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CAS No. 554-84-7
Chemical Name: 3-Nitrophenol
Synonyms: 3-Nitrophe;m-Nitrofenol;3-nitro-pheno;M-NITROPHENOL;3-NITROPHENOL;m-nitro-pheno;Phenol,3-nitro-;meta-Nitrophenol;Phenol, m-nitro-;m-nitrophenol[qr]
CBNumber: CB3728637
Molecular Formula: C6H5NO3
Formula Weight: 139.11
MOL File: 554-84-7.mol
3-Nitrophenol Property
Melting point : 89-95 °C
Boiling point : 194 °C70 mm Hg(lit.)
density : 1,49 g/cm3
Fp : 102°C
storage temp. : Store at +5°C to +30°C.
pka: 8.28(at 25℃)
PH: 6.6-8.6 (H2O, 20℃)
Water Solubility : 13.5 g/L (25 ºC)
Merck : 14,6619
BRN : 1907946
CAS DataBase Reference: 554-84-7(CAS DataBase Reference)
NIST Chemistry Reference: Phenol, 3-nitro-(554-84-7)
EPA Substance Registry System: Phenol, 3-nitro-(554-84-7)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : Xn,Xi
Risk Statements : 22-38-41-36/37/38-33-20/21/22
Safety Statements : 26-36/37-45-36/37/39-22-28
RIDADR : UN 1663 6.1/PG 3
WGK Germany : 3
RTECS : SM1925000
F : 8
Hazard Note : Harmful/Irritant
TSCA : Yes
HazardClass : 6.1
PackingGroup : III
HS Code : 29089000
Hazardous Substances Data: 554-84-7(Hazardous Substances Data)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

3-Nitrophenol Chemical Properties,Usage,Production

Chemical Properties
yellow to brown crystalline powder
3-Nitrophenol is a chemical reagent used in various organic syntheses. Used in the synthesis of RAGE inhibitors via the etherification of phenols. Also used in the synthesis of kinase inhibitors again st epidermal growth factor receptor T790M mutation.
ChEBI: A member of the class of 3-nitrophenols that is phenol in which one of the hydrogens that is meta to the hydroxy group has been replaced by a nitro group.
General Description
Colorless to pale yellow crystalline solid. Sinks in and mixes with water.
Air & Water Reactions
Water insoluble.
Reactivity Profile
3-Nitrophenol is a light-yellow, crystalline material, toxic and irritant. When heated to decomposition 3-Nitrophenol emits toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 941]. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases.
Health Hazard
INHALATION: Inhalation or ingestion causes headaches, drowsiness, nausea, and blue color in lips, ears, and finger nails (cyanosis). EYES: Contact with eyes causes irritation. SKIN: Can be absorbed through intact skin to give same symptoms as for inhalation.
Fire Hazard
Special Hazards of Combustion Products: Dangerous toxic fumes of NO x
3-Nitrophenol Preparation Products And Raw materials
Raw materials
Preparation Products
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