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[(S,S)-Teth-TsDpen RuCl]

CAS No.
851051-43-9
Chemical Name:
[(S,S)-Teth-TsDpen RuCl]
Synonyms
[(S,S)-Teth-TsDpen RuCl];[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%;(S,S)-TETH-TSDPEN RUCL WILLS CATALYST;chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride;Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium;{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II);Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS
CBNumber:
CB32620041
Molecular Formula:
C30H25ClN2O2RuS
Molecular Weight:
614.12
MDL Number:
MFCD16294984
MOL File:
851051-43-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

[(S,S)-Teth-TsDpen RuCl] Properties

Melting point 260-268℃
storage temp. 2-8°C
form Powder
color orange
optical activity [α]22/D +339°, c = 0.5% in chloroform
Sensitive Air & Moisture Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
WGK Germany  3

[(S,S)-Teth-TsDpen RuCl] price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 752800 [(S,S)-Teth-TsDpen RuCl] 851051-43-9 100mg $77.4 2024-03-01 Buy
Sigma-Aldrich 752800 [(S,S)-Teth-TsDpen RuCl] 851051-43-9 500mg $276 2024-03-01 Buy
Strem Chemicals 44-0110 {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST 851051-43-9 100mg $97 2024-03-01 Buy
Strem Chemicals 44-0110 {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST 851051-43-9 500mg $235 2024-03-01 Buy
TRC C378025 Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]rutheniumStereoisomerC30H31ClN2O2RuS 851051-43-9 1g $760 2021-12-16 Buy
Product number Packaging Price Buy
752800 100mg $77.4 Buy
752800 500mg $276 Buy
44-0110 100mg $97 Buy
44-0110 500mg $235 Buy
C378025 1g $760 Buy

[(S,S)-Teth-TsDpen RuCl] Chemical Properties,Uses,Production

Uses

Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS is a catalyst for Asymmetric Transfer Hydrogenations of Ketones.

Uses

Catalyst for the asymmetric transfer hydrogenation of ketones

Uses

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

  • In the reduction of a ketone intermediate for the synthesis of esketamine.
  • In asymmetric hydrogenation of acetylenic ketones.
  • For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

Reactions

Catalyst used for asymmetric -transfer hydrogenation.
Reactions of 851051-43-9

[(S,S)-Teth-TsDpen RuCl] Preparation Products And Raw materials

Raw materials

Preparation Products

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Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
[(S,S)-Teth-TsDPEN-RuCl], Ru 16.3% {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN -ethyl-2-aMino-(kN)]}rutheniuM(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST [(S,S)-Teth-TsDpen RuCl] (S,S)-TETH-TSDPEN RUCL WILLS CATALYST {N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino- 6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS 6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino- {N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN)-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST/{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II) N-[(1S,2S)-1,2-Diphenyl-2-[(3-phenylpropyl)amino]ethyl]-4-methylphenylsulfonamido]ruthenium(II) Chloride Chloro[N-[(1S,2S)-1,2-diphenyl-2-[[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium chloro-[[1,2-diphenyl-2-(3-phenylpropylamino)ethyl]-(p-tolylsulfonyl)amino]ruthenium 851051-43-9 Ru Ru Catalysts Catalysis and Inorganic Chemistry Chemical Synthesis New Products for Chemical Synthesis Organometallic Reagents Ruthenium