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Bismuth trichloride

Bismuth trichloride structure

CAS No.: 7787-60-2

Chemical Name:: Bismuth trichloride

Synonyms: BiCl3;BISMUTH(III) CHLORIDE;BISMUTH CHLORIDE;Trichlorobismuthane;Trichlorobismuth;Bismuth(III) chL;BISMUTH TRICHLORIDE;BISMUTH(+3)CHLORIDE;Bismuth(Ⅲ) chloride;trichloro-bismuthin

CBNumber:: CB3205675

Molecular Formula:: BiCl3

Molecular Weight:: 315.34

MDL Number:: MFCD00003461

MOL File:: 7787-60-2.mol

MSDS File:: SDS

Last updated:2023-12-21 17:48:05

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Bismuth trichloride Properties

Melting point	230-232 °C(lit.)
Boiling point	447 °C(lit.)
Density	4.75
Flash point	430°C
storage temp.	no restrictions.
solubility	Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
form	powder
color	White to beige or gray
Specific Gravity	4.75
Odor	Hydrochloric acid odor
Water Solubility	decomposes
Sensitive	Hygroscopic
Sublimation	430 ºC
Merck	14,1262
Stability	Stable, but reacts with water, moisture.
InChIKey	JHXKRIRFYBPWGE-UHFFFAOYSA-K
CAS DataBase Reference	7787-60-2(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	4X6566U3SD
NIST Chemistry Reference	Bismuth trichloride(7787-60-2)
EPA Substance Registry System	Bismuthine, trichloro- (7787-60-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313

Hazard Codes

Risk Statements

36/38-36/37/38

Safety Statements

26-36-37/39

RIDADR

3260

WGK Germany

RTECS

EB2690000

TSCA

Yes

HS Code

2827 39 85

HazardClass

PackingGroup

III

Toxicity

LD50 orally in Rabbit: 3334 mg/kg

NFPA 704

	0
2		1

Bismuth trichloride price More Price(76)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	224839	Bismuth(III) chloride reagent grade, ≥98%	7787-60-2	25g	$118	2024-03-01	Buy
Sigma-Aldrich	224839	Bismuth(III) chloride reagent grade, ≥98%	7787-60-2	100g	$340	2024-03-01	Buy
Sigma-Aldrich	1.12403	Bismuth(III) chloride 98+	7787-60-2	100g	$329	2024-03-01	Buy
TCI Chemical	B3546	Bismuth(III) Chloride Anhydrous >97.0%(T)	7787-60-2	25g	$50	2024-03-01	Buy
TCI Chemical	B3546	Bismuth(III) Chloride Anhydrous >97.0%(T)	7787-60-2	250g	$194	2024-03-01	Buy

Product number	Packaging	Price	Buy
224839	25g	$118	Buy
224839	100g	$340	Buy
1.12403	100g	$329	Buy
B3546	25g	$50	Buy
B3546	250g	$194	Buy

Bismuth trichloride Chemical Properties,Uses,Production

Chemical Properties

Bismuth trichloride is white crystal and crystalline powder

Physical properties

Yellowish-white crystalline solid; cubic crystals; hygroscopic; density 4.75g/cm³; melts at 230°C; vaporizes at 447°C; vapor pressure 5 torr at 242°C; reacts with water; soluble in acids, alcohol and acetone.

Uses

Bismuth chloride (Bi³⁺ + 3Cl^1- → BiCl3) reacts with water to produce what is known as “bismuth white” pigment.

Uses

In the manufacture of other bismuth salts; as catalyst for organic reactions.

Uses

Bismuth trichloride used as catalyst for organic reactions.

Definition

Bismuth trichloride is a white deliquescent solid. It can be prepared by direct combination of bismuth and chlorine. Bismuth(III) chloride dissolves in excess dilute hydrochloric acid to form a clear liquid, but if diluted it produces a white precipitate of bismuth(III) chloride oxide (bismuthyl chloride, BiOCl): BiCl₃+ H₂O = BiOCl + 2HCl This reaction is often used as an exam ple of a reversible reaction and as a confirmatory test for bismuth during quantitative analysis. Bismuth(V) chloride does not form.

Preparation

Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:
Bi(OH)₂Cl + 2HCl → BiCl₃ + 2H₂O
Also, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:
2Bi + 6HCl → 2BiCl₃ + 3H₂.

General Description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

Purification Methods

Sublime the trichloride under high vacuum, or dry it under a current of HCl gas, followed by fractional distillation, once under HCl and once under argon. It is deliquescent. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 621 1963.]

Bismuth trichloride synthesis

Synthesis of Bismuth trichloride from Hydrochloric acid and Bismuth trioxide

Bismuth trichloride Preparation Products And Raw materials

Raw materials

bismuth oxyperchlorate monohydrate Bismuth trioxide Bismuth Iodine monochloride Pyridine hydrochloride

Thionyl chloride

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Preparation Products

4-METHYL-2-OXO-2 H-CHROMENE-7-CARBALDEHYDE CHLOROETHANE Triphenylbismuth 7-BROMOMETHYL-4-METHYL-CHROMEN-2-ONE 4,7-DIMETHYLCOUMARIN

Selenium

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Bismuth trichloride Suppliers

Global( 410)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Zheyan Biotech Co., Ltd.	18017610038	zheyansh@163.com	CHINA	3620	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
City Chemical LLC	2039322489	sales@citychemical.com	United States	168	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Shandong chuangyingchemical Co., Ltd.	18853181302	sale@chuangyingchem.com	CHINA	5909	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Yanxi Chemical Co., Ltd.	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Zheyan Biotech Co., Ltd.	58
career henan chemical co	58
City Chemical LLC	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
Hubei xin bonus chemical co. LTD	58
Shandong chuangyingchemical Co., Ltd.	58

View Lastest Price from Bismuth trichloride manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-21	Bismuth trichloride 7787-60-2	US $0.00-0.00 / kg	1kg	0.99	50000kg	Hebei Kingfiner Technology Development Co. , Ltd.
2023-10-21	Bismuth trichloride 7787-60-2	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-06	Bismuth chloride 7787-60-2	US $1.00 / kg	1kg	99%	20tons	Hebei Yanxi Chemical Co., Ltd.

Bismuth trichloride
7787-60-2
US $0.00-0.00 / kg
0.99
Hebei Kingfiner Technology Development Co. , Ltd.

Bismuth trichloride
7787-60-2
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Bismuth chloride
7787-60-2
US $1.00 / kg
99%
Hebei Yanxi Chemical Co., Ltd.

Bismuth trichloride Spectrum

Bismuth trichloride(7787-60-2)IR1

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