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2-Nitrochlorobenzene

2-Nitrochlorobenzene
2-Nitrochlorobenzene structure
CAS No.
88-73-3
Chemical Name:
2-Nitrochlorobenzene
Synonyms
ONCB;2-cnb;lenvaint-F;2-Chlornitrobenzol;o-Chloronitrobenzen;O-CHLORONITROBENZENE;O-NITROCHLOROBENZENE;2-CHLORONITROBENZENE;2-NITROCHLOROBENZENE;Chloro-o-nitrobenzene
CBNumber:
CB3767980
Molecular Formula:
C6H4ClNO2
Formula Weight:
157.55
MOL File:
88-73-3.mol

2-Nitrochlorobenzene Properties

Melting point:
31-33 °C(lit.)
Boiling point:
246 °C(lit.)
Density 
1.348 g/mL at 25 °C(lit.)
vapor density 
5.4 (vs air)
vapor pressure 
0.04 mm Hg ( 25 °C)
refractive index 
1.5520 (estimate)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
alcohol: soluble
form 
Fused Crystalline Mass
color 
Yellow
PH
6 (0.4g/l, H2O, 20℃)
explosive limit
1.15-13.1%(V)
Water Solubility 
0.43 g/L (20 ºC)
Merck 
14,2151
BRN 
509273
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, reducing agents, strong bases, alkali metals.
InChIKey
BFCFYVKQTRLZHA-UHFFFAOYSA-N
CAS DataBase Reference
88-73-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-2-nitro-(88-73-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T
Risk Statements  22-24-52-53-52/53
Safety Statements  36/37/39-45-60-38-28A
RIDADR  UN 1578 6.1/PG 2
WGK Germany  2
RTECS  CZ0875000
Autoignition Temperature 500 °F
Hazard Note  Toxic
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29049085
Hazardous Substances Data 88-73-3(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
3 0
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

2-Nitrochlorobenzene price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 185760 1-Chloro-2-nitrobenzene 99% 88-73-3 250g $26.1 2018-11-13 Buy
Sigma-Aldrich 185760 1-Chloro-2-nitrobenzene 99% 88-73-3 1kg $51.4 2018-11-13 Buy
TCI Chemical C0220 2-Chloronitrobenzene >99.0%(GC) 88-73-3 25g $14 2018-11-22 Buy
TCI Chemical C0220 2-Chloronitrobenzene >99.0%(GC) 88-73-3 500g $50 2018-11-22 Buy
Alfa Aesar A15403 1-Chloro-2-nitrobenzene, 99% 88-73-3 1000g $57.3 2018-11-13 Buy

2-Nitrochlorobenzene Chemical Properties,Uses,Production

Chemical Properties

yellow solid with a characteristic odour

Uses

Intermediate, especially for dyes.

General Description

Yellow crystals with an aromatic odor. Sinks in water.

Air & Water Reactions

2-Nitrochlorobenzene may be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

O-NITROCHLOROBENZENE is incompatible with strong bases and strong oxidizing agents. 2-Nitrochlorobenzene will react with ammonia.

Hazard

Toxic by inhalation and ingestion. Combustible. Questionable carcinogen.

Health Hazard

INHALATION: Headache, languour, anemia. Irritation of nose and throat, cyanosis, shallow respiration, convulsions, and coma. EYES: Irritation. SKIN: Irritation. INGESTION: Forms methemoglobin giving rise to cyanosis and blood changes.

Safety Profile

Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion, skin contact, and probably inhalation. Combustible when exposed to heat or flame. To fight fire, use water, foam. Potentially explosive reaction with ammonia at 160℃/30 bar. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.

Purification Methods

Crystallise it from EtOH, MeOH or pentane (charcoal). [Beilstein 5 IV 721.]

2-Nitrochlorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products


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