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m-Anisidine

m-Anisidine
m-Anisidine structure
CAS No.
536-90-3
Chemical Name:
m-Anisidine
Synonyms
m-Anisidin;m-anisidien;3-ANISIDINE;M-ANISIDINE;3-Anisidine 0;m-Anisylamine;3-AMINOANISOLE;META-ANISIDINE;M-AMINOANISOLE;m-Anisidine,99%
CBNumber:
CB4203315
Molecular Formula:
C7H9NO
Formula Weight:
123.15
MOL File:
536-90-3.mol

m-Anisidine Properties

Melting point:
−1-1 °C(lit.)
Boiling point:
251 °C(lit.)
Density 
1.096 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.581(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
18g/l
pka
4.23(at 25℃)
form 
Liquid
color 
Clear yellow to brown
Water Solubility 
<0.1 g/100 mL at 19 ºC
Sensitive 
Light Sensitive
Merck 
14,667
BRN 
386119
CAS DataBase Reference
536-90-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 3-methoxy-(536-90-3)
EPA Substance Registry System
Benzenamine, 3-methoxy-(536-90-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,N,T+
Risk Statements  22-36/37/38-50/53-51/53-33-26/27/28
Safety Statements  26-60-61-45-36/37-28B
RIDADR  UN 2431 6.1/PG 3
WGK Germany  1
RTECS  BZ5408000
8
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29222200
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P391 Collect spillage. Hazardous to the aquatic environment
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

m-Anisidine price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich A88204 m-Anisidine 97% 536-90-3 5g $26.1 2018-11-20 Buy
Sigma-Aldrich A88204 m-Anisidine 97% 536-90-3 1kg $364 2018-11-20 Buy
TCI Chemical A0485 m-Anisidine >98.0%(GC)(T) 536-90-3 25g $14 2018-11-22 Buy
TCI Chemical A0485 m-Anisidine >98.0%(GC)(T) 536-90-3 100g $30 2018-11-22 Buy
Alfa Aesar A10815 m-Anisidine, 98% 536-90-3 50g $33.7 2018-11-13 Buy

m-Anisidine Chemical Properties,Uses,Production

Chemical Properties

Light yellow liquid.

Chemical Properties

Anisidine exists as ortho-, meta-, and paraisomers. They have characteristic amine (fishy) odors.

Uses

m-Anisidine is a highly poisonous monosubstituted aniline used as corrosion inhibitorsfor aluminum, copper and other metals in acidic solutions.

General Description

Pale yellow oily liquid or dark red liquid.

Air & Water Reactions

m-Anisidine may be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

m-Anisidine is incompatible with strong oxidizers. m-Anisidine is also incompatible with acids, acid chlorides, acid anhydrides and chloroformates.

Fire Hazard

m-Anisidine is probably combustible.

Potential Exposure

Anisidines are used in the manufacture of azo dyes; pharmaceuticals; textile-processing chemicals Incompatibilities: Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some coatings and some forms of plastic and rubber.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN2431 Anisidines, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

o-Isomer impurity can be removed by steam distillation. Another possible impurity is the precursor 3-nitroanisole which can be removed as for the preceding o-isomer and fractionating using an efficient column. It is a yellow liquid. [Gilman & Kyle J Am Chem Soc 74 3027 1952, Bryson J Am Chem Soc 82 4858 1960, Kadaba & Massie J Org Chem 22 333 1957, Beilstein 13 IV 953.]

Waste Disposal

Dissolve in combustible solvent (alcohols, benzene, etc.) and spray solution into furnace equipped with afterburner and scrubber, or burn spill residue on sand and soda ash absorbent in a furnace.

m-Anisidine Preparation Products And Raw materials

Raw materials

Preparation Products


m-Anisidine Suppliers

Global( 211)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Chongqing Chemdad Co.,Ltd
+86-19923101450
sales@chemdad.com CHINA 297 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24001 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19923 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24560 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3395 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44046 61

View Lastest Price from m-Anisidine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-17 m-Anisidine
536-90-3
US $8.00 / kg 1kg 99% 10MT career henan chemical co

m-Anisidine Spectrum


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