Ethyl 2-cyano-3,3-diphenylacrylate
- CAS No.
- 5232-99-5
- Chemical Name:
- Ethyl 2-cyano-3,3-diphenylacrylate
- Synonyms
- UV-3035;ETHYL 2-CYANO-3,3-DIPHENYLACRYLATE;ce2;ETOCRYLENE;2-Propenoicacid,2-cyano-3,3-diphenyl-,ethylester;uvinuln35;tocrylene;ETOCRILENE;Viosorb 910;usafa-15972
- CBNumber:
- CB3337091
- Molecular Formula:
- C18H15NO2
- Molecular Weight:
- 277.32
- MDL Number:
- MFCD00027364
- MOL File:
- 5232-99-5.mol
- MSDS File:
- SDS
| Melting point | 97-99 °C(lit.) |
|---|---|
| Boiling point | 174 °C0.2 mm Hg(lit.) |
| Density | 1,05 g/cm3 |
| refractive index | 1.5100 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| form | powder to crystal |
| color | White to Almost white |
| InChI | InChI=1S/C18H15NO2/c1-2-21-18(20)16(13-19)17(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-12H,2H2,1H3 |
| InChIKey | IAJNXBNRYMEYAZ-UHFFFAOYSA-N |
| SMILES | C(OCC)(=O)/C(/C#N)=C(/C1=CC=CC=C1)\C1=CC=CC=C1 |
| LogP | 4.520 (est) |
| CAS DataBase Reference | 5232-99-5(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 974109G71I |
| EPA Substance Registry System | Ethyl 2-cyano-3,3-diphenylacrylate (5232-99-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335-H410 | |||||||||
| Precautionary statements | P261-P264-P271-P273-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,N | |||||||||
| Risk Statements | 36/37/38-50/53 | |||||||||
| Safety Statements | 26-36-60-61 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | AT6200000 | |||||||||
| HS Code | 29269090 | |||||||||
| NFPA 704 |
|
Ethyl 2-cyano-3,3-diphenylacrylate price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 415812 | Ethyl 2-cyano-3,3-diphenylacrylate 98% | 5232-99-5 | 50g | $42.8 | 2024-03-01 | Buy |
| TCI Chemical | C0962 | Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) | 5232-99-5 | 25g | $31 | 2024-03-01 | Buy |
| TCI Chemical | C0962 | Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) | 5232-99-5 | 500g | $220 | 2024-03-01 | Buy |
| TRC | E926273 | Ethyl 2-Cyano-3,3-diphenylacrylate | 5232-99-5 | 25g | $70 | 2021-12-16 | Buy |
| AK Scientific | J53104 | Ethyl-2-cyano-3,3-diphenylpropenoate | 5232-99-5 | 25g | $60 | 2021-12-16 | Buy |
Ethyl 2-cyano-3,3-diphenylacrylate Chemical Properties,Uses,Production
Description
Etocrylene is an organic ester that appears as an off-white crystalline powder and functions as a UV absorber. When applied to the skin, this product absorbs UV rays. It can also be used to protect cosmetics and personal care products from deterioration. This product can be used in the formulation of sun protection products, as well as bath, skin, cleansing, hair, nail and fragrance products.
Uses
Ethyl 2-Cyano-3,3-diphenylacrylate is a sunscreen ingredient.
Uses
Ultraviolet screen.
Synthesis Reference(s)
Journal of the American Chemical Society, 63, p. 3452, 1941 DOI: 10.1021/ja01857a057
Tetrahedron Letters, 33, p. 7535, 1992 DOI: 10.1016/S0040-4039(00)60817-1
Synthesis
The preparation method of Ethyl 2-cyano-3,3-diphenylacrylate includes the following steps: add cyclohexane and benzophenone to the reaction kettle, wait until the benzophenone is completely dissolved, then raise the temperature to 102-104°C and keep it warm. Then, add sodium bicarbonate as a catalyst, add ethyl cyanoacetate into the dripping storage tank, slowly add ethyl cyanoacetate dropwise into the reaction kettle, and react for 16 to 18 hours. During the reaction, the water generated is separated in time, and the reaction is completed. The product Ethyl 2-cyano-3,3-diphenylacrylate is obtained.
Properties and Applications
Ethyl 2-cyano-3,3-diphenylacrylate, another name Etocrylene, belongs to acrylic acid or the like UV light absorbers and is mainly used in making UV light absorbers in plastics, coating, dyestuff, vehicle glass, makeup, sun-screening agent. Because acrylate-based, two phenyls of this product and carbonyl can form a larger π key; thus, the structure shape of this product has extremely strong ultraviolet absorption ability.
Ethyl 2-cyano-3,3-diphenylacrylate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan BJM Pharm Inc | +86-027-5234-1919 +8613545198479 | sales03@benjaminpharmchem.com | China | 671 | 58 |
| Qingdao Truelight functional Material Technology Co., Ltd. | +86-13573844393 | songjames@truelightchem.com | China | 219 | 58 |
| Jiangxi Lotchem Co.,Ltd. | +8615270827708 | lancetu@jxlotchem.com | CHINA | 338 | 58 |
| Changzhou AniKare Pharmatech Co., Ltd. | +86-0519-8359-8696 +8618018249389 | sales@anikare.com | China | 8382 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Hebei Saisier Technology Co., LTD | +86-18400010335 +86-13102810335 | admin@hbsaisier.cn | China | 690 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 | sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
View Lastest Price from Ethyl 2-cyano-3,3-diphenylacrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-19 | Etocrilene
5232-99-5
|
US $6.00 / KG | 1KG | More than 99% | 2000KG/MONTH | Hebei Saisier Technology Co., LTD | |
 |
2024-04-16 | UV ABSORBER TRUELICHT UV 3035
5232-99-5
|
US $0.00 / KG | 1drums | 98.0% | 20 tons | Qingdao Truelight functional Material Technology Co., Ltd. | |
 |
2023-12-25 | Etocrilene
5232-99-5
|
US $0.00 / kg | 1kg | 99% | 1000000 | Hebei Jingbo New Material Technology Co., Ltd |
-
- Etocrilene
5232-99-5
- US $6.00 / KG
- More than 99%
- Hebei Saisier Technology Co., LTD
-
- UV ABSORBER TRUELICHT UV 3035
5232-99-5
- US $0.00 / KG
- 98.0%
- Qingdao Truelight functional Material Technology Co., Ltd.
-
- Etocrilene
5232-99-5
- US $0.00 / kg
- 99%
- Hebei Jingbo New Material Technology Co., Ltd