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RockPhos Pd G3

CAS No.
2009020-38-4
Chemical Name:
RockPhos Pd G3
Synonyms
RockPhos Pd G3;Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (RockPhos Pd G3);2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3-METHOXY-6-METHYL-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ROCKPHOSPALLADACYCLEGEN.3]
CBNumber:
CB33357113
Molecular Formula:
C44H63NO4PPdS-
Molecular Weight:
839.434081
MDL Number:
MFCD27952542
MOL File:
2009020-38-4.mol
Last updated:2024-03-18 16:05:02

RockPhos Pd G3 Properties

Melting point 220-250 °C
form Powder
color brown
InChIKey QAHMIRGGAFFMDS-UHFFFAOYSA-N
CAS DataBase Reference 2009020-38-4

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

RockPhos Pd G3 price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 773905 RockPhos Pd G3 2009020-38-4 100MG $112 2023-06-20 Buy
Sigma-Aldrich 773905 RockPhos Pd G3 2009020-38-4 500MG $532 2023-06-20 Buy
Sigma-Aldrich 773905 RockPhos Pd G3 2009020-38-4 5G $3950 2023-06-20 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 2009020-38-4 100mg $103 2024-03-01 Buy
Strem Chemicals 46-0335 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3] 2009020-38-4 500mg $426 2024-03-01 Buy
Product number Packaging Price Buy
773905 100MG $112 Buy
773905 500MG $532 Buy
773905 5G $3950 Buy
46-0335 100mg $103 Buy
46-0335 500mg $426 Buy

RockPhos Pd G3 Chemical Properties,Uses,Production

Reaction

  1. Palladium precatalyst used for the arylation of an aliphatic alcohol.
  2. Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions.
  3. Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols.
Reactions of 2009020-38-4

Uses

Buchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols.


Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

RockPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

RockPhos Pd G3 Suppliers

Global( 41)Suppliers
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XINXIANG RUNYU MATERIAL CO., LTD.
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Aladdin Scientific
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Henan Runfeng Catalyst Co. LTD 15560227177 sales@runcatalysts.cn China 111 58
METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3-METHOXY-6-METHYL-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ROCKPHOSPALLADACYCLEGEN.3] Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II) 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (RockPhos Pd G3) RockPhos Pd G3 Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium 2009020-38-4 C44H62NO4PPdS