ChemicalBook >> CAS DataBase List >>2,2-Dimethyl-1,3-dioxolane-4-methanol

2,2-Dimethyl-1,3-dioxolane-4-methanol

CAS No.
100-79-8
Chemical Name:
2,2-Dimethyl-1,3-dioxolane-4-methanol
Synonyms
Glycerol acetonide;ISOPROPYLIDENEGLYCEROL;2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL;isopropylidene;glycerolacetonide;AUGEO;1,2-ISOPROPYLIDENEGLYCEROL;GIE;ideneg;idenegL
CBNumber:
CB4305646
Molecular Formula:
C6H12O3
Molecular Weight:
132.16
MDL Number:
MFCD00063238
MOL File:
100-79-8.mol
MSDS File:
SDS
Last updated:2024-01-03 17:25:31

2,2-Dimethyl-1,3-dioxolane-4-methanol Properties

Melting point -27℃
Boiling point 189-191 °C
Density 1.066 g/mL at 20 °C(lit.)
vapor pressure 34Pa at 20℃
refractive index n20/D 1.434
Flash point 176 °F
storage temp. Sealed in dry,2-8°C
solubility 172g/l soluble
form Liquid
pka 14.20±0.10(Predicted)
color Clear colorless
PH 4.0-7.5 (H2O)
Water Solubility miscible
Merck 14,5213
BRN 104465
InChIKey RNVYQYLELCKWAN-UHFFFAOYSA-N
LogP 0.3 at 20℃
CAS DataBase Reference 100-79-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 3XK098O8ZW
NIST Chemistry Reference 1,3-Dioxolane-4-methanol, 2,2-dimethyl-(100-79-8)
EPA Substance Registry System 1,3-Dioxolane-4-methanol, 2,2-dimethyl- (100-79-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  23-24/25-36-26
WGK Germany  2
RTECS  JI0400000
10
TSCA  Yes
HS Code  29329970
Toxicity LD50 in rats (g/kg): 7 orally; 3 i.p. (Perez)
NFPA 704
2
1 0

2,2-Dimethyl-1,3-dioxolane-4-methanol price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 122696 DL-1,2-Isopropylideneglycerol ≥97.0% 100-79-8 100g $41.6 2024-03-01 Buy
Sigma-Aldrich 122696 DL-1,2-Isopropylideneglycerol ≥97.0% 100-79-8 3kg $344 2024-03-01 Buy
TCI Chemical D0710 2,2-Dimethyl-1,3-dioxolane-4-methanol >98.0%(GC) 100-79-8 25g $43 2024-03-01 Buy
TCI Chemical D0710 2,2-Dimethyl-1,3-dioxolane-4-methanol >98.0%(GC) 100-79-8 100g $95 2024-03-01 Buy
Alfa Aesar L02814 Solketal, 97% 100-79-8 100g $40.5 2024-03-01 Buy
Product number Packaging Price Buy
122696 100g $41.6 Buy
122696 3kg $344 Buy
D0710 25g $43 Buy
D0710 100g $95 Buy
L02814 100g $40.5 Buy

2,2-Dimethyl-1,3-dioxolane-4-methanol Chemical Properties,Uses,Production

Chemical Properties

clear colourless liquid

Uses

DL-1,2-Isopropylideneglycerol was used as the starting reagent for synthesis of tulipaline derivatives.

Uses

Solketal is useful for synthesis of mono-, di- and triglycerides. It is used as the starting reagent for synthesis of tulipaline derivatives. It acts as a fuel additive in gasoline. It is an inhibitor of Methyl ethyl ketone .

Uses

A MEK inhibitor

Synthesis Reference(s)

Tetrahedron, 52, p. 9387, 1996 DOI: 10.1016/0040-4020(96)00501-7
The Journal of Organic Chemistry, 53, p. 2859, 1988 DOI: 10.1021/jo00247a043

General Description

DL-1,2-Isopropylideneglycerol undergoes effective isopropylidenation and deprotection reaction catalyzed by phosphotungstic acid.

Safety Profile

A poison by intravenous route. An eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

Global( 387)Suppliers
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Hebei Jingbo New Material Technology Co., Ltd
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View Lastest Price from 2,2-Dimethyl-1,3-dioxolane-4-methanol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2-Dimethyl-1,3-dioxolane-4-methanol pictures 2024-01-04 2,2-Dimethyl-1,3-dioxolane-4-methanol
100-79-8
US $8.00 / kg 1kg 99% 200000 Hebei Jingbo New Material Technology Co., Ltd
2,2-Dimethyl-1,3-dioxolane-4-methanol pictures 2023-12-23 2,2-Dimethyl-1,3-dioxolane-4-methanol
100-79-8
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2,2-Dimethyl-1,3-dioxolane-4-methanol pictures 2023-09-06 2,2-Dimethyl-1,3-dioxolane-4-methanol
100-79-8
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
DL-ALPHA,BETA-ISOPROPYLIDENEGLYCEROL LABOTEST-BB LT00233172 ISOPROPYLIDENGLYCEROL GLYCEROL DIMETHYLKETAL 2,3-O-ISOPROPYLIDENEGLYCEROL (+/-)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL (+/-)-2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE 2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE 1,2-O-ISOPROPYLIDENEGLYCEROL 1,2-ISOPROPYLIDENE-RAC-GLYCEROL 1,2-Isopropylideneglycerin 1,2-O,O-Isopropylideneglycerin (+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol~(+/-)-1,2-O-Isopropylideneglycerol 4-hydroxymethyl-2,2-dimethyl-1,3-dioxolan glycerol 1,2-isopropylidene ether DL-1,2-Isopropylideneglycerol, 98% 2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL(SOLKETAL) Glycerol α,β-isopropylidene ether Dimethyl-4-hydroxymethyl-1,3-dioxolane 1,3-Dioxolane-4-methanol, 2,2-dimethyl- (n)-1,2-o-isopropylideneglycerol (n)-2,2-dimethyl-1,3-dioxolane-4-methanol ACETONE GLYCERINE KETAL ACETONE KETAL OF GLYCERINE SOLKETAL SOLKETAL(R) (R,S)-ISOPROPYLIDENE GLYCEROL 2,2-Dimethyl-1,3-dioxolan-4-yl methanol glycerol,1,2-o-isopropylidene Glycerolacetone dl-α,β-isopropylideneglycerol DL-1,2-Isopropylideneglycerol 98% 1,2-O-Isopropylideneglycerol for synthesis 2,2-dimethyl-3-dioxolane-4-methanol 2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxacyclopentane 2,2-Dimethyl-4-hydroxymethyldioxolane 2,2-Dimethyl-4-oxymethyl-1,3-dioxolane 2,2-Dimethyl-5-hydroxymethyl-1,3-dioxolane 1,2-isopropylidine glycerol 2,3-(Isopropylidenedioxy)propanol 2,3-Isopropylideneglycerol 4-(Hydroxymethyl)-2,2-dimethyl-1,3-dioxolane 4-Hydroxymethyl-2,2-dimethyl-1,3-dioxolane Acetone monoglycerol ketal Acetone, cyclic (hydroxymethyl)ethylene acetal acetone,cyclic(hydroxymethyl)ethyleneacetal acetoneglycerol alpha,beta-Isopropylideneglycerol GIE Glycerinisopropylidene ether Glycerol, 1,2-O-isopropylidene (+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol, 97+% (±)-2,2-Dimethyl-1,3-dioxolane-4-methanol, (±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane, 1,2-Isopropylidene-rac-glycerol, Solketal (±)-2,2-Dimethyl-1,3-dioxolane-4-methanol, (±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane, Solketal Glycerol dimethylketone Solketal ,98% 1,2-O-ISOPROPYLIDENE-RAC-GLYCEROL DL-1,2-Isopropylideneglycerol,(±)-2,2-Dimethyl-1,3-dioxolane-4-methanol, (±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane, 1,2-Isopropylidene-rac-glycerol, Solketal