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[Ir{dFCF3ppy}2(bpy)]PF6

[Ir{dFCF3ppy}2(bpy)]PF6 Structure
[Ir{dFCF3ppy}2(bpy)]PF6 structure
CAS No.
1092775-62-6
Chemical Name:
[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms
uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
CBNumber:
CB33150909
Molecular Formula:
C34H18F16IrN4P
Molecular Weight:
1009.6987322
MDL Number:
MOL File:
1092775-62-6.mol
Last updated:2023-04-23 13:52:06
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[Ir{dFCF3ppy}2(bpy)]PF6 Properties

storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

[Ir{dFCF3ppy}2(bpy)]PF6 price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 804215 [Ir{dFCF3ppy}2(bpy)]PF6 1092775-62-6 50mg $96.4 2024-03-01 Buy
Strem Chemicals 77-0220 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 1092775-62-6 50mg $66 2024-03-01 Buy
Strem Chemicals 77-0220 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 1092775-62-6 250mg $262 2024-03-01 Buy
Strem Chemicals 77-0453 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% 1092775-62-6 50mg $73 2024-03-01 Buy
Strem Chemicals 77-0453 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% 1092775-62-6 250mg $294 2024-03-01 Buy
Product number Packaging Price Buy
804215 50mg $96.4 Buy
77-0220 50mg $66 Buy
77-0220 250mg $262 Buy
77-0453 50mg $73 Buy
77-0453 250mg $294 Buy

[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Uses,Production

Reaction

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
Reactions of 1092775-62-6_1
Reactions of 1092775-62-6_2

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

Global( 58)Suppliers
Supplier Tel Email Country ProdList Advantage
Career Henan Chemica Co 		+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Hunan russell chemicals technology co ltd 		731-88557738 +8613739093081 sales01@russellchem.com CHINA 291 58
Alfa Chemistry 		+1-5166625404 Info@alfa-chemistry.com United States 21317 58
LEAP CHEM CO., LTD. 		+86-852-30606658 market18@leapchem.com China 24738 58
Suzhou Origin Specialty Chemicals Co., Ltd. 		+86-512-68662322 +86-17312436797 hanqun@origsc.com China 788 58
Xian confluore Biological Technology Co., Ltd. 		+86-15680926068 +86-15680926068 1924344760@confluore.cn China 2996 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7639 55
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6854 65
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28398 80
Supplier Advantage
Career Henan Chemica Co 		58
Hunan russell chemicals technology co ltd 		58
Alfa Chemistry 		58
LEAP CHEM CO., LTD. 		58
Suzhou Origin Specialty Chemicals Co., Ltd. 		58
Xian confluore Biological Technology Co., Ltd. 		58
Aladdin Scientific 		58
BeiJing Hwrk Chemicals Limted 55
Daicel Chiral Technologies (China)CO.,LTD 65
TOKYO CHEMICAL INDUSTRY CO., LTD. 80

View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Ir[dFCF3ppy]2(bpy))PF6 pictures 2024-04-02 (Ir[dFCF3ppy]2(bpy))PF6
1092775-62-6
 US $0.00 / g 1g >99.00% 1g Xian confluore Biological Technology Co., Ltd.

1092775-62-6([Ir{dFCF3ppy}2(bpy)]PF6)Related Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium
[2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3
(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6
hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

1of4

[Ir{dFCF3ppy}2(bpy)]PF6 Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine 2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate uoro-2-[5-trifL (2,2'-Bipyridine)bis[3,5-difL Ir[dF(CF3)2ppy]2(bpy)]PF6 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate (2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate 1092775-62-6 C34H18F16IrN4P