Scandium trifluoromethanesulfonate
- CAS No.
- 144026-79-9
- Chemical Name:
- Scandium trifluoromethanesulfonate
- Synonyms
- Sc(OTf)3;Scandium tris(trifluoromethanesulfonate);SCANDIUM TRIFLATE;SCANDIUM(III) TRIFLUOROMETHANESULFONATE;SCANDIUM(III) TRIFLATE;PS-SC(OTF)2;SC(O3SCF3)3;SCANDIUM TRIFLATE RESIN;SCANDIUM(III) TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID SCANDIUM(III) SALT
- CBNumber:
- CB4256487
- Molecular Formula:
- C3F9O9S3Sc
- Molecular Weight:
- 492.16
- MDL Number:
- MFCD00192433
- MOL File:
- 144026-79-9.mol
- MSDS File:
- SDS
Melting point | >300 °C |
---|---|
storage temp. | Inert atmosphere,Room Temperature |
solubility | Water (Slightly) |
form | Powder |
color | White |
Water Solubility | Soluble in water, alcohol and acetonitrile. |
Sensitive | Hygroscopic |
Hydrolytic Sensitivity | 6: forms irreversible hydrate |
BRN | 8510151 |
Stability | hygroscopic |
InChI | InChI=1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 |
InChIKey | HZXJVDYQRYYYOR-UHFFFAOYSA-K |
SMILES | C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Sc+3] |
CAS DataBase Reference | 144026-79-9(CAS DataBase Reference) |
NCI Dictionary of Cancer Terms | scan |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P305+P351+P338-P280a-P304+P340-P405-P501a | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
F | 3-10 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | No | |||||||||
HS Code | 28469099 | |||||||||
NFPA 704 |
|
Scandium trifluoromethanesulfonate price More Price(47)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 418218 | Scandium(III) triflate 99% | 144026-79-9 | 1g | $66.2 | 2024-03-01 | Buy |
Sigma-Aldrich | 418218 | Scandium(III) triflate 97% | 144026-79-9 | 5g | $166 | 2024-03-01 | Buy |
TCI Chemical | T1663 | Scandium(III) Trifluoromethanesulfonate >98.0%(T) | 144026-79-9 | 1g | $55 | 2024-03-01 | Buy |
TCI Chemical | T1663 | Scandium(III) Trifluoromethanesulfonate >98.0%(T) | 144026-79-9 | 5g | $187 | 2024-03-01 | Buy |
Alfa Aesar | 040566 | Scandium(III) trifluoromethanesulfonate, 98% | 144026-79-9 | 1g | $66.2 | 2024-03-01 | Buy |
Scandium trifluoromethanesulfonate Chemical Properties,Uses,Production
Description
Scandium trifluoromethanesulfonate, commonly called Scandium(III) triflate, is a chemical compound with formula Sc(SO3CF3)3, a salt consisting of scandium cations Sc3+ and triflate SO3CF3? anions.
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates.
Chemical Properties
White powder
Uses
Scandium(III) trifluoromethanesulfonate is widely used as a catalyst in hydrothiolation, selective two-electron reduction of oxygen by ferrocene derivatives and vinylogous Fridel-crafts alkylation of indoles and pyrrole in water. It is involved in the Mukaiyama aldol addition and stereochemically catalyzes the radical polymerization of acrylates. It acts as a Lewis acid catalyst and used in the synthesis of bullvalone via a stabilized sulfur ylide.
Uses
Scandium Triflate is an important catalyst used in Friedel-Crafts acylation, Baylis-Hillman reaction and other carbon-carbon bond forming reactions.
Application
Scandium(III) triflate was used as a catalyst in:
Hydrothiolation reaction of aromatic and aliphatic thiols.
Selective two-electron reduction of O2 by ferrocene derivatives.
Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water.
Synthesis of β-cyanoketones.
Combination with triethylsilane to reductively open functionalized pyranoside rings.
The key steps of synthesis of bullvalone via a stabilized sulfur ylide.
Reactions
- Water tolerant Lewis acid.
- Commonly used in a range of Lewis acid catalyzed reactions.
- Efficient metal source for Lewis acid catalyzed asymmetric reactions.
- Catalyzes Friedel-Crafts alkylation, acylation and related reactions.
- Catalyzes various domino- and multi-component processes.
- Catalyzes electrophilic additions of alpha-diazoesters with ketones.
- Catalyzes carbon insertion reactions.
General Description
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates.
Scandium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Aceschem Inc. | +1-817863-6948 +1-(817)863-6948 | sales@aceschem.com | United States | 19639 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1290 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Zhejiang ZETian Fine Chemicals Co. LTD | 18957127338 | stella@zetchem.com | China | 2141 | 58 |
Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10828 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
View Lastest Price from Scandium trifluoromethanesulfonate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-03-10 | Scandium trifluoromethanesulfonate
144026-79-9
|
US $0.00-0.00 / kg | 1kg | 98% | 500 kg | LY Global chemicals co.,ltd . | ||
2023-03-01 | Scandium trifluoromethanesulfonate
144026-79-9
|
US $60.00 / kg | 1kg | 99% | 100 tons | Hebei Duling International Trade Co. LTD | ||
2022-08-13 | Scandium trifluoromethanesulfonate
144026-79-9
|
US $0.00-0.00 / KG | 00001KG | 98%minHPLC | 100kgs/month | Shanghai Rlavie Technology Co ltd |
- Scandium trifluoromethanesulfonate
144026-79-9
- US $0.00-0.00 / kg
- 98%
- LY Global chemicals co.,ltd .
- Scandium trifluoromethanesulfonate
144026-79-9
- US $60.00 / kg
- 99%
- Hebei Duling International Trade Co. LTD
- Scandium trifluoromethanesulfonate
144026-79-9
- US $0.00-0.00 / KG
- 98%minHPLC
- Shanghai Rlavie Technology Co ltd
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