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Allyltributyltin

Allyltributyltin structure

CAS No.: 24850-33-7

Chemical Name:: Allyltributyltin

Synonyms: ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;allyitri－n－butyltin

CBNumber:: CB3257937

Molecular Formula:: C15H32Sn

Molecular Weight:: 331.12

MDL Number:: MFCD00010346

MOL File:: 24850-33-7.mol

Last updated:2023-05-15 10:43:51

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Allyltributyltin Properties

Melting point	134-135 °C
Boiling point	88-92 °C0.2 mm Hg(lit.)
Density	1.068 g/mL at 25 °C(lit.)
refractive index	n20/D 1.486(lit.)
Flash point	>230 °F
storage temp.	2-8°C
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Liquid
color	Clear colorless
Specific Gravity	1.068
Water Solubility	Immiscible with water.
Sensitive	Air Sensitive
Hydrolytic Sensitivity	1: no significant reaction with aqueous systems
BRN	3588340
Exposure limits	ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability	Air Sensitive
InChIKey	YLGRTLMDMVAFNI-UHFFFAOYSA-N
CAS DataBase Reference	24850-33-7(CAS DataBase Reference)
FDA UNII	AOR8OD4103
NIST Chemistry Reference	Allyltributyltin(24850-33-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08,GHS09

Signal word

Danger

Hazard statements

H301-H312-H315-H319-H360FD-H372-H410

Precautionary statements

P201-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338

Hazard Codes

T,N

Risk Statements

21-25-36/38-48/23/25-50/53-23/24/25

Safety Statements

35-36/37/39-45-60-61-28-27-26

RIDADR

UN 2788 6.1/PG 2

WGK Germany

TSCA

HazardClass

6.1

PackingGroup

HS Code

29319019

NFPA 704

	0
3		0

Allyltributyltin price More Price(22)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	271411	Allyltributylstannane 97%	24850-33-7	5g	$62.7	2024-03-01	Buy
Sigma-Aldrich	271411	Allyltributylstannane 97%	24850-33-7	25g	$136	2024-03-01	Buy
Alfa Aesar	L14087	Allyltri-n-butyltin, 97%	24850-33-7	5g	$39.6	2023-06-20	Buy
Alfa Aesar	L14087	Allyltri-n-butyltin, 97%	24850-33-7	25g	$136	2023-06-20	Buy
Sigma-Aldrich	271411	Allyltributylstannane 97%	24850-33-7	100g	$290	2024-03-01	Buy

Product number	Packaging	Price	Buy
271411	5g	$62.7	Buy
271411	25g	$136	Buy
L14087	5g	$39.6	Buy
L14087	25g	$136	Buy
271411	100g	$290	Buy

Allyltributyltin Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Purification Methods

A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]

Allyltributyltin synthesis

Synthesis of Allyltributyltin from Tributyltin hydroxide and Allyl bromide

Allyltributyltin Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 2-methyl-4-pentenoate 3-(4-TERT-BUTYLPHENYL)-1-PROPENE TRI-N-BUTYLTIN METHOXIDE Benzenamine, 4-(2-propen-1-yl)- N-Benzyl-N-(but-3-en-1-yl)but-3-en-1-aMine

3-(4-METHOXY-2-METHYLPHENYL)-1-PROPENE 3-(3-CYANO-4-FLUOROPHENYL)-1-PROPENE

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Allyltributyltin Suppliers

Global( 212)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Nanjing Kaitian Chemical Co., LTD	+undefined13337835376	kt_chem@126.com	China	40	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	906	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10297	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58

Supplier	Advantage
Nanjing Kaitian Chemical Co., LTD	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Arbor Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from Allyltributyltin manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-04-11	Allyltributyltin 24850-33-7	US $0.00-0.00 / kg	1kg	98%	1 ton	Nanjing Kaitian Chemical Co., LTD
	2020-01-09	Allyltributyltin 24850-33-7	US $6.68 / KG	1KG	97%-99%	1kg-1000kg	Career Henan Chemical Co

Allyltributyltin
24850-33-7
US $0.00-0.00 / kg
98%
Nanjing Kaitian Chemical Co., LTD

Allyltributyltin
24850-33-7
US $6.68 / KG
97%-99%
Career Henan Chemical Co

Allyltributyltin Spectrum

Allyltributyltin(24850-33-7)MS Allyltributyltin(24850-33-7)¹HNMR Allyltributyltin(24850-33-7)¹³CNMR Allyltributyltin(24850-33-7)IR1 Allyltributyltin(24850-33-7)Raman

24850-33-7(Allyltributyltin)Related Search:

Allyl chloride Tributyltin chloride Diallylamine Allyl bromide Sodium allylsulfonate

Allyl glycidyl ether ALLYLOXY-T-BUTYLDIMETHYLSILANE ALLYLOXYTRIMETHYLSILANE POTASSIUM ALLYLTRIFLUOROBORATE Allyl methyl sulfide

Allyltrimethylsilane allyltrimethylammonium chloride Allyltriphenylphosphonium bromide 3-Allyloxy-2-Hydroxy-1-Propane,Sodium Salt Allyltrimethoxysilane

ALLYLTRIS(TRIMETHYLSILOXY)SILANE ALLYLTRIISOPROPYLSILANE ALLYLTRIETHOXYSILANE

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Stannane, tributyl-2-propenyl- ALLYLTRIBUTYLTIN ALLYLTRIBUTYLTIN(IV) Allytri-N-Butyltin Allyltri-n-butyltin,97% (2-Propenyl)tributylstannane Allyltributyltin,97% Allyltributyltin(Ⅳ) allyitri－n－butyltin tri-n-butyl-2-propenylstannane Allyltributylstannane 97% The threebutyltinpropenyl Allyltributyltin, 97% 1GR (Prop-2-en-1-yl)tributyl stannane, 3-(Tributylstannyl)prop-1-ene 3-(Tributylstannyl)prop-1-ene Stannane, tributyl-2-propen-1-yl- Allyltributyltin ISO 9001：2015 REACH SKL1093 tributyl(prop-2-enyl)stannane ALLYLTRIBUTYLSTANNANE ALLYLTRI-N-BUTYLTIN TRIBUTYL-2-PROPENYLSTANNANE 2-Propenyltributylstannane Tributylallylstannane allyltri-n-butylstannane ributyl(prop-2-enyl)stannane Allyl Tri n-butyl tin /stannane 24850-33-7 CH2CHCH2SnCH2CH2CH2CH33 Classes of Metal Compounds Alkyl Metals Sn (Tin) Compounds Typical Metal Compounds Grignard Reagents & Alkyl Metals Organotin Organotins Organometallic Reagents Organotins Stannanes Chemical Synthesis Organometallic Reagents Alkyl Metals Sn (Tin) Compounds Classes of Metal Compounds Grignard Reagents & Alkyl Metals Synthetic Organic Chemistry Typical Metal Compounds Organometallic Reagents Organotin