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1-Bromohexadecane

CAS No.
112-82-3
Chemical Name:
1-Bromohexadecane
Synonyms
CETYL BROMIDE;1-Bromhexadecan;BROMOHEXADECANE;Hexadecylbromid;Palmitylbromide;1-BROMOHEXADECANE;HEXADECYL BROMIDE;1-bromo-hexadecan;1-HEXADECYL BROMIDE;N-HEXADECYL BROMIDE
CBNumber:
CB3211988
Molecular Formula:
C16H33Br
Molecular Weight:
305.34
MDL Number:
MFCD00000230
MOL File:
112-82-3.mol
MSDS File:
SDS
Last updated:2023-12-25 13:23:17

1-Bromohexadecane Properties

Melting point 16-18 °C(lit.)
Boiling point 190 °C11 mm Hg(lit.)
Density 0.999 g/mL at 25 °C(lit.)
vapor density 10.6 (vs air)
vapor pressure <1 mm Hg ( 20 °C)
refractive index n20/D 1.4609(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Difficult to mix.
form Liquid After Melting
color Clear amber to brown-black
Specific Gravity 1.000 (20/4℃)
Water Solubility INSOLUBLE
BRN 773989
Dielectric constant 3.71
Stability Stable. Incompatible with strong oxidizing agents. Combustible.
InChIKey HNTGIJLWHDPAFN-UHFFFAOYSA-N
LogP 8.54
CAS DataBase Reference 112-82-3(CAS DataBase Reference)
FDA UNII 76GJI7GVAM
NIST Chemistry Reference Hexadecane, 1-bromo-(112-82-3)
EPA Substance Registry System Hexadecane, 1-bromo- (112-82-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315
Precautionary statements  P302+P352
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
TSCA  Yes
HS Code  29033036
NFPA 704
0
0 0

1-Bromohexadecane price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 234451 1-Bromohexadecane 97% 112-82-3 100g $46.4 2024-03-01 Buy
TCI Chemical B0599 1-Bromohexadecane >96.0%(GC) 112-82-3 25g $17 2024-03-01 Buy
TCI Chemical B0599 1-Bromohexadecane >96.0%(GC) 112-82-3 100g $34 2024-03-01 Buy
Alfa Aesar A15147 1-Bromohexadecane, 98% 112-82-3 25g $20.65 2024-03-01 Buy
Alfa Aesar A15147 1-Bromohexadecane, 98% 112-82-3 250g $62.2 2024-03-01 Buy
Product number Packaging Price Buy
234451 100g $46.4 Buy
B0599 25g $17 Buy
B0599 100g $34 Buy
A15147 25g $20.65 Buy
A15147 250g $62.2 Buy

1-Bromohexadecane Chemical Properties,Uses,Production

Chemical Properties

colourless to yellow liquid or solid.soluble in ether, alcohol, insoluble in water.

Uses

1-Bromohexadecane is used in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains. It is also used to synthesize [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents.

Uses

1-Bromohexadecane has been used:
in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains
as extraction solvent in determination of endocrine-disrupting phenols (EDPs) in water samples by ultrasound-assisted emulsification microextraction (MS-USAEME) method
in the preparation of [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents
in the synthesis of surfactant, N-hexadecyl ethylenediamine triacetic acid (HED3A)

Preparation

Synthesis of 1-Bromohexadecane from hexadecanol by bromination: put hexadecanol into the reaction pot and stir, heat, melt and put in red phosphorus. Add bromine drop by drop at 100℃ with sufficient stirring on one side, control 120-130℃, about 6h drop by drop, continue the reaction and drain the hydrogen bromide. Cool to below 50 ℃, add saturated and sodium chloride, stirring and washing, resting stratification, parting off the lower waste stream, then wash with water to neutral, distillation, collect 220-230 ℃ (2kPa) fraction, to obtain 1-bromohexadecane.

Purification Methods

Shake the bromide with H2SO4, wash with H2O, dry with K2CO3 and fractionally distil it in vacuo.[Beilstein 1 IV 542.]

36653-82-4
112-82-3
Synthesis of 1-Bromohexadecane from 1-Hexadecanol
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View Lastest Price from 1-Bromohexadecane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Bromohexadecane pictures 2024-04-25 1-Bromohexadecane
112-82-3
US $0.00 / KG 1KG 99% 500mt/year Jinan Finer Chemical Co., Ltd
1-Bromohexadecane pictures 2023-12-26 1-Bromohexadecane
112-82-3
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1-Bromohexadecane pictures 2023-10-14 1-Bromohexadecane
112-82-3
US $0.00 / kg 1kg 0.98 20tons Hebei Yanxi Chemical Co., Ltd.
1-BROMOHEXADECANE 1-HEXADECYL BROMIDE 1-Bromhexadecan 1-bromo-hexadecan HEXADECYL BROMIDE N-HEXADECYL BROMIDE N-HEXADECYL BROMIDE (CETYL) 1-BROMOHEXADECANE pure BROMOHEXADECANE Cetyl bromide, Hexadecyl bromide 1-Bromohexadecane,97% 1-Bromohexadecane,99% 1-Bromohexadecane ,98% 1-BroMohexadecane, 97% 250ML 1-BROMOHEXADECANE FOR SYNTHESIS 1-Bromohexadecane 〔Cetyl Bromide〕 BroMine generation cetane Hexadecane,1-bromo- Hexadecylbromid n-Hexadecyl-1-bromide Palmitylbromide 1-Bromohexadecane > 1-Bromohexadecane ISO 9001:2015 REACH High purity CAS 112-82-3 1-Bromohexadecane in stock CETYL BROMIDE 112-82-3 101-37-5 CH3CH215Br BrCH2CH214CH3 112823 C16H33Br CH3CH214CH2Br Alkyl Building Blocks Organic Building Blocks Halogenated Hydrocarbons Monofunctional & 伪,蠅-Bifunctional Alkanes Alkyl Bromides Monofunctional Alkanes Pharmaceutical Intermediates Alkyl Bromides Monofunctional & alpha,omega-Bifunctional Alkanes Monofunctional Alkanes