Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>MN(TMHD)3

MN(TMHD)3

MN(TMHD)3 Structure
MN(TMHD)3 structure
CAS No.
14324-99-3
Chemical Name:
MN(TMHD)3
Synonyms
Mn(dpm)3;Tris(dipivaloylmethanato)manganese;Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese;manganic;MN(TMHD)3;anese(III);-3,5-heptanedionato)mang;Tris(2,2,6,6-tetramethyL;Shenvi Hydrogenation Catalyst;-3,5-heptanedionato)manganese(III)
CBNumber:
CB4241944
Molecular Formula:
C33H57MnO6
Molecular Weight:
604.74
MDL Number:
MFCD00269825
MOL File:
14324-99-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:58:17
Product description Number Pack Size Price
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) 97% 700223 1g $63.8
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) T4217 1G $87
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) T4217 5G $262
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3] 25-5000 1g $55
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3] 25-5000 5g $218
Request For Quotation

MN(TMHD)3 Properties

Melting point 165°C
Boiling point 255°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color black
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
InChI 1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChIKey ORZPLLPBZHORSD-LWTKGLMZSA-K
SMILES CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36/37
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MN(TMHD)3 price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 700223 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) 97% 14324-99-3 1g $63.8 2026-03-19 Buy
TCI Chemical T4217 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) 14324-99-3 1G $87 2026-03-19 Buy
TCI Chemical T4217 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) 14324-99-3 5G $262 2026-03-19 Buy
Strem Chemicals 25-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3] 14324-99-3 1g $55 2024-03-01 Buy
Strem Chemicals 25-5000 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3] 14324-99-3 5g $218 2024-03-01 Buy
Product number Packaging Price Buy
700223 1g $63.8 Buy
T4217 1G $87 Buy
T4217 5G $262 Buy
25-5000 1g $55 Buy
25-5000 5g $218 Buy

MN(TMHD)3 Chemical Properties,Uses,Production

Uses

Catalyst for:

  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol

reaction suitability

core: manganese
reagent type: catalyst

Synthesis

To a mixture of manganese (II) sulfate monohydrate (1.5 g, 9 mmol, 1.0 eq) and 2,2,6,6-tetramethyl-3,5-heptanedione (5.0 g, , 27 mmol, 4.0 eq) in water (30 mL) and methanol (6 mL) was added dropwise a concentrated ammonia solution (12 ) at room temperature. 27 mmol, 4.0 eq) in a mixture of water (30 mL) and methanol (6 mL) were added dropwise to a concentrated ammonia solution (12 ), resulting in an immediate decrease in the amount of ammonia in the mixture. mL), resulting in the immediate formation of a dark olive green/brown precipitate. The precipitate was filtered out, washed with water (3x10mL) and dried under vacuum for 24 hours to give Mn(dpm)3 (4.9 g, 90%). . X-ray mass crystals of the complex were obtained from isopropanol, which showed the structure to be tris(2,2,6,6-tetramethyl-3,5-heptenoic acid) manganese in yield (4.9 g, 90%).

MN(TMHD)3 Preparation Products And Raw materials

Raw materials

Preparation Products

MN(TMHD)3 Suppliers

Global( 92)Suppliers
Supplier Tel Email Country ProdList Advantage
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49977 58
Zhengzhou Alfa Chemical Co.,Ltd 		+8618530059196 sale04@alfachem.cn China 9546 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Hunan russell chemicals technology co ltd 		731-88557738 +8613739093081 sales01@russellchem.com CHINA 291 58
Xi'an MC Biotech, Co., Ltd. 		029-89275612 +8618991951683 mcbio_sales@163.com China 2251 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
HANGZHOU LEAP CHEM CO., LTD. 		+86-571-87711850 market18@leapchem.com China 24597 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18126 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD 		+86-0512-83500002 +8618662433356 3899766280@qq.com China 26362 58
Supplier Advantage
Accela ChemBio Inc. 		58
CONIER CHEM AND PHARMA LIMITED 		58
Zhengzhou Alfa Chemical Co.,Ltd 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Hunan russell chemicals technology co ltd 		58
Xi'an MC Biotech, Co., Ltd. 		58
Labnetwork lnc. 		58
HANGZHOU LEAP CHEM CO., LTD. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
SUZHOU SENFEIDA CHEMICAL CO.,LTD 		58

MN(TMHD)3 Spectrum

MN(TMHD)3(14324-99-3)1HNMR

14324-99-3(MN(TMHD)3)Related Search:

RU(TMHD)3 GD(TMHD)3 TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)ALUMINUM INDIUM (2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) ERBIUM TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)THULIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)COBALT (III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTRIUM(III) PR(TMHD)3 TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SCANDIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTERBIUM TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SAMARIUM(III) ND(TMHD)3 3-HEPTENOIC ACID
MN(TMHD)3 MANGANESE(II) ACETYLACETONATE Manganic acetylacetonate

1of4

MN(TMHD)3 TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese (III), (Mn(TMHD)3) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) 99% [MN(TMHD)3] Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(II) Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) manganese (III) Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III) Tris(2,2,6,6tetramethyl-3,5-heptanedionato)manganese(Ⅲ) Manganese tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Tris(tetramethylheptanedionato)manganese Tris-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O'')-manganese 2,2,6,6-TetraMethyl-3,5-heptanedionate(III)Manganese MANGANESE(lll) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE Shenvi Hydrogenation Catalyst Manganese(III)tris(2,2,6,6-tetramethyl-3,5-heptanedionate) tris(((Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-yl)oxy)manganese MANGANESE(III) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE -3,5-heptanedionato)mang anese(III) Tris(2,2,6,6-tetramethyL Tris[(2,2,6,6-tetramethyl-5-oxo-3-hepten-3-yl)oxy]manganese -3,5-heptanedionato)manganese(III) manganese(3+) ion tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate) Manganese,tris(2,2,6,6-tetramethyl-3,5-heptanedionato-kO3,kO5)-, (OC-6-11)- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese Tris(dipivaloylmethanato)manganese Mn(dpm)3 Tris (2,2,6,6- tetramethyl -3,5- heptanedioic acid) manganese Manganese tetramethylheptanedionate(Mn(thd)3) manganic tris(2,2,6,6-tetramethylheptane-3,5-dione) manganic tris(2,2,6,6-tetramethylheptane-3,5-dione) tri(tetramethylheptyldione)manganese 14324-99-3 MnCH33CCOCHCOCCH333 C33H57MnO6 MnC11H19O23 ALD Precursors metal beta-diketonate complexes