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2,4,6-Trimethyliodobenzene

2,4,6-Trimethyliodobenzene structure

CAS No.: 4028-63-1

Chemical Name:: 2,4,6-Trimethyliodobenzene

Synonyms: DF77;SKL669;Mesityliodine;MESITYL IODIDE;IODOMESITYLENE;2-Iodmesitylen;2-IODOMESITYLENE;MesitylIodide>2-Iodo-3-isopropyltoluene;2,4,6-TRIMETHYLIODOBENZENE

CBNumber:: CB3674064

Molecular Formula:: C9H11I

Molecular Weight:: 246.09

MDL Number:: MFCD00013707

MOL File:: 4028-63-1.mol

MSDS File:: SDS

Last updated:2023-12-28 18:13:10

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2,4,6-Trimethyliodobenzene Properties

Melting point	28-32 °C
Boiling point	250 °C
Density	1.5100 (rough estimate)
refractive index	1.5905 (estimate)
storage temp.	2-8°C(protect from light)
form	powder to lump to clear liquid
color	White or Colorless to Light yellow
Sensitive	Light Sensitive
BRN	1860064
InChIKey	GTPNXFKONRIHRW-UHFFFAOYSA-N
CAS DataBase Reference	4028-63-1(CAS DataBase Reference)
NIST Chemistry Reference	2,4,6-Trimethyliodobenzene(4028-63-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H319

Precautionary statements

P305+P351+P338

Risk Statements

36/37/38

Safety Statements

24/25-36/37/39-24/28

HazardClass

LIGHT SENSITIVE

HS Code

29039990

NFPA 704

	0
0		0

2,4,6-Trimethyliodobenzene price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	R258377	2-IODO-1,3,5-TRIMETHYL-BENZENE Aldrich	4028-63-1	50mg	$29.8	2024-03-01	Buy
TCI Chemical	I0478	Mesityl Iodide	4028-63-1	5G	$18	2024-03-01	Buy
TCI Chemical	I0478	Mesityl Iodide	4028-63-1	25G	$62	2024-03-01	Buy
Alfa Aesar	A15360	2-Iodo-1,3,5-trimethylbenzene, 98%	4028-63-1	5g	$51.65	2024-03-01	Buy
Alfa Aesar	A15360	2-Iodo-1,3,5-trimethylbenzene, 98%	4028-63-1	25g	$196.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
R258377	50mg	$29.8	Buy
I0478	5G	$18	Buy
I0478	25G	$62	Buy
A15360	5g	$51.65	Buy
A15360	25g	$196.65	Buy

2,4,6-Trimethyliodobenzene Chemical Properties,Uses,Production

Chemical Properties

yellow crystalline low melting solid

Uses

Iodomesitylene can be used as a good catalyst for living radical polymerization due to its good molecular weight distribution.

Uses

suzuki reaction

Synthesis Reference(s)

Tetrahedron Letters, 10, p. 2427, 1969 DOI: 10.1017/S0009838800024678

Hazard

May cause eye, skin, and respiratory tract irritation. Light sensitive.

Health effects

Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.

Synthesis

The synthesis of 2,4,6-Trimethyliodobenzene is as follows:
A 10 mL glass flask equipped with a magnetic stir bar wascharged with a methyl ketone (1 mmol) and dissolved in MeCN (2 mL). To thermostat solution NH4NO3 (10-25 mol%), I2 (50 mol%) and H2SO4 (aqueous 96% solution, 10-20 mol%) were added and the flask was furtherequipped with a balloon filled with air (1 L) and magnetically stirred at 60 C.The consumption of starting material was monitored by TLC. After completion of the reaction, the mixture was cooled to room temperature, diluted withEtOAc (10 mL), and insoluble material identified as ammonium sulfate filtered off. The filtrate neutralized with NaHCO3 (aqueous 10% solution, 2 mL)and Na2S2O3 (aqueous 10% solution, 2 mL) and phase was separated. The waterphase was washed with EtOAc additionally two times (2 5 mL). The combined organic phase was dried over anhydrous Na2SO4 and the solvent distilled under reduced pressure. The crude product obtained was analyzed by 1H NMR. Finally, the crude product was purified using column chromatography (SiO2, n-hexane/CH2Cl2 elution) and preparative thin layer chromatography to afford purematerial.
synthesis of 2,4,6-Trimethyliodobenzene.png

storage

Store in a cool, dry place. Store in a tightly closed container. Store protected from light.

2,4,6-Trimethyliodobenzene synthesis

Synthesis of 2,4,6-Trimethyliodobenzene from Mesitylene

2,4,6-Trimethyliodobenzene Preparation Products And Raw materials

Raw materials

Iodonium, (3-chlorophenyl)(2,4,6-trimethylphenyl)-, 1,1,1-trifluoromethanesulfonate (1:1) 1,1'-Biphenyl, 3,3',4,4'-tetrafluoro- 2,4-DIIODO-1,3,5-TRIMETHYL-BENZENE Iodonium, [4-?(ethoxycarbonyl)?phenyl]?(2,?4,?6-?trimethylphenyl)?-?, 1,?1,?1-?trifluoromethanesulf?onate (1:1) (3-BroMophenyl)(2,4,6-triMethylphenyl)iodoniuM triflate

4,4'-Diacetylbiphenyl 3,3'-DICHLOROBIPHENYL DIETHYL BIPHENYL-4,4'-DICARBOXYLATE P-BENZANISIDIDE 1-bromo-3-(3-bromophenyl)benzene

2,4-Dimethylphenol Dimesityliodonium triflate

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Preparation Products

2,4,6-Trimethylbenzoic acid IODOMESITYLENE DIACETATE 3,3'-Dimethylbiphenyl

2,4,6-Trimethyliodobenzene Suppliers

Global( 188)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Nanjing Triumpharm Co.,Ltd	+86-02586182925 +86-15105172550	info@triumpharm.com	China	129	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8823	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58

Supplier	Advantage
Nanjing Triumpharm Co.,Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Hangzhou FandaChem Co.,Ltd.	55
career henan chemical co	58
Accela ChemBio Inc.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Chongqing Chemdad Co., Ltd	58

View Lastest Price from 2,4,6-Trimethyliodobenzene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-29	2,4,6-Trimethyliodobenzene 4028-63-1	US $101.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-07-28	2,4,6-Trimethyliodobenzene 4028-63-1	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-04-18	2,4,6-Trimethyliodobenzene 4028-63-1	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Guanlang Biotechnology Co., Ltd.

2,4,6-Trimethyliodobenzene
4028-63-1
US $101.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

2,4,6-Trimethyliodobenzene
4028-63-1
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

2,4,6-Trimethyliodobenzene
4028-63-1
US $0.00-0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

2,4,6-Trimethyliodobenzene Spectrum

2,4,6-Trimethyliodobenzene(4028-63-1)MS 2,4,6-Trimethyliodobenzene(4028-63-1)¹HNMR 2,4,6-Trimethyliodobenzene(4028-63-1)¹³CNMR 2,4,6-Trimethyliodobenzene(4028-63-1)IR1 2,4,6-Trimethyliodobenzene(4028-63-1)IR2

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Iodomesitylene~2,4,6-Trimethyliodobenzene 2,4,6-TRIMETHYLIODOBENZENE (2-IODOMESITYLENE) 2,4,6-Trimethylphenyl iodide Mesityliodine 2,4,6-Trimethyliodobenzene,98% 2-Iodo-3-isopropyltoluene 2-Iodo-1,3,5-trimethylbenzene, 2-Iodomesitylene, Mesityl iodide 2-Iodomesitylene 2-Iodo-1,3,5-trimethylbenzene 2-IODO-1,3,5-TRIMETHYLBENZENE 2-IODOMESITYLENE 2,4,6-TRIMETHYLIODOBENZENE 1-IODO-2,4,6-TRIMETHYLBENZENE MESITYL IODIDE IODOMESITYLENE Benzene, 2-iodo-1,3,5-trimethyl- Iodo-2,4,6-trimethylbenzene 2,4,6-Trimethyliodobenzene 98% 2-Iodmesitylen 2,4,6-Trimethyliodobenzene, 97%, for synthesis MesitylIodide> SKL669 DF77 4028-63-1 C9H11I Aromatic Halides (substituted)