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MEPANIPYRIM

CAS No.
110235-47-7
Chemical Name:
MEPANIPYRIM
Synonyms
FRUPICA;MEPANIPYRIM;Mepanioyrim;mepanipyrin;Mepanipyrim 50;Mepanipyrim-D5;Mepanipyrim [iso];MEPANIPYRIM STANDARD;Mepanipyrim@100 μg/mL in AcCN;mepanipyrim (bsi, draft e-iso)
CBNumber:
CB3230301
Molecular Formula:
C14H13N3
Molecular Weight:
223.27
MDL Number:
MFCD01656050
MOL File:
110235-47-7.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:05

MEPANIPYRIM Properties

Melting point 125-126° (Maeno); also reported as 132.8° (Hayashi)
Boiling point 418.2±47.0 °C(Predicted)
Density 1.16±0.1 g/cm3(Predicted)
vapor pressure 2.32 x l0-5 Pa (20 °C)
Flash point 131 °C
storage temp. 0-6°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka 4.5 (est. base)
Water Solubility 3.1 mg l-1(20 °C)
color White to Off-White
LogP 3.280
EWG's Food Scores 2
FDA UNII B150X76OJY
Proposition 65 List Mepanipyrim
Pesticides Freedom of Information Act (FOIA) Mepanipyrim
EPA Substance Registry System Mepanipyrim (110235-47-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS08,GHS09
Signal word  Warning
Hazard statements  H351-H410
Precautionary statements  P202-P273-P280-P308+P313-P391-P405
Hazard Codes  N,Xn
Risk Statements  51/53-50/53-40
Safety Statements  60-61-46-36/37
RIDADR  UN3077 9/PG 3
WGK Germany  2
RTECS  UV6261540
Toxicity LD50 in mice, rats, bobwhite, mallard (mg/kg): >5000, >5000, >2250, >2250 orally; in rats (mg/kg): >2000 dermally; LC50 in bluegill, rainbow trout (mg/l): 3.8, 3.1 (Maeno)

MEPANIPYRIM price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 33970 Mepanipyrim PESTANAL 110235-47-7 50mg $141 2024-03-01 Buy
TRC M223600 Mepanipyrim 110235-47-7 100mg $650 2021-12-16 Buy
American Custom Chemicals Corporation AGR0000782 MEPANIPYRIM 95.00% 110235-47-7 100MG $329.7 2021-12-16 Buy
Medical Isotopes, Inc. 41258 Mepanipyrim 110235-47-7 1g $2200 2021-12-16 Buy
Labseeker SC-67415 mepanipirim 95 110235-47-7 50mg $583 2021-12-16 Buy
Product number Packaging Price Buy
33970 50mg $141 Buy
M223600 100mg $650 Buy
AGR0000782 100MG $329.7 Buy
41258 1g $2200 Buy
SC-67415 50mg $583 Buy

MEPANIPYRIM Chemical Properties,Uses,Production

Uses

Mepanipyrim is a non-systemic fungicide that provides preventative control of diseases in pome fruits (scab), vines, strawberries, tomatoes and cucumbers (grey mould) and peaches (brown rots) caused by Botrytis cinerea, Venturia inaequaris and Monilinia fructicola.

Uses

Agricultural fungicide.

Uses

Mepanipyrim is an anilinopyrimidine fungicide which have been used in the management of fungal diseases in strawberries.

Definition

ChEBI: A member of the class of aminopyrimidines that is N-phenylpyrimidin-2-amine carrying additional methyl and 1-propynyl substituents at positions 4 and 6 respectively. A fungicide used to control a wide range of diseases including grey mou d on strawberries, tomatoes and cucumabers, and scab on apples and pears.

Metabolic pathway

By tomato seedlings, 14C-mepanipyrim is biotransformed via the pathways including elimination of the phenyl group, hydroxylation of the propynyl moiety, and hydroxylation at the phenyl ring to yield several kinds of metabolite, and 2- and 4-[4-methyl-6- (1-propynyl)pyrimidin-2-ylamino]phenols, 1-(2-anilino-6- methylpyrimidin-4-yl)-2-propanol, and 4-methyl-6-(1- propynyl)pyrimidin-2-ylamine are tentatively identified as major metabolites. In soils under laboratory conditions, 14C-mepanipyrim undergoes degradation to give the degradation products and the main pathway is elimination of the phenyl group.

Degradation

Mepanipyrim (1) is stable to hydrolytic degradation in the pH range 4-9 with a DT50 >1 year. It decomposed rapidly in water when exposed to light (DT50 13 days) (PM).

6967-54-0
74-99-7
110235-47-7
Synthesis of MEPANIPYRIM from 2-Anilino-4-chloro-6-methylpyrimidine and Propyne

MEPANIPYRIM Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 76)Suppliers
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Amadis Chemical Company Limited
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4-methyl-n-phenyl-6-(1-propynyl)-2-pyrimidinamin MEPANIPYRIM FRUPICA 4-METHYL-N-PHENYL-6-(1-PROPYNYL)-2-PYRIMIDINAMINE mepanipyrim (bsi, draft e-iso) MEPANIPYRIM STANDARD N-(4-Methyl-6-prop-1-ynylpyrimidin-2-yl)-aniline 4-methyl-N-phenyl-6-(prop-1-ynyl)pyrimidin-2-amine Mepanioyrim 2-Pyrimidinamine, 4-methyl-N-phenyl-6-(1-propynyl)- Mepanipyrim [iso] N-(4-Methyl-6-prop-1-ynylpyrimidin-2-yl)aniline (iupac) Mepanipyrim 50 mepanipyrin N-(4-methyl-6prop-1-ynylpyrimidin-2-yl)anikine 4-Methyl-N-phenyl-6-(prop-1-yn-1-yl)pyriMidin-2-aMine Mepanipyrim-D5 MepanipyrimSolution,100mg/L,1ml Mepanipyrim@100 μg/mL in AcCN Mepanipyrim@1000 μg/mL in Acetonitrile MepanipyrimSolution,1,000mg/L,1ml 2-Pyrimidinamine, 4-methyl-N-phenyl-6-(1-propyn-1-yl)- 110235-47-7