 1835-14-9(CAS DataBase Reference) |
FDA UNII | B6B3PL2HRF |
NIST Chemistry Reference | 1-(4-hydroxy-3-methoxyphenyl)propanone(1835-14-9) |
EPA Substance Registry System | 1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)- (1835-14-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS09,GHS06 |
---|---|
Signal word | Danger |
Hazard statements | H411-H301 |
Precautionary statements | P264-P270-P301+P310-P321-P330-P405-P501 |
Hazard Codes | T,N |
Risk Statements | 25-51/53 |
Safety Statements | 45-61 |
HS Code | 2914500090 |
4'-Hydroxy-3'-methoxypropiophenone price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | H947600 | 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone | 1835-14-9 | 50mg | $185 | 2021-12-16 | Buy |
Matrix Scientific | 126754 | 1-(4-Hydroxy-3-methoxyphenyl)propan-1-one >95% | 1835-14-9 | 1g | $252 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | APN0000263 | 4-HYDROXY-3-METHOXYPROPIOPHENONE 95.00% | 1835-14-9 | 1G | $278.25 | 2021-12-16 | Buy |
AK Scientific | Q284 | 3-Methoxy-4-hydroxypropiophenone | 1835-14-9 | 250mg | $118 | 2021-12-16 | Buy |
Medical Isotopes, Inc. | 95813 | 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone | 1835-14-9 | 10mg | $450 | 2021-12-16 | Buy |
4'-Hydroxy-3'-methoxypropiophenone Chemical Properties,Uses,Production
Uses
1-(4-Hydroxy-3-methoxyphenyl)-1-propanone is a derivative of Guaiacol, a precursor to various flavorants, such as eugenol and vanillin.
Preparation
Preparation by Fries rearrangement of 2-methoxyphenyl propionate, (b.p.20 140–143°)
with aluminium chloride in nitrobenzene, first at 60–80° for 1 h, then at r.t. overnight, at 60° for 1 h or at 50° for 5 h (44%) ;
with aluminium chloride (2 mol) in nitromethane at r.t. for 24 h (65%)
with aluminium chloride in carbon disulfide
with titanium tetrachloride (2 mol) in nitromethane at r.t. for 24 h (62%)
with stannic chloride (2 mol) in nitromethane at r.t. for 24 h (69%)
with antimony pentachloride (2 mol) in nitromethane at r.t. for 24 h (28%) with formation of important tars.
Synthesis Reference(s)
The Journal of Organic Chemistry, 15, p. 227, 1950 DOI: 10.1021/jo01148a001
4'-Hydroxy-3'-methoxypropiophenone Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10828 | 58 |
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 13854 | 58 |
CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 20356 | 58 |
Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4226 | 58 |
changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9821 | 58 |
View Lastest Price from 4'-Hydroxy-3'-methoxypropiophenone manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2019-08-30 | 4'-Hydroxy-3'-methoxypropiophenone
1835-14-9
|
US $1.00 / KG | 1KG | 98% | 200kg | Career Henan Chemical Co |
- 4'-Hydroxy-3'-methoxypropiophenone
1835-14-9
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
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