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Ethyl benzoylformate

Ethyl benzoylformate structure

CAS No.: 1603-79-8

Chemical Name:: Ethyl benzoylformate

Synonyms: ETHYL 2-OXO-2-PHENYLACETATE;ETHYL PHENYLGLYOXYLATE;Benzeneacetic acid, .alpha.-oxo-, ethyl ester;Ethyl oxophenyla;RARECHEM AL BI 0384;ETHYL BENZOYLFORMATE;PHENYLETHYLGLYOXYLATE;Ethyloxophenylacetate;Ethyl oxophenylacetate;Ethylα-oxobenzeneacetate

CBNumber:: CB4299905

Molecular Formula:: C10H10O3

Molecular Weight:: 178.18

MDL Number:: MFCD00009120

MOL File:: 1603-79-8.mol

Last updated:2023-05-25 18:01:09

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Ethyl benzoylformate Properties

Boiling point	138-139 °C/18 mmHg (lit.)
Density	1.122 g/mL at 25 °C (lit.)
refractive index	1.515-1.517
Flash point	113 °C
storage temp.	Store below +30°C.
form	Liquid
Specific Gravity	1.122
color	Clear colorless to greenish
Water Solubility	Soluble in water 1143 mg/L @ 25°C .
Sensitive	Moisture Sensitive
InChI	InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChIKey	QKLCQKPAECHXCQ-UHFFFAOYSA-N
SMILES	C1(C=CC=CC=1)C(=O)C(=O)OCC
LogP	1.974 (est)
CAS DataBase Reference	1603-79-8(CAS DataBase Reference)
FDA UNII	AMN28N4D74
NIST Chemistry Reference	Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8)
EPA Substance Registry System	Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H302-H314-H227

Precautionary statements

P501-P270-P210-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405

Hazard Codes

Safety Statements

24/25

WGK Germany

Hazard Note

Moisture Sensitive

TSCA

Yes

HazardClass

IRRITANT

HS Code

29183000

NFPA 704

	1
0		0

Ethyl benzoylformate price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	258911	Ethyl benzoylformate 95%	1603-79-8	5g	$31.8	2024-03-01	Buy
Sigma-Aldrich	258911	Ethyl benzoylformate 95%	1603-79-8	25g	$71	2024-03-01	Buy
TCI Chemical	B0109	Ethyl Benzoylformate >96.0%(GC)	1603-79-8	5mL	$29	2024-03-01	Buy
TCI Chemical	B0109	Ethyl Benzoylformate >96.0%(GC)	1603-79-8	25mL	$76	2024-03-01	Buy
Alfa Aesar	B25292	Ethyl phenylglyoxylate, 98%	1603-79-8	5g	$27.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
258911	5g	$31.8	Buy
258911	25g	$71	Buy
B0109	5mL	$29	Buy
B0109	25mL	$76	Buy
B25292	5g	$27.65	Buy

Ethyl benzoylformate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to greenish liquid

Uses

Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.

Application

Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Definition

ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7

General Description

Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al₂O₃ modified with dihydrocinchonidine has been studied.

Ethyl benzoylformate synthesis

Synthesis of Ethyl benzoylformate from Methyl benzoylformate and Ethanol

Ethyl benzoylformate Preparation Products And Raw materials

Raw materials

Nitrogen Diethyl oxalate Bromobenzene Diethyl ether Ammonium chloride

Magnesium 2H-1,4-Benzoxazin-2-one, 3-phenyl- Benzene, (2-ethoxyethynyl)- Benzeneacetyl chloride, alpha-oxo- (9CI) 2-AMINOPHENOL HYDROCHLORIDE

Ethyl diazophenylacetate ETHYL (R)-(-)-MANDELATE 4,4,4-TRIFLUORO-3-HYDROXY-1-PHENYL-BUT-2-EN-1-ONE Benzoylacetonitrile 2,4,6-Triphenylboroxin

PHENYLGLYOXAL Phenylboronic acid Ethyl phenylacetate

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Preparation Products

Ethyl benzoylformate Suppliers

Global( 234)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shenyang Simchoice Chemical Co.,Ltd	+86-024-23769576 +86-15040101888	sales@simchoicechem.com	China	255	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Hi-Tech Chemistry Corp	0519-86626038	yuhh@hitechem.com	CHINA	811	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10828	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58

Supplier	Advantage
Shenyang Simchoice Chemical Co.,Ltd	58
Capot Chemical Co.,Ltd.	60
Hi-Tech Chemistry Corp	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
Jinan Liheng Biotechnology Co., Ltd.	58

View Lastest Price from Ethyl benzoylformate manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-07-06	Ethyl benzoylformate 1603-79-8	US $2.00 / kg	1kg	99%	100kg	Career Henan Chemical Co

Ethyl benzoylformate
1603-79-8
US $2.00 / kg
99%
Career Henan Chemical Co

Ethyl benzoylformate Spectrum

Ethyl benzoylformate(1603-79-8)¹HNMR Ethyl benzoylformate(1603-79-8)¹³CNMR Ethyl benzoylformate(1603-79-8)IR1 Ethyl benzoylformate(1603-79-8)Raman

1603-79-8(Ethyl benzoylformate)Related Search:

Benzoyl peroxide Ethanol Ethyl acetate Ethylparaben Ethyl cyanoacetate

ETHYL ANTHRANILATE Ethyl benzoate Ethyl acrylate Stearoylbenzoylmethane Ethyl benzoylacetate

Ethyl pyruvate Ethyl formate ISOXADIFEN-ETHYL Trinexapac-ethyl ETHYL 4-METHOXYBENZOYLFORMATE

ETHYL 4-NITROPHENYLGLYOXYLATE ETHYL MESITYLGLYOXYLATE Ethyl phenylacetate

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RARECHEM AL BI 0384 PHENYLETHYLGLYOXYLATE PHENYLGLYOXYLIC ACID ETHYL ESTER alpha-oxo-benzeneaceticaciethylester Benzenaceticacid,-oxoethylester Benzeneaceticacid,α-oxo-,ethylester Ethyl oxophenylacetate Ethyloxophenylacetate Ethylα-oxobenzeneacetate Glyoxylic acid, phenyl-, ethyl ester alpha-oxo-benzeneacetic acid ethyl ester Ethyl oxo(phenyl)acetate 98% Ethyl phenylglyoxylate, Ethyl benzoylformate Benzoylformic Acid Ethyl Ester Ethyl Phenylglyoxylate Phenylglyoxylic Acid Ethyl Ester ETHYL PHENYLGLYOXYLATE FOR SYNTHESIS Gloyoxylic acid, phenyl-, ethyl ester 2-Oxo-2-phenylacetic acid ethyl ester 2-Phenylglyoxalic acid ethyl ester Phenyloxoacetic acid ethyl ester Ethyl benzoylformate,95% a-Oxo-benzeneacetic acid ethyl ester Ethyl BenzoylforMate, 97+% Glyoxylicacid,phenyl-,ethylester Oxo-phenyl-aceticacidethylester α-Oxobenzeneaceticacidethylester ETHYL BENZOYLFORMATE BENZOYLFORMIC ACID ETHYL ESTER Benzoylformic acid ethyl ester~Ethyl phenylglyoxylate BENZENACETIC ACID, -OXO ETHYL ESTER 96% PhenylglyoxylicAcidEthylEther Ethyl benzoylformate 98% Ethyl oxophenyla Benzeneacetic acid, α-oxo-, ethyl ester ETHYL 2-OXO-2-PHENYLACETATE ETHYL PHENYLGLYOXYLATE Benzeneacetic acid, .alpha.-oxo-, ethyl ester 1603-79-8 C6H5COCO2C2H5 C6H5COCOOC2H5 Carbonyl Compounds C10 to C11 Building Blocks Esters Organic Building Blocks Pharmaceutical Intermediates Aromatic Esters Esters Phenyls & Phenyl-Het API intermediates Phenyls & Phenyl-Het