2-Bromothiophene
- CAS No.
- 1003-09-4
- Chemical Name:
- 2-Bromothiophene
- Synonyms
- S0502;DKIIR;NSC 4456;INDIP-020;forTipepidine;Thienyl bromide;2-bromo-thiophen;2-BROMOTHIOPHENE;2-Bromothiaphene;2-THIENYL BROMIDE
- CBNumber:
- CB3335815
- Molecular Formula:
- C4H3BrS
- Molecular Weight:
- 163.04
- MDL Number:
- MFCD00005417
- MOL File:
- 1003-09-4.mol
- MSDS File:
- SDS
| Melting point | -10 °C |
|---|---|
| Boiling point | 149-151 °C (lit.) |
| Density | 1.684 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 140 °F |
| storage temp. | 2-8°C |
| form | Liquid |
| Specific Gravity | 1.684 |
| color | Clear colorless to slightly brownish |
| Water Solubility | IMMISCIBLE |
| Sensitive | Light Sensitive |
| BRN | 104663 |
| InChIKey | TUCRZHGAIRVWTI-UHFFFAOYSA-N |
| CAS DataBase Reference | 1003-09-4(CAS DataBase Reference) |
| FDA UNII | GFF929NUW7 |
| NIST Chemistry Reference | Thiophene, 2-bromo-(1003-09-4) |
| EPA Substance Registry System | Thiophene, 2-bromo- (1003-09-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H300-H318 | |||||||||
| Precautionary statements | P210-P233-P240-P280-P301+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T,N,Xn | |||||||||
| Risk Statements | 10-25-41-51/53-36/37/38-23/24-22-20/21/22 | |||||||||
| Safety Statements | 26-36/37/39-45-61-16-36 | |||||||||
| RIDADR | UN 2929 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | T | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29349990 | |||||||||
| NFPA 704 |
|
2-Bromothiophene price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 124168 | 2-Bromothiophene 98% | 1003-09-4 | 10g | $41.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 124168 | 2-Bromothiophene 98% | 1003-09-4 | 50g | $72.5 | 2024-03-01 | Buy |
| TCI Chemical | B0941 | 2-Bromothiophene >98.0%(GC) | 1003-09-4 | 25g | $21 | 2024-03-01 | Buy |
| TCI Chemical | B0941 | 2-Bromothiophene >98.0%(GC) | 1003-09-4 | 250g | $111 | 2024-03-01 | Buy |
| Alfa Aesar | A11959 | 2-Bromothiophene, 98+% | 1003-09-4 | 50g | $51.8 | 2024-03-01 | Buy |
2-Bromothiophene Chemical Properties,Uses,Production
General description
2-Bromothiophene undergoes metallation-alkylation reaction with various electrophiles to generate various 5-alkylated 2-bromo products. It is coupled with 4-bromoallyl phenyl ether to produce allyl thiophene ether, which is a new type of organic thin film transistor dielectric material.
Application
In dimethylformamide containing tetramethylammonium perchlorate, 2-bromothiophene is electrochemically reduced many mono- and dihalothiophenes on a carbon cathode by cyclic voltammetry and controlled potential electrolysis.
Product Introduction
The 2-Bromothiophene(casno:1003-09-4) is an organic compound with the formula C4H3BrS. The IUPAC name of this chemical is 2-bromothiophene. With the CAS registry number 1003-09-4, it is also named as Bromothiophene. The product's categories are Thiophenes; Halides; Thiophenes & Benzothiophenes; Thiophene & Benzothiophene; Thiophenes & Benzothiophenes. Besides, 2-Bromothiophene(casno:1003-09-4) is a colorless to light yellow transparent liquid, which should be stored in a closed dark and cool place. 2-Bromothiophene(casno:1003-09-4) can be used for organic synthesis and pharmaceutical intermediates.
Chemical Properties
colorless to light yellow liquid. Soluble in ether and acetone, insoluble in water.
Uses
2-Bromothiophene has been used in electrochemical reduction of a number of mono- and dihalothiophenes at carbon cathodes in dimethylformamide containing tetramethylammonium per chlorate by cyclic voltammetry and controlled-potential electrolysis.
Preparation
2-Bromothiophene is synthesized by bromination of thiophene, which is achieved through the following steps: dissolve thiophene in acetic acid, and add bromine in glacial acetic acid solution below 10°C. Water was added to the reaction mixture to precipitate an oily liquid. Extract with ether. Add potassium carbonate to the extract to remove acetic acid, dry it, distill off the ether, and then conduct vacuum distillation to collect fractions at 42-46°C (1.73kPa) to obtain 2-bromothiophene with a yield of 55%.
Synthesis Reference(s)
Journal of the American Chemical Society, 79, p. 5474, 1957 DOI: 10.1021/ja01577a039
Synthesis, p. 890, 1988 DOI: 10.1055/s-1988-27740
General Description
2-Bromothiophene undergoes metalation-alkylation reaction with various electrophiles to form various 5-alkylated 2-bromo products. It undergoes coupling with 4-bromo allyl phenyl ether to form allyl phenyl thiophene ether, which is a novel potential dielectric material for organic thin film transistors.
2-Bromothiophene Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Firsky International Trade (Wuhan) Co., Ltd | +8615387054039 | admin@firsky-cn.com | China | 436 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@airuikechemical.com | China | 994 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
View Lastest Price from 2-Bromothiophene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-09 | 2-bromothiophene
1003-09-4
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. | |
 |
2024-01-23 | Bromothiophene
1003-09-4
|
US $9.00-0.90 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-10-09 | 2-Bromothiophene
1003-09-4
|
US $30.00 / KG | 1KG | 99% | 20T | Firsky International Trade (Wuhan) Co., Ltd |
-
- 2-bromothiophene
1003-09-4
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
-
- Bromothiophene
1003-09-4
- US $9.00-0.90 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 2-Bromothiophene
1003-09-4
- US $30.00 / KG
- 99%
- Firsky International Trade (Wuhan) Co., Ltd
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