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Methyl 2-methyl-3-nitrobenzoate

CAS No.
59382-59-1
Chemical Name:
Methyl 2-methyl-3-nitrobenzoate
Synonyms
DK835;Methyl 2-methyl-3-;Lenalidoide Ipurity 23;METHYL 3-NITRO-O-TOLUATE;2-Methyl-3-nitrobenzoate;METHYL 2-METHYL-3-NITROBENZOATE;Methyl 3-nitro-2-methylbenzoate;Methyl 2-Methyl-3-Nitro-Benzoatee;Methyl2-Methyl-3-nitrobenzoate>3-NITRO-0-TOLUIC ACID METHYL ESTER
CBNumber:
CB3328974
Molecular Formula:
C9H9NO4
Molecular Weight:
195.17
MDL Number:
MFCD00082564
MOL File:
59382-59-1.mol
MSDS File:
SDS
Last updated:2024-03-26 15:22:20

Methyl 2-methyl-3-nitrobenzoate Properties

Melting point 62-65 °C (lit.)
Boiling point 286.6±20.0 °C(Predicted)
Density 1?+-.0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Soluble in methanol.
form Solid
color Pale Beige
BRN 1964020
CAS DataBase Reference 59382-59-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315-H335
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Safety Statements  24/25
WGK Germany  3
HS Code  29163990
NFPA 704
1
0 0

Methyl 2-methyl-3-nitrobenzoate price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 366765 Methyl 2-methyl-3-nitrobenzoate 97% 59382-59-1 25g $71.8 2024-03-01 Buy
TCI Chemical M2144 Methyl 2-Methyl-3-nitrobenzoate >98.0%(GC) 59382-59-1 5g $21 2024-03-01 Buy
TCI Chemical M2144 Methyl 2-Methyl-3-nitrobenzoate >98.0%(GC) 59382-59-1 25g $42 2024-03-01 Buy
Alfa Aesar H60242 Methyl 2-methyl-3-nitrobenzoate, 97% 59382-59-1 5g $34.65 2024-03-01 Buy
Alfa Aesar H60242 Methyl 2-methyl-3-nitrobenzoate, 97% 59382-59-1 25g $129.65 2024-03-01 Buy
Product number Packaging Price Buy
366765 25g $71.8 Buy
M2144 5g $21 Buy
M2144 25g $42 Buy
H60242 5g $34.65 Buy
H60242 25g $129.65 Buy

Methyl 2-methyl-3-nitrobenzoate Chemical Properties,Uses,Production

Description

Methyl 2-methyl-3-nitrobenzoate is an important organic synthetic material and pharmaceutical intermediate compound. It can be used for the preparation of the anticancer drug lenalidomide as well as other organic compounds (e.g., indole-4-carboxylic acid methyl ester, 5-nitroisocoumarin, 5-aminoisoquinolin-1(2H)-one, etc.).

Chemical Properties

White crystalline powder

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of:

  • methyl indole-4-carboxylate
  • 5-aminoisoquinolin-1(2H)-one
  • 5-nitroisocoumarin
  • substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
  • 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
  • [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.

Solubility in organics

Soluble in methanol.

Global( 288)Suppliers
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Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
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ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
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Chongqing Chemdad Co., Ltd
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10828 58

View Lastest Price from Methyl 2-methyl-3-nitrobenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 2-methyl-3-nitrobenzoate pictures 2024-04-25 Methyl 2-methyl-3-nitrobenzoate
59382-59-1
US $67.81 / Kg/Drum 5KG 99.0%min 5tons/momth Asia Chem I and E (Jiangsu) Co Ltd
Methyl 2-methyl-3-nitrobenzoate pictures 2021-10-23 Methyl 2-methyl-3-nitrobenzoate
59382-59-1
US $0.00-0.00 / Kg/Drum 1KG 99%min 500kg WUHAN FORTUNA CHEMICAL CO., LTD
Methyl 2-methyl-3-nitrobenzoate pictures 2019-07-06 Methyl 2-methyl-3-nitrobenzoate
59382-59-1
US $1.00 / KG 1KG 98-100% 100KG Career Henan Chemical Co
3-NITRO-O-TOLUIC ACID METHYL ESTER 3-NITRO-0-TOLUIC ACID METHYL ESTER 3-Nitro-o-toluic acid methyl ester (COOCH3=1) Methyl 3-nitro-2-methylbenzoate Benzoic acid, 2-methyl-3-nitro-, methyl ester Methyl 2-methyl-3-nitrobenzoate, 98+% METHYL 3-NITRO-O-TOLUATE METHYL 2-METHYL-3-NITROBENZENECARBOXYLATE METHYL 2-METHYL-3-NITROBENZOATE Methyl 2-Methyl-3-Nitro-Benzoatee 3-Nitro-2-methylbenzoic acid methyl ester 3-(Methoxycarbonyl)-2-methylnitrobenzene, 2-(Methoxycarbonyl)-6-nitrotoluene 2-Methyl-3-nitrobenzoic Acid Methyl Ester Methyl 3-Nitro-o-toluate 3-Nitro-o-toluic Acid Methyl Ester 2-Methyl-3-nitrobenzoate Methyl 2-Methyl-3-nitrobenzoate, 95+% Methyl2-Methyl-3-nitrobenzoate> Methyl 2-methyl-3- Benzoic acid, 2-methyl-3-nitro-, methyl ester (9CI, ACI) DK835 2-methyl-3-nitro-Benzoic acid methyl ester (9CI ACI) Lenalidoide Ipurity 23 59382-59-1 10001-13-2 CH3C6H3NO2CO2CH3 Building Blocks Carbonyl Compounds C8 to C9 Esters Organic Building Blocks API intermediates Aromatic Esters FINE Chemical & INTERMEDIATES blocks Carboxes NitroCompounds