6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE
- CAS No.
- 54325-28-9
- Chemical Name:
- 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE
- Synonyms
- 6-O-Trityl-α-D-glucopyranose;6-O-TRITYL-ALPHA-D-GLUCOPYRANOSE;6-O-(Triphenylmethyl)-α-D-glucopyranose;6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE;α-D-Glucopyranose, 6-O-(triphenylmethyl)-;(2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol
- CBNumber:
- CB42451905
- Molecular Formula:
- C25H26O6
- Molecular Weight:
- 422.47
- MDL Number:
- MFCD09864629
- MOL File:
- 54325-28-9.mol
| Product description | Number | Pack Size | Price |
| 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE 95.00% | CRB0005076 | 5MG | $503.93 |
| (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | CD70000961 | 1g | $574 |
| (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol | 54325289 | 1g | $643.8 |
| (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | A476635 | 100mg | $62 |
| (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | A476635 | 250mg | $93 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| American Custom Chemicals Corporation | CRB0005076 | 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE 95.00% | 54325-28-9 | 5MG | $503.93 | 2021-12-16 | Buy |
| Crysdot | CD70000961 | (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | 54325-28-9 | 1g | $574 | 2021-12-16 | Buy |
| Alichem | 54325289 | (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol | 54325-28-9 | 1g | $643.8 | 2021-12-16 | Buy |
| Ambeed | A476635 | (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | 54325-28-9 | 100mg | $62 | 2021-12-16 | Buy |
| Ambeed | A476635 | (2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% | 54325-28-9 | 250mg | $93 | 2021-12-16 | Buy |
6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE Chemical Properties,Uses,Production
Synthesis
50-99-7
76-83-5
54325-28-9
The general procedure for the synthesis of (2S,3R,4S,5S,6R)-6-((triphenylmethoxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol from D-anhydrous glucose and triphenylmethyl chloride was as follows: D-anhydrous glucose (5 g; 0.0277 mol) was suspended in pyridine (50 mL), followed by addition of triphenylmethyl chloride. The reaction mixture was stirred at 80 °C for about 4 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) using dichloromethane: methanol (85:15) as the unfolding agent. Upon completion of the reaction, the reaction was quenched with water (100 mL) and extracted with dichloromethane (150 mL x 2). The organic layers were combined, washed with saturated aqueous sodium bicarbonate and dried over anhydrous sodium sulfate. The solvent was subsequently removed using a rotary evaporator. The target product (2S,3R,4S,5S,6R)-6-((triphenylmethoxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol (10.3 g; 88% yield) was finally obtained by milling the crude product with a hexane:ether mixture (100 mL) to remove residual triphthaloyl chloride and pyridine. The structure of the product was confirmed by LC-MS and the molecular ion peak (M+) was observed to be 446 amu.
References
[1] Patent: WO2007/54977, 2007, A2. Location in patent: Page/Page column 21
[2] Patent: KR101595939, 2016, B1. Location in patent: Paragraph 0102-0103
6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE Preparation Products And Raw materials
6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| BOC Sciences | +1-631-485-4226 | inquiry@bocsci.com | United States | 19552 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
| Wuhan Jingkang en Biomedical Technology Co., Ltd | +8613720134139 | orders@jknbiochem.com | China | 5221 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Shanghai Changyan Chem & Tech Co., Ltd. | 021-20242659 18930833303 | Sales@changyanchem.cn | China | 5001 | 55 |
| ShangHai Biochempartner Co.,Ltd | 177-54423994 17754423994 | 2853530910@QQ.com | China | 8000 | 62 |
| Amel Pharmatech Corporation | 027-888-4366503 | sales@amelpharmatech.com | China | 4998 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44918 | 58 |
| Shanghai Sunway Pharmaceutical Technology Co.,Ltd. | 021-51816796-820 13611835272 | sales2@sunwaypharm.com | China | 44113 | 58 |
| Bide Pharmatech Ltd. | 400-6005915 | sales@picasso-e.com | China | 39653 | 58 |
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