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COBALT(II) BROMIDE

CAS No.
7789-43-7
Chemical Name:
COBALT(II) BROMIDE
Synonyms
CoBr2;COBALT BROMIDE;dibromocobalt;cobaltdibromide;COBALTOUS BROMIDE;COBALT(+2)BROMIDE;Cobalt(Ⅱ) Bromide;COBALT(II) BROMIDE;Cobalt(ll) bromide;Mancobride mancanese
CBNumber:
CB4144320
Molecular Formula:
Br2Co
Lewis structure
cobr2 lewis structure
Molecular Weight:
218.74
MDL Number:
MFCD00016017
MOL File:
7789-43-7.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

COBALT(II) BROMIDE Properties

Melting point 678°C
Density 4.909 g/mL at 25 °C(lit.)
solubility acetone: soluble(lit.)
form beads
color Green
Specific Gravity 4.909
Water Solubility Soluble in water. Soluble in methyl acetate, ether, alcohol, acetone.
Sensitive Hygroscopic
Merck 14,2435
Exposure limits ACGIH: TWA 0.02 mg/m3
CAS DataBase Reference 7789-43-7(CAS DataBase Reference)
FDA UNII 7M7RX75BAL
EPA Substance Registry System Cobalt bromide (7789-43-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H317-H334-H341-H350-H410
Precautionary statements  P202-P273-P280-P301+P312-P302+P352-P308+P313
Hazard Codes  T,Xn
Risk Statements  45-20/21/22-36/37/38-42/43
Safety Statements  36-45-36/37/39-26-22-53
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
RTECS  GF9595000
TSCA  Yes
NFPA 704
0
2 1

COBALT(II) BROMIDE price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 334022 Cobalt(II) bromide 99% 7789-43-7 50g $83.8 2024-03-01 Buy
Sigma-Aldrich 334022 Cobalt(II) bromide 99% 7789-43-7 250g $332 2024-03-01 Buy
Alfa Aesar 023149 Cobalt(II) bromide, anhydrous, 97% 7789-43-7 50g $89.2 2024-03-01 Buy
Alfa Aesar 023149 Cobalt(II) bromide, anhydrous, 97% 7789-43-7 250g $390 2024-03-01 Buy
Sigma-Aldrich 427136 Cobalt(II) bromide anhydrous, beads, 10 mesh, 99.99% trace metals basis 7789-43-7 1g $102 2024-03-01 Buy
Product number Packaging Price Buy
334022 50g $83.8 Buy
334022 250g $332 Buy
023149 50g $89.2 Buy
023149 250g $390 Buy
427136 1g $102 Buy

COBALT(II) BROMIDE Chemical Properties,Uses,Production

Chemical Properties

The green anhydrous salt is prepared by dehydration of the red hexahydrate or by the action of bromine on heated cobalt. It is very soluble in water and soluble in many polar organic solvents; it deliquesces in moist air to a red solution. The hexahydrate crystallizes from aqueous solution at room temperature; it melts at 100°, evolving water and forming the purple dihydrate.

Chemical Properties

Reddish violet crystalline powder

Uses

Cobalt(II) bromide is used as a catalyst in organic synthesis. It is used as a precursor in the production of ethylsulfanyl)porphyrazinato)cobalt(II), which gives the possibility of intermolecular ferromagnetic interactions.

Uses

Used in the preparation of a new complex, Co(OESPz), which offers the possibility of intermolecular ferromagnetic interactions.1

General Description

COBALT(II) BROMIDE is a red violet crystalline solid. COBALT(II) BROMIDE is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. COBALT(II) BROMIDE is used as a catalyst in the production of other chemicals.

Air & Water Reactions

Water soluble.

Reactivity Profile

Acidic salts, such as COBALT(II) BROMIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. When heated to decomposition can give off highly toxic fumes of Br [USCG, 1999].

Health Hazard

SOLID: Irritating to skin and eyes. Harmful if swallowed.

Fire Hazard

Not flammable. POISONOUS FUMES ARE PRODUCED WHEN HEATED TO DECOMPOSITION. When heated to decomposition can give off highly toxic fumes of Br.

Purification Methods

Crystallise it from water (1mL/g) by partial evaporation in a desiccator. The anhydrous salt is soluble in EtOH, Me2CO, MeOAc to form blue-coloured solutions. [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1517 1965.]

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COBALT(+2)BROMIDE COBALTOUS BROMIDE Cobalt(Ⅱ) Bromide, Anhydrous Cobalt(II) bromide, anhydrous≥ 98% (Metal basis) Cobalt bromide (CoBr2) cobalt(ii)bromideanhydrous cobaltbromide(cobr2) cobaltdibromide Mancobride mancanese COBALT BROMIDE, ANHYDROUS REAGENT COBALTOUS BROMIDE HYDRATE COBALT(II) BROMIDE, ANHYDROUS, 99.99% Cobalt(II)bromide,ultradry,99.99%(metalsbasis) cobalt(ii) bromide, ultra dry Cobalt(II) bromide, anhydrous, Co 26.6% min Cobaltous bromide: (Cobalt(II) bromide) Cobaltous bromide anhydrous Cobalt bromide 1g [7789-43-7] Cobalt(II) dibromide Cobalt(II) bromide 99% Cobalt(Ⅱ) Bromide COBALT(II) BROMIDE COBALT(II) BROMIDE ISO 9001:2015 REACH Cobalt(II) bromide Beads dibromocobalt CoBr2 COBALT BROMIDE Cobalt(ll) bromide Anhydrous COBALT(II) BROMIDE 7789-43-7 CoBr26H2O Cobalt Salts CobaltMetal and Ceramic Science Crystal Grade Inorganics Metal and Ceramic Science Salts 27: Co Beaded Materials Cobalt Cobalt Salts Crystal Grade Inorganics Materials Science Metal and Ceramic Science