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POLY(VINYL ACETATE)

POLY(VINYL ACETATE)
POLY(VINYL ACETATE) structure
CAS No.
9003-20-7
Chemical Name:
POLY(VINYL ACETATE)
Synonyms
ts2;d50m;ayaa;ayaf;ayjv;PVAc;ps3h;pvae;v501;76res
CBNumber:
CB3700594
Molecular Formula:
C4H6O2
Formula Weight:
86.08924
MOL File:
9003-20-7.mol

POLY(VINYL ACETATE) Properties

Melting point:
60°C
Boiling point:
70-150 °C
Density 
1.191 g/mL at 25 °C
refractive index 
n20/D 1.467
Flash point:
>100℃
storage temp. 
2-8°C
solubility 
ketones, ethers and aromatic hydrocarbons: soluble
form 
pellets
color 
Clear
PH
3.0-5.5
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
Substances Added to Food (formerly EAFUS)
POLYVINYL ACETATE
FDA 21 CFR
172.615; 175.300; 175.320; 176.170; 177.1200; 177.2800; 181.30; 73.1
FDA UNII
32K497ZK2U
EPA Substance Registry System
Polyvinyl acetate (9003-20-7)
SAFETY
  • Risk and Safety Statements
Risk Statements  45-46
Safety Statements  24/25
WGK Germany  3
RTECS  AK0920000
TSCA  Yes
HS Code  39051900
Toxicity LD50 oral in mouse: > 25gm/kg

POLY(VINYL ACETATE) price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 182508 Poly(vinyl acetate) analytical standard, molecular weight series 9003-20-7 1set $370 2019-12-02 Buy
Sigma-Aldrich 1548032 Polyvinyl acetate United States Pharmacopeia (USP) Reference Standard 9003-20-7 1g $384.65 2019-12-02 Buy
Alfa Aesar A12732 Polyvinyl acetate, M.W. ca 50,000 9003-20-7 100g $31.9 2019-12-02 Buy
Alfa Aesar A12732 Polyvinyl acetate, M.W. ca 50,000 9003-20-7 500g $111 2019-12-02 Buy
Sigma-Aldrich Y0000792 Poly(vinyl acetate) dispersion 30 per cent European Pharmacopoeia (EP) Reference Standard 9003-20-7 y0000792 $183 2019-12-02 Buy

POLY(VINYL ACETATE) Chemical Properties,Uses,Production

Chemical Properties

transparent pellets or white powder

Chemical Properties

The degree of polymerization of polyvinyl acetate typically is 100 to 5000. The ester groups of the polyvinyl acetate are sensitive to base hydrolysis and will slowly convert PVAc into polyvinyl alcohol and acetic acid.
Under alkaline conditions, boron compounds such as boric acid or borax cause the polymer to cross-link, forming tackifying precipitates or slime.

History

Polyvinyl acetate was discovered in Germany in 1912 by Fritz Klatte.
The monomer, vinyl acetate, was first produced on an industrial scale by addition of acetic acid to acetylene with a mercury(I) salt[3] but it is now primarily made by palladium catalyzed oxidative addition of acetic acid to ethylene.

Uses

As an emulsion in water, aPVAc emulsions are used as adhesives for porous materials, particularly for wood, paper, and cloth, and as a consolidant for porous building stone, in particular sandstone . Uses :
As wood glue PVAc is known as "white glue" and the yellow "carpenter's glue" or PVA glue.
As paper adhesive during paper packaging converting
In bookbinding and book arts, due to its flexible strong bond and non-acidic nature (unlike many other polymers). The use of PVAC on the Archimedes Palimpsest during the 20th century greatly hindered the task of disbinding the book and preserving and imaging the pages in the early 21st century, in part because the glue was stronger than the parchment it held together.
The stiff homopolymer PVAc, but mostly the more soft copolymer a combination of vinyl acetate and ethylene, vinyl acetate ethylene (VAE), is used also in paper coatings, paint and other industrial coatings, as binder in nonwovens in glass fibers. sanitary napkins, filter paper and in textile finishing
PVAc can also be used as coating to protect cheese from fungi and humidity.
Polyvinyl acetate is also the raw material to make other polymers like : Polyvinyl alcohol -[HOCHCH2]-: Polyvinyl acetate is partially or completely hydrolysed to give polyvinyl alcohol. This reversible saponification and esterification reaction was a strong hint for Hermann Staudinger in the formulation of his theory of macro molecules.
Polyvinyl acetate phthalate (PVAP): Polyvinyl acetate is partially hydrolyzed and then esterified with phthalic acid.

Uses

drug delivery, hemodynamics, wound dressing, coatings

Definition

ChEBI: A polymer composed of repeating acetoxyethylene units.

Preparation

PVAc is a vinyl polymer. Polyvinyl acetate is prepared by polymerization of vinyl acetate monomer (free radical vinyl polymerization of the monomer vinyl acetate).

Production Methods

Polyvinyl acetate is derived from the polymerization of vinyl acetate; the catalysts used in polymerization may include hydrogen peroxide, peroxy sulfates, or various redox combinations. The polymerization process is described as being carried out by charging all ingredients to the reactor, heating to reflux, and stirring until the reaction is complete. Typically, only a part of the monomer and catalyst is initially charged; the remainder is added during the course of the reaction.

Hazard

Questionable carcinogen.

Industrial uses

Polyvinyl acetate is a leathery, colorless thermoplasticmaterial that softens at relatively lowtemperatures and that is relatively stable to lightand oxygen. The polymers are clear and noncrystalline.The chief applications of polyvinylacetate are as adhesives and binders for waterbasedor emulsion paints.
Vinyl acetate is conveniently prepared bythe reaction of acetylene with acetic acid.

Safety Profile

Very low toxicity by ingestion. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS

Purification Methods

Precipitate it from acetone by addition of n-hexane.

POLY(VINYL ACETATE) Preparation Products And Raw materials

Raw materials

Preparation Products


POLY(VINYL ACETATE) Suppliers

Global( 126)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21838 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22625 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30043 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23977 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 10157 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6371 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23045 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
BOC Sciences
1-631-619-7922
1-631-614-7828 inquiry@bocsci.com United States 20039 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35434 58

Related articles


View Lastest Price from POLY(VINYL ACETATE) manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2020-04-22 Polyvinyl acetate
9003-20-7
US $1.00-1.00 / KG 1g 99% 50tons Shaanxi Dideu Medichem Co. Ltd
2018-12-25 SEC-BUTYLACETATE
9003-20-7
US $1.00 / kg 1kg 95%-99% 1000kg career henan chemical co

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