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Lead monoxide

Chemical properties Toxicity Uses Production method Hazards & Safety Information
Lead monoxide
Lead monoxide
CAS No.
1317-36-8
Chemical Name:
Lead monoxide
Synonyms
massicot;LITHARGE;RED LEAD;c.i. 77577;massicotite;lithargepure;leadmonooxide;litharge(SnO);Litharge(PbO);leadprotoxide
CBNumber:
CB4119629
Molecular Formula:
OPb
Formula Weight:
223.1994
MOL File:
1317-36-8.mol

Lead monoxide Properties

Melting point:
886 °C(lit.)
Boiling point:
1470 °C
Density 
9.53
vapor pressure 
10 mm Hg ( 0 °C)
refractive index 
2.67
storage temp. 
Store below +30°C.
solubility 
Soluble in concentrated alkali, HCl and ammonium chloride. Insoluble in dilute alkali and alcohol.
form 
powder
color 
yellow
PH
8-9 (100g/l, H2O, 20℃)(slurry)
Water Solubility 
Soluble in concentrated alkali, hydrochloric acid, and ammonium chloride. Insoluble in water, dilute alkali and alcohol.
Merck 
14,5413
Stability:
Stable. Reacts violently with hydrogen peroxide, strong oxidizing agents, aluminium, zirconium, halogens, sulphur trioxide, boron, silicon, sodium, zinc.
CAS DataBase Reference
1317-36-8(CAS DataBase Reference)
NIST Chemistry Reference
Lead monoxide(1317-36-8)
EPA Substance Registry System
Lead oxide (PbO)(1317-36-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N
Risk Statements  61-20/22-33-50/53-62
Safety Statements  53-45-60-61
RIDADR  UN 2291 6.1/PG 3
WGK Germany  3
RTECS  OG1750000
TSCA  Yes
HS Code  2824 10 00
HazardClass  6.1(b)
PackingGroup  III
Hazardous Substances Data 1317-36-8(Hazardous Substances Data)
Toxicity LD50 i.p. in rats: 40 mg Pb/100g (Bradley, Fredrick)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H362 May cause harm to breast-fed children Reproductive toxicity, effects on or via lactation Additional category P201, P260, P263, P264, P270,P308+P313
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P263 Avoid contact during pregnancy/while nursing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.

Lead monoxide price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 15338 Lead(II) oxide puriss. p.a., ≥99.0% (KT), yellow 1317-36-8 50g $37.2 2018-11-13 Buy
Sigma-Aldrich 15338 Lead(II) oxide puriss. p.a., ≥99.0% (KT), yellow 1317-36-8 1kg $139 2018-11-13 Buy
Alfa Aesar 010728 Lead(II) oxide, Puratronic?, 99.9995% (metals basis) 1317-36-8 25g $149 2018-11-16 Buy
Alfa Aesar 010728 Lead(II) oxide, Puratronic?, 99.9995% (metals basis) 1317-36-8 100g $487 2018-11-16 Buy
Strem Chemicals 93-8219 Lead(II) oxide (99.999+%-Pb) PURATREM 1317-36-8 50g $173 2018-11-13 Buy

Lead monoxide Chemical Properties,Uses,Production

Chemical properties

Yellow tetragonal powder; insoluble in water and ethanol; soluble in acetone, nitric acid, caustic soda and ammonium chloride.

Toxicity

(1) see lead monoxide
(2) The early poisoning symptom is that lead lines appear on the edge of the gums, which may not appear when obviously poisoning, and the skin is soil gray. Neurasthenic syndrome will also emerge in the early period of poisoning. The cerebellar poisoning can result in lead poisoning depression, lead poisoning mania, as well as lead toxicity and paralysis sensitivity multiple neuritis. The lead poisoning can also cause hypochromic anemia and metabolic and endocrine disorders. Moreover, the lead poisoning can inhibit the activity of certain enzymes in digestive system and cause indigestion, abdominal severe pain and liver damage. And it can also cause high blood pressure and cholesterol increasing.
If there is severe abdominal pain, some measures can be taken, such as subcutaneous injection of atropine and other drugs, abdominal warm, enema, hot water bath and so on.
The maximum allowable concentration in air is 0.01 mg/m3.
Wearing mask in operation can block 95% to 97% of lead dust. When steam concentration is high, the filter-type gas mask or hose-type gas masks can be used to mandatorily supply fresh air. In the workplace, eating and smoking are prohibited during working hours. It is essential to take a shower after work and gargle and brush your teeth before meals and after work. After bathing, the lead on the hands or other contaminated parts should also be washed with 1% acetic acid solution. People who have symptoms of lead poisoning should be temporarily out of work, and serious people should be exchanged to the operating post long-termly exposed to lead.

Uses

1. Lead oxide is Mainly used in electron tubes, picture tubes, optical glass, anti-X-ray lead glass and radiation-resistant rubber products.
2. Used in smelting metal lead and preparing lead glass, lead compound, catalyst and paint drier.
3. Used as analytical reagents, silicate flux, but also for the precipitation of amino acids
4. Lead oxide is used in the manufacture of PVC plastic stabilizer and also is the raw materials of other lead salts. In the paint industry, it can be used with oil to make lead soap for paint driers. It can also be used in the manufacture of high refractive index optical glass, ceramic enamel, plane grinding agent of precision machine tool, medical raw materials and rubber coloring agent. It is also used for battery plate manufacturing, oil refining and so on.
5. Used as pigments, metallurgical fluxes and paint driers, and also used in petroleum, rubber, glass, enamel and other industries
6. Used as fluxing agents of decomposing silicate and metallurgy and paint driers, and also used for determination of gold and silver and precipitation of amino acids. It can be blended with glycerol to produce hard materials as adhesives in glass and rubber industry.

Production method

(1) Lead oxidation method: heat lead for melting to make lead tablets, and then grind at 170~210℃ and roast for oxidation at high temperature above 600℃. The oxide products are grind to obtain the finished lead oxide.
2Pb + O2→2PbO
(2) The lead oxidation method sees "lead monoxide".

Hazards & Safety Information

Category Toxic substances
Toxicity classification  high toxicity
Acute toxicity
Peritoneal-rat LDL0: 430 mg/kg; Abdominal-mouse LD50: 217 mg/kg
Stimulation Data Skin-Rabbit 100 mg/24 h mild
Flammability Hazardous properties
Non-combustible materials; heated to produce toxic lead-containing fumes
Storage and transportation characteristics
Stored in the low-temperature, well-ventilated and dry warehouse and stored separately with food additives
Fire extinguishing agent water, foam, sand, carbon dioxide
Occupational Standard TLV-TWA 0.15 mg (lead)/m3; STEL 0.04 mg (lead)/m3

Chemical Properties

light yellow-orange powder

Uses

Assay of gold and silver ores.

Uses

In ointments, plasters; preparing solution of lead subacetate. Glazing pottery; glass flux for painting on porcelain and glass; lead glass; varnishes; with glycerol as metal cement; producing iridescent colors on brass and bronze; coloring sulfur-containing substances, e.g., hair, nails, wool, horn; manufacture of artificial tortoise shell and horn; pigment for rubber; manufacture of boiled linseed oil; in assay of gold and silver ores.

General Description

Odorless gray or yellow green or red-brown solid. Sinks in water.

Reactivity Profile

Lead monoxide has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive. Aluminum carbide is oxidized with incandescence on warming with lead oxide, [Mellor, 1946, Vol. 5, 872]. Mixtures of lead oxide with aluminum powder(as with other metals: sodium, zirconium) give a violent explosions, [Mellor, 1946, Vol. 5, 217, 1941].

Health Hazard

General symptoms of lead poisoning (delayed). Inhalation or ingestion causes abdominal pain (lead colic), metallic taste in mouth, loss of weight, pain in muscles, and muscular weakness. Dust may irritate eyes.

Purification Methods

Higher oxides are removed by heating under vacuum at 550o with subsequent cooling under vacuum. It is red at room temperature but becomes yellow at high temperatures (~480o) reversibly. [Ray & Ogg J Am Chem Soc 78 5994 1956, Kwestroo et al. J Inorg Nucl Chem 29 39 1967.]

Lead monoxide Preparation Products And Raw materials

Raw materials

Preparation Products


Lead monoxide Suppliers

Global( 169)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40399 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 1443 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44192 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 12609 60
Suzhou Kaiyuan Minsheng Sci&Tech Corp. Ltd. +86-512-62889106
+86-512-62889738 marketing@minshengpharm.com China 97 66
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10088 60

View Lastest Price from Lead monoxide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-18 Lead monoxide
1317-36-8
US $2.00 / kg 1kg 99% ask career henan chemical co

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