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Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate

CAS No.
71301-98-9
Chemical Name:
Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate
Synonyms
(R)-ethyl 2-(4-hydroxyphenoxy)propanoate;Ethyl 2(R)-(4-Hydroxy-phenoxy)-propionate;Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propanoate;(R)-2-(p-Hydroxyphenoxy)propionic acid ethyl ester;(R)-2-(4-Hydroxyphenoxy)propionic acid ethyl ester;Propanoic acid, 2-(4-hydroxyphenoxy)-, ethyl ester, (2R)-
CBNumber:
CB41126914
Molecular Formula:
C11H14O4
Molecular Weight:
210.23
MDL Number:
MFCD12911580
MOL File:
71301-98-9.mol
MSDS File:
SDS
Last updated:2023-12-20 15:23:48

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate Properties

Melting point 36-37℃
Boiling point 327℃
Density 1.156
Flash point 124℃
storage temp. 2-8°C
pka 10.09±0.15(Predicted)

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC E927038 Ethyl(R)-(+)-2-(4-Hydroxyphenoxy)propionate 71301-98-9 50mg $110 2021-12-16 Buy
AK Scientific X5983 Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propionate 71301-98-9 1g $480 2021-12-16 Buy
Aaron Chemicals AR00FD66 Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propionate 97% 71301-98-9 5g $26 2021-12-16 Buy
Aaron Chemicals AR00FD66 Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propionate 97% 71301-98-9 25g $73 2021-12-16 Buy
Aaron Chemicals AR00FD66 Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propionate 97% 71301-98-9 100g $216 2021-12-16 Buy
Product number Packaging Price Buy
E927038 50mg $110 Buy
X5983 1g $480 Buy
AR00FD66 5g $26 Buy
AR00FD66 25g $73 Buy
AR00FD66 100g $216 Buy

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate Chemical Properties,Uses,Production

Uses

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate is an organic intermediate compound used mainly as a raw material for the synthesis of other compounds or for chemical research. It is also a degradation product of the herbicide fenoxaprop-ethyl (FE) in water, sediment and water-sediment microenvironments.

Synthesis

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate is prepared by the reaction of hydroquinone and (R)-ethyl O-bezenesulfonyl lactate in the presence of inert atmosphere. The steps are as follows:
Add hydroquinone (8.25g, 0.075mol), sodium carbonate (6.36g, 0.06mol), PEG-1500 (0.5g) into a 250mL nitrogen-proof flask equipped with a magnetic stir bar, and pass the nitrogen-proof flask into The nitrogen is then pumped with an oil pump and then fed into nitrogen (three consecutive times), and then 80 mL of xylene is added, and the reaction flask is placed in an oil bath heated to 120°C for 1 hour.Then add dropwise the xylene dilution liquid of ethyl lactate benzenesulfonate (12.9g, 0.05mol/20ml xylene, add three times, add once in 10 minutes, and add the next in 30 minutes), and then react after the addition is complete. The 6h reaction is over; the reaction solution is suction filtered, an appropriate amount of water is added to the suction filtrate, the solution is extracted with dichloromethane (washed and separated three times), dried with anhydrous sodium sulfate, and finally the solvent is removed by a rotary evaporator to obtain a light yellow Transparent crystals (containing a small amount of hydroquinone), 9.1 g of Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate was obtained by column chromatography, and the yield was 86.7%. Where Ar represents that the reaction system is always isolated from oxygen, that is, inert gas protection is used.
Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate synthesis

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate Suppliers

Global( 46)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569266 15319487004 1015@dideu.com China 2263 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Henan Alfa Chemical Co., Ltd
+8618339805032 alfa4@alfachem.cn China 12755 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418684 +8618949823763 sales@tnjchem.com China 25363 58
Hebei Duling International Trade Co. LTD
+8618032673083 sales05@hbduling.cn China 15745 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18457 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490 info@gihichemicals.com China 49999 58

View Lastest Price from Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate pictures 2020-01-14 Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate
71301-98-9
US $7.00 / KG 1KG 99% 1000kg Career Henan Chemical Co

71301-98-9(Ethyl (R)-(+)-2-(4-hydroxyphenoxy)propionate)Related Search:

Ethyl(R)-(+)-2-(4-hydroxyphenoxy)propanoate (R)-ethyl 2-(4-hydroxyphenoxy)propanoate (R)-2-(4-Hydroxyphenoxy)propionic acid ethyl ester (R)-2-(p-Hydroxyphenoxy)propionic acid ethyl ester Propanoic acid, 2-(4-hydroxyphenoxy)-, ethyl ester, (2R)- Ethyl 2(R)-(4-Hydroxy-phenoxy)-propionate 71301-98-9