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m-Anisidine

m-Anisidine
m-Anisidine structure
CAS No.
536-90-3
Chemical Name:
m-Anisidine
Synonyms
JABJM;m-Anisidin;m-anisidien;3-ANISIDINE;M-ANISIDINE;3-Anisidine 0;m-Anisylamine;3-AMINOANISOLE;META-ANISIDINE;M-AMINOANISOLE
CBNumber:
CB4203315
Molecular Formula:
C7H9NO
Formula Weight:
123.15
MOL File:
536-90-3.mol

m-Anisidine Properties

Melting point:
−1-1 °C(lit.)
Boiling point:
251 °C(lit.)
Density 
1.096 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.581(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
18g/l
form 
Liquid
pka
4.23(at 25℃)
color 
Clear yellow to brown
Water Solubility 
<0.1 g/100 mL at 19 ºC
Sensitive 
Light Sensitive
Merck 
14,667
BRN 
386119
InChIKey
NCBZRJODKRCREW-UHFFFAOYSA-N
CAS DataBase Reference
536-90-3(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
JXA144KX2I
NIST Chemistry Reference
Benzenamine, 3-methoxy-(536-90-3)
EPA Substance Registry System
m-Anisidine (536-90-3)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS09,GHS06,GHS08
Signal word  Warning
Hazard statements  H400-H301+H311+H331-H371-H372-H302-H315-H319-H335-H410
Precautionary statements  P260-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P308+P311-P391-P403+P233-P405-P261-P273-P305+P351+P338-P501-P280a-P304+P340-P501a
Hazard Codes  Xn,N,T+
Risk Statements  22-36/37/38-50/53-51/53-33-26/27/28
Safety Statements  26-60-61-45-36/37-28B
RIDADR  UN 2431 6.1/PG 3
WGK Germany  1
RTECS  BZ5408000
8
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29222200
Toxicity cyt-ham:ovr 160 mg/L EMMUEG 10(Suppl 10),1,87
NFPA 704
1
2 0

m-Anisidine price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich A88204 m-Anisidine 97% 536-90-3 5g $27.9 2021-03-22 Buy
Sigma-Aldrich A88204 m-Anisidine 97% 536-90-3 1kg $403 2021-03-22 Buy
TCI Chemical A0485 m-Anisidine >98.0%(GC)(T) 536-90-3 25g $14 2021-03-22 Buy
TCI Chemical A0485 m-Anisidine >98.0%(GC)(T) 536-90-3 100g $28 2021-03-22 Buy
Alfa Aesar A10815 m-Anisidine, 98% 536-90-3 50g $37.2 2021-03-22 Buy

m-Anisidine Chemical Properties,Uses,Production

Chemical Properties

Light yellow liquid.

Chemical Properties

Anisidine exists as ortho-, meta-, and paraisomers. They have characteristic amine (fishy) odors.

Uses

m-Anisidine is a highly poisonous monosubstituted aniline used as corrosion inhibitorsfor aluminum, copper and other metals in acidic solutions.

Synthesis Reference(s)

The Journal of Organic Chemistry, 22, p. 333, 1957 DOI: 10.1021/jo01354a610
Tetrahedron Letters, 24, p. 4121, 1983 DOI: 10.1016/S0040-4039(00)88277-5

General Description

Pale yellow oily liquid or dark red liquid.

Air & Water Reactions

m-Anisidine may be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

m-Anisidine is incompatible with strong oxidizers. m-Anisidine is also incompatible with acids, acid chlorides, acid anhydrides and chloroformates.

Fire Hazard

m-Anisidine is probably combustible.

Safety Profile

Moderately toxic by ingestion.Mutation data reported. When heated to decomposition itemits toxic vapors of NOx.

Potential Exposure

Anisidines are used in the manufacture of azo dyes; pharmaceuticals; textile-processing chemicals Incompatibilities: Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some coatings and some forms of plastic and rubber.

Shipping

UN2431 Anisidines, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

o-Isomer impurity can be removed by steam distillation. Another possible impurity is the precursor 3-nitroanisole which can be removed as for the preceding o-isomer and fractionating using an efficient column. It is a yellow liquid. [Gilman & Kyle J Am Chem Soc 74 3027 1952, Bryson J Am Chem Soc 82 4858 1960, Kadaba & Massie J Org Chem 22 333 1957, Beilstein 13 IV 953.]

Waste Disposal

Dissolve in combustible solvent (alcohols, benzene, etc.) and spray solution into furnace equipped with afterburner and scrubber, or burn spill residue on sand and soda ash absorbent in a furnace.

m-Anisidine Preparation Products And Raw materials

Raw materials

Preparation Products


m-Anisidine Suppliers

Global( 276)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29955 58
Hebei Guanlang Biotechnology Co., Ltd.
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sales3@crovellbio.com China 5902 58
Chongqing Chemdad Co.,Ltd
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Shanghai Longyu Biotechnology Co., Ltd.
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Chongqing Chemdad Co., Ltd
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Alchem Pharmtech,Inc.
8485655694
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HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47498 58

View Lastest Price from m-Anisidine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-12-01 M-Anisidine
536-90-3
US $2.00 / KG/Tin 10g 99 % 10000kg Hebei Crovell Biotech Co Ltd
2021-06-25 m-Anisidine
536-90-3
US $10.00 / ASSAYS 1ASSAYS 99% 100 mt Hebei Guanlang Biotechnology Co., Ltd.
2019-07-06 m-Anisidine
536-90-3
US $8.00 / kg 1kg 99% 10MT career henan chemical co

m-Anisidine Spectrum


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