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N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE

CAS No.
22737-33-3
Chemical Name:
N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE
Synonyms
Methylbistrimethylsilylhydroxylamine;N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE;N-trimethylsilyl-N-trimethylsilyloxymethanamine;Silanamine, N,1,1,1-tetramethyl-N-[(trimethylsilyl)oxy]-
CBNumber:
CB4256876
Molecular Formula:
C7H21NOSi2
Molecular Weight:
191.42
MDL Number:
MFCD00191463
MOL File:
22737-33-3.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:37

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Properties

Boiling point 155.3±23.0 °C(Predicted)
Density 1.4146 g/cm3
storage temp. Refrigerator
solubility sol benzene, toluene, CH2Cl2, CHCl3.
form clear liquid
pka 5.95±0.70(Predicted)
color Colorless to Light yellow to Light orange

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS02
Signal word  Danger
Hazard statements  H314-H226
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
RIDADR  UN 2920 8/3/PG II
HS Code  2931.90.9010
HazardClass  8/3
PackingGroup  II
NFPA 704
2
1 0

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M1077 N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine 22737-33-3 1mL $143 2024-03-01 Buy
TCI Chemical M1077 N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine 22737-33-3 5mL $485 2024-03-01 Buy
TRC M695880 N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine 22737-33-3 50mg $45 2021-12-16 Buy
American Custom Chemicals Corporation ING0004589 N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE 95.00% 22737-33-3 5ML $1025.18 2021-12-16 Buy
American Custom Chemicals Corporation ING0004589 N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE 95.00% 22737-33-3 1ML $244 2021-12-16 Buy
Product number Packaging Price Buy
M1077 1mL $143 Buy
M1077 5mL $485 Buy
M695880 50mg $45 Buy
ING0004589 5ML $1025.18 Buy
ING0004589 1ML $244 Buy

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Chemical Properties,Uses,Production

Physical properties

bp 40–41 °C/10 mmHg; n20 D 1.4146.2

Uses

As bis-trimethylsilylated N-methylhydroxylamine N-Methyl-N,O-bis(trimethylsilyl)- hydroxylamine can convert aldehydes and ketones to N-methyl nitrones with regio- and chemoselectivity; source of methylnitrene by pyrolysis; source of the trimethylsilyl(methyl)aminyl radical by photolysis.

Preparation

It is obtained in 52% yield by reaction of Nmethylhydroxylamine with chlorotrimethylsilane (2.0 equiv) and triethylamine (3.3 equiv) in ether at 25 °C.

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Suppliers

Global( 31)Suppliers
Supplier Tel Email Country ProdList Advantage
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
PT CHEM GROUP LIMITED
+86-85511178 +86-85511178 peter68@ptchemgroup.com China 35453 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490 info@gihichemicals.com China 49999 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Longsheng chemical Co.,Ltd. 021-58099652-8005 13585536065 bin.wu@shlschem.com China 9816 59
Maya High Purity Chemicals +86 (573) 82222445 (0)18006601000 452520369 sales@maya-r.com China 11714 57
N-METHYL-N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE Methylbistrimethylsilylhydroxylamine Silanamine, N,1,1,1-tetramethyl-N-[(trimethylsilyl)oxy]- N-trimethylsilyl-N-trimethylsilyloxymethanamine 22737-33-3 C7H21NOSi2 Silicon Compounds (for Synthesis) Hydroxylamines Trimethylsilylazide, etc. Hydroxylamines (N-Substituted) Protection & Derivatization Reagents (for Synthesis) Hydroxylamines (O-Substituted) Si (Classes of Silicon Compounds) Si-N Compounds Hydroxylamines Hydroxylamines (N-Substituted) Hydroxylamines (O-Substituted) Protection & Derivatization Reagents (for Synthesis) Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-N Compounds Synthetic Organic Chemistry Trimethylsilylazide, etc.