(S)-1-PHENYL-BUT-3-EN-1-OL
- CAS No.
- 77118-87-7
- Chemical Name:
- (S)-1-PHENYL-BUT-3-EN-1-OL
- Synonyms
- (1S)-1-phenylbut-3-en-1-ol;(S)-1-PHENYL-BUT-3-EN-1-OL;Benzenemethanol, α-2-propen-1-yl-, (αS)-
- CBNumber:
- CB3846542
- Molecular Formula:
- C10H12O
- Molecular Weight:
- 148.2
- MDL Number:
- MFCD09032484
- MOL File:
- 77118-87-7.mol
(S)-1-PHENYL-BUT-3-EN-1-OL price
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
American Custom Chemicals Corporation | CCH0001895 | (S)-1-PHENYL-BUT-3-EN-1-OL 95.00% | 77118-87-7 | 5MG | $496.86 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | CCH0001895 | (S)-1-PHENYL-BUT-3-EN-1-OL 95.00% | 77118-87-7 | 1G | $2905.35 | 2021-12-16 | Buy |
JR MediChem | JR01-C008 | (S)-1-phenylbut-3-en-1-ol 96% | 77118-87-7 | 1g | $268 | 2021-12-16 | Buy |
(S)-1-PHENYL-BUT-3-EN-1-OL Chemical Properties,Uses,Production
Synthesis
To a solution of the bis-phosphoramide catalyst (59 mg, 0.1 mmol) in CH2Cl2 (1 mL) and diisopropylethylamine (1.0 mL) under N2 at −78 °C was added allyltrichlorosilane (580 µL, 4.0 mmol). The solution was stirred at −78 °C for 10 min before benzaldehyde (200 mL, 2.0 mmol) was added. The resulting mixture was stirred at this temperature for 8 h whereupon the cold solution was poured in to a mixture of saturated aqueous NaHCO3 (10 mL) and saturated aqueous KF (10 mL) at 0 °C with vigorous stirring. The mixture was stirred for 2 h at room temperature and then fifiltered through Celite. The layers were then separated and the aqueous layer was extracted with CH2Cl2 (3 × 30 mL). The combined organic extracts were dried (MgSO4), fifiltered, and concentrated. The oily residue was purifified by column chromatography (silica gel) eluting with CH2Cl2:pentane (3:1) followed by CH2Cl2 to give 254 mg (85%) of the benzylic alcohol in 87% ee. Reference: Denmark, S. E.; Fu, J. J. Am. Chem. Soc. 2001, 123, 9488−9489
(S)-1-PHENYL-BUT-3-EN-1-OL Preparation Products And Raw materials
(S)-1-PHENYL-BUT-3-EN-1-OL Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
AlliChem, LLC | -- | sales@allichemllc.com | United States | 6527 | 60 |
Beta Pharma, Inc. | -- | sales@betapharma.com | United States | 6238 | 60 |
APAC Pharmaceutical, LLC | -- | sales@apacpharma.com | United States | 6332 | 38 |
ChemPacific Corporation | -- | sales@chempacific.com | United States | 6902 | 51 |
Supplier | Advantage |
---|---|
AlliChem, LLC | 60 |
Beta Pharma, Inc. | 60 |
APAC Pharmaceutical, LLC | 38 |
ChemPacific Corporation | 51 |
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