ChemicalBook >> CAS DataBase List >>(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

CAS No.
158923-11-6
Chemical Name:
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
Synonyms
JOSIPHOS SL-J009-1;(R)-(S)-cy2PF-PtBu2;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene;CyPFt-Bu;(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE;(R)-1-[(S;(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t...;(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
CBNumber:
CB4258744
Molecular Formula:
C32H52FeP2 10*
Molecular Weight:
554.55
MDL Number:
MFCD03426994
MOL File:
158923-11-6.mol
MSDS File:
SDS
Last updated:2023-08-02 17:35:45

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Properties

Melting point 118-120oC
alpha -185° ±10° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Slightly), Methanol (Very Slightly)
form Powder
color orange

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
HS Code  29319090

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 88733 (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 158923-11-6 1g $662 2024-03-01 Buy
Sigma-Aldrich 88733 (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 158923-11-6 5g $2430 2024-03-01 Buy
Strem Chemicals 26-0975 (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97% 158923-11-6 100mg $107 2024-03-01 Buy
Strem Chemicals 26-0975 (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97% 158923-11-6 500mg $375 2024-03-01 Buy
Sigma-Aldrich 88733 (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 158923-11-6 100mg $122 2024-03-01 Buy
Product number Packaging Price Buy
88733 1g $662 Buy
88733 5g $2430 Buy
26-0975 100mg $107 Buy
26-0975 500mg $375 Buy
88733 100mg $122 Buy

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties,Uses,Production

Reaction

  1. Ligand for Palladium-catalyzed C-N cross-coupling.
  2. Ligand for Palladium-catalyzed C-S cross-coupling.
  3. Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
  4. Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
  5. Ligand for Palladium-catalyzed C-O cross-coupling.
  6. Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
  7. Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
Reactions of 158923-11-6_1
Reactions of 158923-11-6_2
Reactions of 158923-11-6_3

Chemical Properties

Orange powder

Uses

It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.

General Description

sold in collaboration with Solvias AG

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 133)Suppliers
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XINXIANG RUNYU MATERIAL CO., LTD.
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View Lastest Price from (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE pictures 2023-08-02 (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
158923-11-6
US $10.00 / kg 1kg 99% 500t/month Henan Bao Enluo International TradeCo.,LTD
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE pictures 2023-07-27 (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
158923-11-6
US $0.00-0.00 / KG 1KG 0.98 larger package as required XINXIANG RUNYU MATERIAL CO., LTD.
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE pictures 2022-08-19 (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
158923-11-6
US $80.00 / kg 1kg 99%min 1 Hebei Duling International Trade Co. LTD

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Spectrum

(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)- (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97% (Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97% (R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DICYCLOHEXYLPHOSPHINO)FERROCENE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97% (r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to cas) Josiphos SL-J009-1 / (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine (R)-1-[(S (R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl]di-tert-butylphosphine (R)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl di-tert-butylphospine (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t... (R)-(S)-cy2PF-PtBu2 (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE JOSIPHOS SL-J009-1 CyPFt-Bu (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene (R)-(-)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine(Josiphos SL-J009-1) 158923-11-6 C32H52FeP2 C27H47P2C5H5Fe Solvias Ligands Privileged Ligands Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents organophosphine ligand Chiral Phosphine Ferrocene Series Josiphos Series