ChemicalBook >> CAS DataBase List >>RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
- CAS No.
- 12289-94-0
- Chemical Name:
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
- Synonyms
- Ru(Me-allyl)2(COD);Bis(2-methylallyl);-1,5-cyclooctadieneruthenium (II);BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&;BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&;Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium;(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium;(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
- CBNumber:
- CB4264385
- Molecular Formula:
- C16H18Ru
- Molecular Weight:
- 311.39
- MDL Number:
- MFCD00216965
- MOL File:
- 12289-94-0.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 81-85 °C |
|---|---|
| Boiling point | 100°C/0.05mmHg |
| storage temp. | -20°C |
| form | Powder |
| color | tan to brown |
| Water Solubility | It is soluble in water. |
| Sensitive | Air & Moisture Sensitive |
| Stability | store cold |
| InChIKey | KMYRLYRRLMVJNK-XMWBDPRZSA-N |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H261 | |||||||||
| Precautionary statements | P280a-P370+P378c-P402+P404-P501a-P231+P232-P422 | |||||||||
| Hazard Codes | Xn,F | |||||||||
| Risk Statements | 20/21/22-15 | |||||||||
| Safety Statements | 36/37-43 | |||||||||
| RIDADR | UN3395 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Alfa Aesar | H26891 | Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) | 12289-94-0 | 1g | $159 | 2024-03-01 | Buy |
| Strem Chemicals | 44-0046 | Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97% | 12289-94-0 | 250mg | $54 | 2024-03-01 | Buy |
| Strem Chemicals | 44-0046 | Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97% | 12289-94-0 | 1g | $156 | 2024-03-01 | Buy |
| Strem Chemicals | 44-0046 | Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97% | 12289-94-0 | 5g | $624 | 2024-03-01 | Buy |
| TRC | M287223 | Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(ii) | 12289-94-0 | 100mg | $140 | 2021-12-16 | Buy |
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties,Uses,Production
Reaction
- Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
- β-ketoester reduction.
- Anti-Markovnikov addition of amides to alkynes.
- Anti-Markovnikov hydroamination of vinylarenes.
- Catalyst for the addition of amides to alkynes.
Chemical Properties
tan/brown powder
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Uses
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.
General Description
This product has been enhanced for catalytic efficiency.
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Preparation Products And Raw materials
Raw materials
Preparation Products
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Suppliers
Global( 102)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5601 | 58 |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2255 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9705 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
View Lastest Price from RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
12289-94-0
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
12289-94-0
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), 32% Ru, Product of Umicore
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANED...
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