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2-Bromoaniline

CAS No.
615-36-1
Chemical Name:
2-Bromoaniline
Synonyms
O-BROMOANILINE;2-Bromoanilines;2-bromobenzenamine;1-Amino-2-bromobenzene;2-BromoaniL;2-BROMOANILINE;BROMOANILINE(2-);Aniline, o-bromo-;AKOS BBS-00003650;2-bromo-benzenamin
CBNumber:
CB4140711
Molecular Formula:
C6H6BrN
Molecular Weight:
172.02
MDL Number:
MFCD00007632
MOL File:
615-36-1.mol
MSDS File:
SDS
Last updated:2023-12-24 21:24:35

2-Bromoaniline Properties

Melting point 24-28 °C (lit.)
Boiling point 229 °C (lit.)
Density 1.52 g/mL at 25 °C (lit.)
refractive index 1.617-1.619
Flash point >230 °F
storage temp. 2-8°C
solubility 0.949g/l
form Liquid After Melting
pka 2.53(at 25℃)
color Clear yellow to red-brown
Water Solubility Insoluble in water.
BRN 742062
InChIKey AOPBDRUWRLBSDB-UHFFFAOYSA-N
CAS DataBase Reference 615-36-1(CAS DataBase Reference)
FDA UNII VTP98DS78E
NIST Chemistry Reference Benzenamine, 2-bromo-(615-36-1)
EPA Substance Registry System Benzenamine, 2-bromo- (615-36-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H302+H312+H332-H373-H410
Precautionary statements  P273-P280-P301+P312-P302+P352+P312-P304+P340+P312-P314
Hazard Codes  T,Xn
Risk Statements  23/24/25-33-52/53-36/37/38-20/21/22-24/25
Safety Statements  36/37-45-61-36/37/39-26
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
8-23
Hazard Note  Toxic
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29214210
NFPA 704
1
3 0

2-Bromoaniline price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B56420 2-Bromoaniline 98% 615-36-1 5g $14.56 2024-03-01 Buy
Sigma-Aldrich B56420 2-Bromoaniline 98% 615-36-1 25g $71.9 2024-03-01 Buy
TCI Chemical B0541 2-Bromoaniline >98.0%(GC)(T) 615-36-1 25g $44 2024-03-01 Buy
TCI Chemical B0541 2-Bromoaniline >98.0%(GC)(T) 615-36-1 250g $254 2024-03-01 Buy
Alfa Aesar A11788 2-Bromoaniline, 98% 615-36-1 25g $58.65 2024-03-01 Buy
Product number Packaging Price Buy
B56420 5g $14.56 Buy
B56420 25g $71.9 Buy
B0541 25g $44 Buy
B0541 250g $254 Buy
A11788 25g $58.65 Buy

2-Bromoaniline Chemical Properties,Uses,Production

Description

O-bromoaniline, m-bromoaniline and p-bromoaniline corresponds to the three isomers of bromoaniline. All of them three are toxic with its toxicity being more severe than chloroanilines. It can be all via percutaneous absorption, being hemolytic and able to cause bladder cancer. It is mainly used for dye raw materials, such as azo dyes, quinazoline dyes and so on. Heating together with glycerol, concentrated sulfuric acid and o-bromonitrobenzene can generate 8-bromoquinoline.
The preparation of the three isomers is as follows:

  1. Take the corresponding nitroaniline as raw material, have it reacted with sodium nitrite in sulfuric acid, leading to the formation of diazonium salt, followed by reaction with hydrobromic acid under the action of cuprous bromide, leading to the formation of nitrobromobenzene, further subjecting to iron powder reaction in the bromic acid to generate the above three isomers.
  2. Take benzene as raw material, under the action of iron powder, have it reacted with bromine to generate bromobenzene. It is then reacted with mixed acid (the mixture of sulfuric acid and nitric acid) to generate o-nitrobenzene and p-nitro bromobenzene (orthoaccounts of 35%; paraaccounts of 65%), so that the two are separated, followed by the same process as method one to generate o-bromoaniline and p-bromoaniline.
  3. Take bromoacetanilide as raw material, put it into sodium hydroxide solution; apply water vapor reflux to obtain the bromoaniline.

Chemical Properties

It appears as white needle crystal with a melting point of 32 ° C, boiling point of 229 ° C, 138-141 ° C (6.38-6.92 kPa), 110.5 ° C (2.53 kPa), relative density of 1.578 (20/4 ° C) and a refractive index of 1.6133. It is soluble in alcohol and ether, but can’t be dissolved in water.

Uses

Organic synthesis intermediates

Chemical Properties

CLEAR YELLOW TO RED-BROWN LIQUID AFTER MELTING

Uses

2-Bromoaniline is used as a corrosion inhibitor, emulsifying and antiseptic agents. It is used in the rubber industry, e.g. diphenylguanidines, phenylenediamines mercaptobenzothiazoles, aniline ketones and etc.

Global( 463)Suppliers
Supplier Tel Email Country ProdList Advantage
Changzhou Zechong Biopharma Co., Ltd.
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Henan Fengda Chemical Co., Ltd
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ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Zhejiang ZETian Fine Chemicals Co. LTD
18957127338 stella@zetchem.com China 2141 58

View Lastest Price from 2-Bromoaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromoaniline pictures 2023-12-24 2-Bromoaniline
615-36-1
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-Bromoaniline pictures 2023-04-29 2-Bromoaniline
615-36-1
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
2-Bromoaniline pictures 2023-01-31 2-Bromoaniline
615-36-1
US $0.00 / Kg/Bag 1Kg/Bag 99% 20ton Hebei Mojin Biotechnology Co., Ltd
  • 2-Bromoaniline pictures
  • 2-Bromoaniline
    615-36-1
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • 2-Bromoaniline pictures
  • 2-Bromoaniline
    615-36-1
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • 2-Bromoaniline pictures
  • 2-Bromoaniline
    615-36-1
  • US $0.00 / Kg/Bag
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
2-bromo-benzenamin Aniline, o-bromo- Benzenamine,2-bromo- o-Aminobromobenzene o-Chloroaceto-N-acetanilide 2-BROMOANILINE BROMOANILINE(2-) o-Bromoaniline 2-Bromoaniline 2-BROMOANILINE 99% 2-Bromoaniline,~98% 2-BROMO ANILINE FOR SYNTHESIS ORTHO-BROMOANILINE 2-Bromo-phenylamine AKOS BBS-00003650 2-Bromobenzeneamine 2-Amino-1-bromobenzene -Aminobromobenzene 2-Bromoaniline ,99% 2-BA : 2-BroMoaniline 2-BroMoaniline, 98% 25GR Aniline adjacent broMide 1-Amino-2-bromobenzene o-Bromoaniline 2-BromoaniL 2-Bromoaniline > 2-Bromoaniline ISO 9001:2015 REACH O-BROMOANILINE 2-bromobenzenamine 2-Bromoanilines 1-Amino-2-bromobenzene Vortioxetine Impurity 49 Phloroglucinol Impurity 10 Vortioxetine Hydrobromide impurity A Vostine Hydrobromide Impurity 1 Vortioxetine Impurity 61 2-Bromoaniline, ≥ 98.0% 615-36-1 615-76-6 2615-36-1 651-36-1 H2NC6H4Br C6H4NH2Br C2 to C6 Nitrogen Compounds Organic Building Blocks Building Blocks Amines amine | alkyl bromide Amines blocks Bromides Anilines, Aromatic Amines and Nitro Compounds Miscellaneous Anilines, Amides & Amines Bromine Compounds C2 to C6 Nitrogen Compounds bc0001 Apinno