ChemicalBook >> CAS DataBase List >>Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)

CAS No.
374067-51-3
Chemical Name:
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
Synonyms
(R)-Ru(OAc)2(H8-BINAP);Diacetato[(R)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95%;Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]
CBNumber:
CB41181058
Molecular Formula:
C48H48O4P2Ru
Molecular Weight:
851.909842
MDL Number:
MFCD09753023
MOL File:
374067-51-3.mol
Last updated:2023-04-23 13:52:06

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Properties

Melting point >100°C
storage temp. 2-8°C
form Powder
color olive
Sensitive air sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692166 (R)-Ru(OAc)2(H8-BINAP) 374067-51-3 100mg $76.4 2024-03-01 Buy
Sigma-Aldrich 692166 (R)-Ru(OAc)2(H8-BINAP) 374067-51-3 50mg $108 2023-06-20 Buy
Strem Chemicals 44-0166 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap] 374067-51-3 50mg $83 2024-03-01 Buy
Strem Chemicals 44-0166 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap] 374067-51-3 250mg $332 2024-03-01 Buy
TRC R701845 (R)-Rutheniumdiacetate-(H8-BINAP) 374067-51-3 250mg $990 2021-12-16 Buy
Product number Packaging Price Buy
692166 100mg $76.4 Buy
692166 50mg $108 Buy
44-0166 50mg $83 Buy
44-0166 250mg $332 Buy
R701845 250mg $990 Buy

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Chemical Properties,Uses,Production

Reaction

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
Reactions of 374067-51-3

Uses

(R)-Rutheniumdiacetate-(H8-BINAP) is used as a catalyst in the asymmetric hydrogenation of unsaturated carboxylic acids in supercritical carbon dioxide fluid.

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Suppliers

Global( 26)Suppliers
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career henan chemical co
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Chongqing Chemdad Co., Ltd
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changzhou huayang technology co., ltd
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Alfa Chemistry
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Hangzhou MolCore BioPharmatech Co.,Ltd.
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Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60

View Lastest Price from Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) pictures 2019-08-09 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
374067-51-3
US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) (R)-Ru(OAc)2(H8-BINAP) Diacetato[(R)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap] Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95% 374067-51-3 C48H46O4P2Ru Ru