Methyl 2-furoate
- CAS No.
- 611-13-2
- Chemical Name:
- Methyl 2-furoate
- Synonyms
- METHYL FURAN-2-CARBOXYLATE;2-FURANCARBOXYLIC ACID METHYL ESTER;MEFAT;FEMA 2703;2-METHYLFUROATE;Methyle furoate;METHYL 2-FUROATE;METHYL PYROMUCATE;Methyl 2-furanoate;RARECHEM AL BF 0007
- CBNumber:
- CB3306772
- Molecular Formula:
- C6H6O3
- Molecular Weight:
- 126.11
- MDL Number:
- MFCD00003236
- MOL File:
- 611-13-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Methyl 2-furoate ≥98%, FG | W270318 | 1 each | $55.9 |
| Methyl 2-furoate ≥98%, FG | W270318 | 100g | $77.2 |
| Methyl 2-furoate ≥98%, FG | W270318 | 1kg | $224 |
| Methyl 2-furoate ≥98%, FG | W270318 | 5kg | $508 |
| Methyl 2-furoate 98% | 129852 | 25g | $38.8 |
| More product size | |||
| Boiling point | 181 °C (lit.) |
|---|---|
| Density | 1.179 g/mL at 25 °C (lit.) |
| FLAVIS Number | 13.002 | Methyl 2-furoate |
| FEMA | 2703 | METHYL 2-FUROATE |
| refractive index |
n |
| Flash point | 164 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Liquid |
| color | Clear pale yellow to brown |
| Odor | fruity, mushroom-like odor |
| Odor Type | fungal |
| biological source | synthetic |
| Water Solubility | slightly soluble |
| Sensitive | Lachrymatory |
| Merck | 14,4307 |
| JECFA Number | 746 |
| BRN | 111110 |
| Cosmetics Ingredients Functions | PERFUMING |
| InChI | 1S/C6H6O3/c1-8-6(7)5-3-2-4-9-5/h2-4H,1H3 |
| InChIKey | HDJLSECJEQSPKW-UHFFFAOYSA-N |
| SMILES | COC(=O)c1ccco1 |
| LogP | 0.99 |
| CAS DataBase Reference | 611-13-2(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | METHYL 2-FUROATE |
| FDA UNII | O9A8D29YDE |
| NIST Chemistry Reference | Methyl 2-furoate(611-13-2) |
| EPA Substance Registry System | 2-Furancarboxylic acid, methyl ester (611-13-2) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312-H315-H319-H335 | |||||||||
| Precautionary statements | P280-P301+P310+P330-P302+P352+P312-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 36/37/38-21/22-22 | |||||||||
| Safety Statements | 26-36-36/37/39 | |||||||||
| RIDADR | UN 2810 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | LV1950000 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29321900 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
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| Hazard Classifications | Acute Tox. 3 Oral Acute Tox. 4 Dermal Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
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| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Methyl 2-furoate price More Price(35)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 1 each | $55.9 | 2026-03-19 | Buy |
| Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 100g | $77.2 | 2026-03-19 | Buy |
| Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 1kg | $224 | 2026-03-19 | Buy |
| Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 5kg | $508 | 2026-03-19 | Buy |
| Sigma-Aldrich | 129852 | Methyl 2-furoate 98% | 611-13-2 | 25g | $38.8 | 2026-03-19 | Buy |
Methyl 2-furoate Chemical Properties,Uses,Production
Description
Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).
Chemical Properties
Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy
Chemical Properties
Colorless to light yellow liqui
Occurrence
Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.
Uses
Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.
Uses
Solvent, organic synthesis.
Definition
ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.
Preparation
From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)
Aroma threshold values
Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.
Taste threshold values
Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance
Synthesis Reference(s)
Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225
General Description
Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.
Safety Profile
Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
88-14-2
108-59-8
611-13-2
To a Schlenk tube equipped with a magnetic stirring bar, furoic acid (0.3 mmol), dimethyl malonate (1.8 mmol), KBr (0.09 mmol) and DMF (2 mL) were added sequentially. The reaction mixture was stirred at the set temperature for 12 hours. After the reaction was completed, the mixture was cooled to room temperature. The reaction solution was poured into ethyl acetate, washed with water and extracted with ethyl acetate. The organic phases were combined, dried with anhydrous Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by fast column chromatography (eluent: petroleum ether or mixed solvent of petroleum ether/ethyl acetate) to obtain high purity methyl 2-furoate.
References
[1] Tetrahedron, 2015, vol. 71, # 48, p. 9067 - 9072
Methyl 2-furoate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8738 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8618531123677 | faithe@yan-xi.com | China | 5853 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| Shaanxi Haibo Biotechnology Co., Ltd | +undefined18602966907 | qinhe02@xaltbio.com | China | 997 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3692 | 58 |
| JINING XINHE CHEMICAL CO., LTD | +8615318402391 | sales@xinhepharma.com | China | 809 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21591 | 55 |
| Jiangsu Qingquan Chemical Co., Ltd. | +86-571-86589381,86589382,86589383 | sales1@qqpharm.com | CHINA | 154 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29820 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8615060885618 | sales@amoychem.com | China | 6369 | 58 |
View Lastest Price from Methyl 2-furoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-04-22 | Methyl 2-furoate
611-13-2
|
US $29.00 / mL | 99.85% | 10g | TargetMol Chemicals Inc. | ||
 |
2026-03-20 | Methyl 2-furoate
611-13-2
|
US $10.00 / KG | 1KG | 99% | 5tons | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-12-01 | Methyl 2-furoate
611-13-2
|
US $0.00 / kg | 1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd |
-
- Methyl 2-furoate
611-13-2
- US $29.00 / mL
- 99.85%
- TargetMol Chemicals Inc.
-
- Methyl 2-furoate
611-13-2
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl 2-furoate
611-13-2
- US $0.00 / kg
- 99%
- Shaanxi Dideu New Materials Co. Ltd
