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SALCOMINE structure
Chemical Name:
Molecular Formula:
Formula Weight:
MOL File:

SALCOMINE Properties

Water Solubility 
Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stable. Incompatible with strong acids, strong oxidizing agents.
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  2
RTECS  GG0590000
HS Code  29349990
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

SALCOMINE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 274712 N,N′-Bis(salicylidene)ethylenediaminocobalt(II) 99% 14167-18-1 1g $48.4 2018-11-13 Buy
Sigma-Aldrich 274712 N,N′-Bis(salicylidene)ethylenediaminocobalt(II) 99% 14167-18-1 5g $169 2018-11-13 Buy
TCI Chemical S0318 Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)] >95.0%(T) 14167-18-1 25g $93 2018-11-22 Buy
TCI Chemical S0318 Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)] >95.0%(T) 14167-18-1 100g $247 2018-11-22 Buy
Alfa Aesar 043174 N,N'-Bis(salicylidene)ethylenediaminecobalt(II), 96% 14167-18-1 1g $13.8 2018-11-16 Buy

SALCOMINE Chemical Properties,Uses,Production

Chemical Properties

black crystalline powder

General Description

A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.

Reactivity Profile

SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.

Purification Methods

The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]

SALCOMINE Preparation Products And Raw materials

Raw materials

Preparation Products


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