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t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3 structure

CAS No.: 1536473-72-9

Chemical Name:: t-BuBrettPhos Palladacycle Gen. 3

Synonyms: P](methane;N)[1,1’-(Amino-κtbuttphos Pd G3;-biphenyl]-2-yl-κC][[3,6-dimethoxy-2’-tris(1-methylethyl)[1,1’t-BuBrettPhos Palladacycle Gen. 3;t-butylBrettPhos Palladacycle Gen. 3;t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH

CBNumber:: CB33052898

Molecular Formula:: C44H63NO5PPdS-

Molecular Weight:: 855.433481

MDL Number:: MFCD25976528

MOL File:: 1536473-72-9.mol

MSDS File:: SDS

Last updated:2024-03-18 16:05:02

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t-BuBrettPhos Palladacycle Gen. 3 Properties

Melting point	119-131°C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	solid
color	brown-green
InChIKey	VKLHIPFGYVFUGT-UHFFFAOYSA-N
CAS DataBase Reference	1536473-72-9

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS08
Signal word	Danger
Hazard statements	H350i
Precautionary statements	P201-P202-P280-P308+P313-P405-P501
WGK Germany	3

t-BuBrettPhos Palladacycle Gen. 3 price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	1536473-72-9	100MG	$81.6	2024-03-01	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	1536473-72-9	500MG	$147	2024-03-01	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	1536473-72-9	1G	$341	2024-03-01	Buy
Sigma-Aldrich	928313	tBuBrettPhos Pd G3 ChemBeads	1536473-72-9	1G	$287	2024-03-01	Buy
Sigma-Aldrich	745979	tBuBrettPhos Pd G3 96%	1536473-72-9	2G	$666	2024-03-01	Buy

Product number	Packaging	Price	Buy
745979	100MG	$81.6	Buy
745979	500MG	$147	Buy
745979	1G	$341	Buy
928313	1G	$287	Buy
745979	2G	$666	Buy

t-BuBrettPhos Palladacycle Gen. 3 Chemical Properties,Uses,Production

Reaction

Palladium catalyst used for the arylation of primary amides.
Palladium catalyst used for the synthesis of N-aryl carbamates.
Palladium catalyst used for the N-monoarylation of amidines.
Palladium catalyst used for the cross-coupling of aryl chlorides and triflates with sodium cyanate – a practical synthesis of unsymmetrical ureas.
Palladium catalyst used in the synthesis of imidazo[4,5-b]pyridines and imidazo[4,5]pyrazines through amidation of 2-chloro-3-amino-heterocycles.
Palladium catalyst used in the N-arylation of 2-aminothiazoles
Palladium catalyst used in the synthesis of diarylethers under mild conditions.
Palladium catalyst used in the hydroxylation of aryl and heteroaryl halides.

Uses

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

General Description

tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

t-BuBrettPhos Palladacycle Gen. 3 Preparation Products And Raw materials

Raw materials

Preparation Products

t-BuBrettPhos Palladacycle Gen. 3 Suppliers

Global( 116)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	407	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Wuhan Pengo Technology.,Ltd.	+86-27-81330736 +86-13628634921	sunny.w@boronicgroup.com	CHINA	171	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-18789408387	1057@dideu.com	China	3537	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Shanghai Time Chemicals CO., Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
Accela ChemBio Inc.	58
Wuhan Pengo Technology.,Ltd.	58
career henan chemical co	58
Shaanxi Dideu Medichem Co. Ltd	58
Jinan Liheng Biotechnology Co., Ltd.	58
Richest Group Ltd	58

View Lastest Price from t-BuBrettPhos Palladacycle Gen. 3 manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-07-25	t-BuBrettPhos Palladacycle Gen. 3 1536473-72-9	US $1.10 / g	1g	99.00%	100 Tons Min	Dideu Industries Group Limited
2021-06-11	Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3 1536473-72-9	US $0.00-0.00 / g	1g	0.98	50KG	Wuhan LPBchem Technology Co.,Ltd
2020-04-22	tBuBrettPhos Pd G3 1536473-72-9	US $1.00 / KG	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd

t-BuBrettPhos Palladacycle Gen. 3
1536473-72-9
US $1.10 / g
99.00%
Dideu Industries Group Limited

Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3
1536473-72-9
US $0.00-0.00 / g
0.98
Wuhan LPBchem Technology Co.,Ltd

tBuBrettPhos Pd G3
1536473-72-9
US $1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

1536473-72-9(t-BuBrettPhos Palladacycle Gen. 3)Related Search:

cataCXium A Pd G3 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3

BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle

Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct

RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1

1of4

Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3] t-BuBrettPhos Palladacycle Gen. 3 Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3] Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen. Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle t-butylBrettPhos Palladacycle Gen. 3 Methanesulfonate[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) tBuBrettPhos Pd G3 Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium -(Amino-&kappa -biphenyl]-2-yl-&kappa C][[3,6-dimethoxy-2&rsquo -biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-&kappa P](methane N)[1,1&rsquo -tris(1-methylethyl)[1,1&rsquo t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium (tBuBrettPhos Pd G3) Methanesulfonato(2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (tBuBrettPhos Pd G3) t-ButylXPhos Pd G4 / Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) tbuttphos Pd G3 methanesulfonato 2-di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii) (2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate ditert-butyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane methylsulfonyloxy-(2-phenylanilino)palladium 1536473-72-9 C44H62NO5PPdS C31H49O2PC13H13NO3PdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd