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METHYLMAGNESIUM IODIDE

CAS No.
917-64-6
Chemical Name:
METHYLMAGNESIUM IODIDE
Synonyms
CHLOROMETHYLMAGNESIUM;Methylmagnesium iodide solution;nesium iodide;iodomethylmagnesium;iodomethyl-magnesiu;Methyliodomagnesium;METHYLMAGNESIUM IODIDE;Methylmagnesium iodine;MagnesiuM, iodoMethyl-;3.0 M in diethyl ether
CBNumber:
CB4248837
Molecular Formula:
CH3IMg
Molecular Weight:
166.24
MDL Number:
MFCD00001026
MOL File:
917-64-6.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

METHYLMAGNESIUM IODIDE Properties

Density 1.26 g/mL at 20 °C
Flash point -40 °C
BRN 1209226
InChIKey AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System Magnesium, iodomethyl- (917-64-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H260-H314-H336-H225
Precautionary statements  P223-P231+P232-P261-P280-P370+P378-P422-P210
Hazard Codes  F+,C,F
Risk Statements  12-14/15-22-34-66-67-19-11
Safety Statements  16-26-36/37/39-43-45-7/8
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
1-3-10
HazardClass  4.2
PackingGroup  I
HS Code  29319090
NFPA 704
3
2 2

METHYLMAGNESIUM IODIDE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 254363 Methylmagnesium iodide solution 3.0M in diethyl ether 917-64-6 100ml $89.2 2024-03-01 Buy
Sigma-Aldrich 254363 Methylmagnesium iodide solution 3.0M in diethyl ether 917-64-6 800ml $349.6 2024-03-01 Buy
TCI Chemical M0364 Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L) 917-64-6 100G $62 2024-03-01 Buy
Sigma-Aldrich 257109 Methylmagnesium iodide solution 3.0M in diethyl ether 917-64-6 200ml $227 2021-12-16 Buy
TRC M316653 MethylmagnesiumIodide(3.0MinDiethylether) 917-64-6 10ml $45 2021-12-16 Buy
Product number Packaging Price Buy
254363 100ml $89.2 Buy
254363 800ml $349.6 Buy
M0364 100G $62 Buy
257109 200ml $227 Buy
M316653 10ml $45 Buy

METHYLMAGNESIUM IODIDE Chemical Properties,Uses,Production

Chemical Properties

Dark grey liquid

Uses

Methylmagnesium iodide solution can be used:

  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Uses

Alkylating agent in organic synthesis, Grignardreagent.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

74-88-4
917-64-6
Synthesis of METHYLMAGNESIUM IODIDE from Iodomethane
Global( 167)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9354 55
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Yurui (Shanghai) Chemical Co., Ltd.
+86-021-50456736 +8615000292053 sales209@riyngroup.com China 942 58
GLR Innovations
+91 9891111994 info@glrgroup.in India 4542 58

View Lastest Price from METHYLMAGNESIUM IODIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYLMAGNESIUM IODIDE pictures 2020-01-13 METHYLMAGNESIUM IODIDE
917-64-6
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co
METHYLMAGNESIUM IODIDE MAGNESIUM METHYL IODIDE iodomethyl-magnesiu methylmagnesiumiodidesol. Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L) iodomethylmagnesium METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER METHYLMAGNESIUM IODIDE, 3.0M SOLUTION IN DIETHYL ETHER Methylmagnesium iodide, 2-3M in diethyl ether Methylmagnesium iodide solution 3.0 M in diethyl ether Methylmagnesium iodide, 3M solution in diethyl ether, AcroSeal Methyliodomagnesium Methylmagnesium iodide,3M solution in diethylether magnesium carbanide iodide Methylmagnesium iodine Methylmagnesium iodide 3M solution in DEE MethylMagnesiuM iodide, 3.0M solution in diethyl ether, J&KSeal MagnesiuM, iodoMethyl- MethylMagnesiuM iodide, 3.0 M in diethyl ether, SpcSeal Methyl magnesium iodide 3M ether solution methylmagnesium iodide 2M in THF nesium iodide Methylmagnesium bromide [solution in THF] Methylmagnesium Iodide, Diethyl Ether Solution (abt. 1mol/l) Methylmagnesium Iodide (3.0 M in Diethyl ether) 3.0 M in diethyl ether Methylmagnesium iodide solution CHLOROMETHYLMAGNESIUM Methylmagnesium iodide (6CI) Methylmagnesium iodide, 3M in diethyl ether Methyl magnesium iodide 1M in THF METHYL MAGNESIUM IODIDE IN ETHER Methyl Magnesium Iodide 3 Molar Solution in Diethyl Ether Methylmagnesium iodide, 3M in diethyl 917-64-6 CH3IMg CH3MgI Alkyl Organometallic Reagents Mg (Magnesium) Compounds Grignard Reagents & Alkyl Metals Typical Metal Compounds Grignard Reagents Classes of Metal Compounds Typical Metal Compounds Grignard Reagent Alkyl Chemical Synthesis Organic Bases Organometallic Reagents Synthetic Reagents AlkylChemical Synthesis Grignard Reagents Organic Bases Organometallic Reagents Synthetic Reagents Classes of Metal Compounds Grignard Reagents