Dibutoxymethane
- CAS No.
- 2568-90-3
- Chemical Name:
- Dibutoxymethane
- Synonyms
- Butylal;Dibutyl formal;Dibutoxymethane;Di-n-butyl formal;5,7-Dioxaundecane;Methane, dibutoxy-;5,7-Dioxahendecane;DI-N-BUTOXYMETHANE;Dibutoxymethane>Bis(butyloxy)methane
- CBNumber:
- CB3346224
- Molecular Formula:
- C9H20O2
- Molecular Weight:
- 160.25
- MDL Number:
- MFCD00059270
- MOL File:
- 2568-90-3.mol
| Melting point | -58.1°C |
|---|---|
| Boiling point | 180°C |
| Density | 0,84 g/cm3 |
| vapor pressure | 1-1.11hPa at 22.7-25℃ |
| refractive index | n20/D1.406 |
| Flash point | 60°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Water Solubility | 222.5-250mg/L at 20℃ |
| LogP | 2.77-4.1 at 20-21.5℃ |
| FDA UNII | V5WWR58LDU |
| EPA Substance Registry System | Butane, 1,1'-[methylenebis(oxy)]bis- (2568-90-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226 | |||||||||
| Precautionary statements | P210-P233-P240-P241+P242+P243-P280-P303+P361+P353-P370+P378-P403+P235-P501 | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| RIDADR | 3271 | |||||||||
| WGK Germany | 1 | |||||||||
| HS Code | 2911.00.5000 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
Dibutoxymethane price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 689386 | Formaldehyde dibutyl acetal puriss., ≥98.5% (GC) | 2568-90-3 | 250ml | $73.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 689386 | Formaldehyde dibutyl acetal puriss., ≥98.5% (GC) | 2568-90-3 | 1l | $221 | 2024-03-01 | Buy |
| TCI Chemical | D1711 | Dibutoxymethane >98.0%(GC) | 2568-90-3 | 25g | $156 | 2024-03-01 | Buy |
| TRC | M303265 | 1,1''-[Methylenebis(oxy)]bis-butane | 2568-90-3 | 50ml | $45 | 2021-12-16 | Buy |
| TRC | M303265 | 1,1''-[Methylenebis(oxy)]bis-butane | 2568-90-3 | 100ml | $55 | 2021-12-16 | Buy |
Dibutoxymethane Chemical Properties,Uses,Production
Uses
Formaldehyde dibutyl acetal is a halogen-free and less toxic solvent that can be used to solubilize commercial low-density polyethylene (LDPE) samples to analyze molecular weight distribution using gel permeation chromatography (GPC). It can also be used as a reactant to prepare butoxymethyltriphenylphosphonium iodide, which is used for carbon homologation and also as a useful key intermediate in organic synthesis.
Preparation
A flask containing 15 gm (0.5 mole) of paraformaldehyde, 74 gm (1.0 mole) of η-butyl alcohol, and 2.0 gm of anhydrous ferric chloride is refluxed for 10 hr. The lower layer of 3-4 ml of material is discarded and then 50 ml of 10% aqueous sodium carbonate solution is added to remove the ferric chloride as ferric hydroxide. The product is shaken with a mixture of 40 ml of 20% hydrogen peroxide and 5 ml of 10% sodium carbonate solution at 45°C in order to remove any remaining aldehyde. The product is also washed with water, dried, and distilled from excess sodium metal to afford 62 gm (78%).
Synthesis Reference(s)
The Journal of Organic Chemistry, 45, p. 3341, 1980 DOI: 10.1021/jo01304a039
General Description
Formaldehyde dibutyl acetal is an acetal used in the manufacture of synthetic resins, antiseptics, deodorants, and fungicides. It is also used as a fuel additive to increase the octane number of gasoline or the n-cetane number of diesel fuels and reduce smoke and particulate emissions.
Dibutoxymethane Preparation Products And Raw materials
Dibutoxymethane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 20356 | 58 |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | alfa4@alfachem.cn | China | 12755 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178 +86-85511178 | peter68@ptchemgroup.com | China | 35453 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49999 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33349 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |