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(S)-1-PHENYL-BUT-3-EN-1-OL

CAS No.
77118-87-7
Chemical Name:
(S)-1-PHENYL-BUT-3-EN-1-OL
Synonyms
(1S)-1-phenylbut-3-en-1-ol;(S)-1-PHENYL-BUT-3-EN-1-OL;Benzenemethanol, α-2-propen-1-yl-, (αS)-
CBNumber:
CB3846542
Molecular Formula:
C10H12O
Molecular Weight:
148.2
MDL Number:
MFCD09032484
MOL File:
77118-87-7.mol

(S)-1-PHENYL-BUT-3-EN-1-OL price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CCH0001895 (S)-1-PHENYL-BUT-3-EN-1-OL 95.00% 77118-87-7 5MG $496.86 2021-12-16 Buy
American Custom Chemicals Corporation CCH0001895 (S)-1-PHENYL-BUT-3-EN-1-OL 95.00% 77118-87-7 1G $2905.35 2021-12-16 Buy
JR MediChem JR01-C008 (S)-1-phenylbut-3-en-1-ol 96% 77118-87-7 1g $268 2021-12-16 Buy
Product number Packaging Price Buy
CCH0001895 5MG $496.86 Buy
CCH0001895 1G $2905.35 Buy
JR01-C008 1g $268 Buy

(S)-1-PHENYL-BUT-3-EN-1-OL Chemical Properties,Uses,Production

Synthesis

To a solution of the bis-phosphoramide catalyst (59 mg, 0.1 mmol) in CH2Cl2 (1 mL) and diisopropylethylamine (1.0 mL) under N2 at −78 °C was added allyltrichlorosilane (580 µL, 4.0 mmol). The solution was stirred at −78 °C for 10 min before benzaldehyde (200 mL, 2.0 mmol) was added. The resulting mixture was stirred at this temperature for 8 h whereupon the cold solution was poured in to a mixture of saturated aqueous NaHCO3 (10 mL) and saturated aqueous KF (10 mL) at 0 °C with vigorous stirring. The mixture was stirred for 2 h at room temperature and then fifiltered through Celite. The layers were then separated and the aqueous layer was extracted with CH2Cl2 (3 × 30 mL). The combined organic extracts were dried (MgSO4), fifiltered, and concentrated. The oily residue was purifified by column chromatography (silica gel) eluting with CH2Cl2:pentane (3:1) followed by CH2Cl2 to give 254 mg (85%) of the benzylic alcohol in 87% ee. Reference: Denmark, S. E.; Fu, J. J. Am. Chem. Soc. 2001, 123, 9488−9489

(S)-1-PHENYL-BUT-3-EN-1-OL Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-1-PHENYL-BUT-3-EN-1-OL Suppliers

Global( 4)Suppliers
Supplier Tel Email Country ProdList Advantage
AlliChem, LLC -- sales@allichemllc.com United States 6527 60
Beta Pharma, Inc. -- sales@betapharma.com United States 6238 60
APAC Pharmaceutical, LLC -- sales@apacpharma.com United States 6332 38
ChemPacific Corporation -- sales@chempacific.com United States 6902 51
(S)-1-PHENYL-BUT-3-EN-1-OL (1S)-1-phenylbut-3-en-1-ol Benzenemethanol, α-2-propen-1-yl-, (αS)- 77118-87-7