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Bis(4-hydroxyphenyl) Sulfone

CAS No.
80-09-1
Chemical Name:
Bis(4-hydroxyphenyl) Sulfone
Synonyms
BISPHENOL S;SDP;4,4-DIHYDROXYDIPHENYL SULPHONE;4,4-SULFONYLDIPHENOL;4,4'-SULFONYLDIPHENOL;-Hexabromodiphenyl Ether-13C6;bps1;50kg;3-dione;diphonec
CBNumber:
CB4306294
Molecular Formula:
C12H10O4S
Molecular Weight:
250.27
MDL Number:
MFCD00002350
MOL File:
80-09-1.mol
MSDS File:
SDS
Last updated:2024-04-17 18:50:11

Bis(4-hydroxyphenyl) Sulfone Properties

Melting point 245-250 °C (lit.)
Boiling point 363.4°C (rough estimate)
Density 1.366
vapor pressure <0.0001 Pa (20 °C)
refractive index 1.5220 (estimate)
storage temp. Store below +30°C.
solubility 1.1g/l
form Crystalline Powder
pka 7?+-.0.15(Predicted)
color White to grayish-green
PH 6.6-7.0 (100g/l, H2O, 20℃)
Odor odorless
Water Solubility 1.1 g/L (20 ºC)
λmax 295nm(H2O)(lit.)
BRN 2052954
Stability Stable. Incompatible with strong bases, acid chloride, acid anhydrides, strong oxidizing agents.
InChIKey VPWNQTHUCYMVMZ-UHFFFAOYSA-N
LogP 1.2 at 23℃
Indirect Additives used in Food Contact Substances DIPHENYLSULFONE
CAS DataBase Reference 80-09-1(CAS DataBase Reference)
FDA UNII 3OX4RR782R
EPA Substance Registry System Phenol, 4,4'-sulfonylbis- (80-09-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H402-H303-H315-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P273-P280-P305+P351+P338+P337+P313-P501
Hazard Codes  Xi
Risk Statements  36-36/37/38
Safety Statements  26-39-36-37
WGK Germany  2
RTECS  SM8925000
Autoignition Temperature >=400 °C
TSCA  Yes
HS Code  29309070
Toxicity LD50 orally in Rabbit: 2830 mg/kg
NFPA 704
1
2 0

Bis(4-hydroxyphenyl) Sulfone price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 103039 4,4′-Sulfonyldiphenol 98% 80-09-1 100g $47.1 2024-03-01 Buy
Sigma-Aldrich 103039 4,4′-Sulfonyldiphenol 98% 80-09-1 500g $165 2024-03-01 Buy
Sigma-Aldrich 8.03258 Bis(4-hydroxyphenyl) sulfone for synthesis 80-09-1 100g $43.2 2023-06-20 Buy
Sigma-Aldrich 8.03258 Bis(4-hydroxyphenyl) sulfone for synthesis 80-09-1 500g $85.4 2023-06-20 Buy
TCI Chemical B0495 Bis(4-hydroxyphenyl) Sulfone >98.0%(HPLC)(T) 80-09-1 25g $21 2024-03-01 Buy
Product number Packaging Price Buy
103039 100g $47.1 Buy
103039 500g $165 Buy
8.03258 100g $43.2 Buy
8.03258 500g $85.4 Buy
B0495 25g $21 Buy

Bis(4-hydroxyphenyl) Sulfone Chemical Properties,Uses,Production

Chemical Properties

White needle-like crystals. Freely soluble in aliphatic hydrocarbons, soluble in alcohols and ethers, slightly soluble in aromatics, insoluble in water. Bisphenol S molecule contains two hydroxyl groups and a strong electron-absorbing sulfone group, so the acidity is stronger than other phenols.

Uses

Bis(4-hydroxyphenyl) Sulfone is commonly used as a reactant in epoxy reactions and is also used as a latent thermal catalyst for epoxy resin.

Uses

4,4'-Sulfonyldiphenol is commonly used as a reactant in epoxy reactions and is also used as a latent thermal catalyst for epoxy resin.

Definition

4,4'-Sulfonyldiphenol is a sulfone that is diphenyl sulfone in which both of the para hydrogens have been replaced by hydroxy groups.

Preparation

A process for the preparation of bis(4-hydroxyphenyl)sulfone by reacting phenol with sulfuric acid in the presence of a solvent at from 130° to 220° C and in the presence or absence of a sulfonating assistant. 

General Description

Bisphenol S (BPS), belonging to the class of bisphenols, is a structural analog of bisphenol A (BPA), used in a variety of industrial applications and products marketed as BPA-free. It is commonly identified in food and beverages, environmental samples, biological matrices, etc. It is also reported to be used in the production of epoxy resins. BPS is also found to be stable compared to BPA at elevated temperature and sunlight conditions.

Health Hazard

Although there is no direct link established between bis(4-hydroxyphenyl) sulfone(BPS) and cardiac disease, it is thought that bis(4-hydroxyphenyl) sulfone may operate by a similar mechanism to BPA and could cause cardiac toxicity.

Flammability and Explosibility

Non flammable

108-95-2
80-09-1
5397-34-2
Synthesis of Bis(4-hydroxyphenyl) Sulfone from Phenol
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View Lastest Price from Bis(4-hydroxyphenyl) Sulfone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(4-hydroxyphenyl) Sulfone pictures 2024-04-19 Bis(4-hydroxyphenyl) Sulfone
80-09-1
US $0.00-0.00 / kg 1kg 99%+ 10000kgs per Month Shanghai Qyubiotech Co., Ltd.
4,4'-Sulfonyldiphenol pictures 2024-04-19 4,4'-Sulfonyldiphenol
80-09-1
US $0.00 / Kg/Bag 1KG 99% 5000mt/year Jinan Finer Chemical Co., Ltd
Bis(4-hydroxyphenyl) Sulfone pictures 2024-04-18 Bis(4-hydroxyphenyl) Sulfone
80-09-1
US $50.00 / kg 1kg 99.10% 5000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
4-Hydroxyphenyl sulfone, Bis(4-hydroxyphenyl) sulfone, Bisphenol S 4-(4-Hydroxyphenyl)sulfonylphenol 4,4'-Sulfonyldiphenol ,97% 4,4zzhlxy-Sulfonyldiphenol (4,4zzhlxy-Dihydroxydiphenylsulfone) Bisphenol S 4,4'-Dihydroxydiphenyl Sulfone 4,4'-Sulfonyldiphenol BIS(4-HYDROXYPHENYL) SULFONE FOR SYNTHES 4,4'-Sulfonyldiphenol, Bisphenol S -Sulfonyldiphenol 4,4'-Dihydroxydiphenyl sulphone, Bis(4-hydroxyphenyl) sulphone 4-Hydroxyphenyl sulfone Bis(4-hydroxyphenyl) sulfone Bisphenol S 4,4'-Dihydroxydiphenylsulfone Bis(4-hydroxyphenyl) sulfone for synthesis BIS(4-HYDROXYPHENYL) SULPHONE BIS(4-HYDROXYPHENYL) SULFONE 4-HYDROXYPHENYL SULFONE 4,4'-DIHYDROXYDIPHENYLSULPHONE 4,4'-DIHYDROXYDIPHENYL SULFONE 4,4-DIHYDROXYDIPHENYL SULFONE 4,4’-bisphenols 4,4’-dlhydroxydiphenylsulfone 4,4’-sulfonylbis-pheno 4,4’-sulfonylbisphenol 4,4’-sulfonylbis-Phenol 4,4’-sulfonyldi-pheno bis(p-hydroxyphenyl)sulfone bps1 Di-(4-Hydroxyphenyl)sulphone diphonec p,p’-dihydroxydiphenylsulfone phenol,4,4’-sulfonylbis 4,4'-Dihydroxyphenyl sulfone Bis(4-hydroxyphenyl)sulfone, 99+% 4,4-sulphonyldiphenol Bisphenol S~4,4-Dihydroxydiphenyl sulphone~4-Hydroxyphenyl sulphone~4,4-Sulphonyldiphenol Bis(4-hydroxyphenyl)sulfone,97% 4,4'-Sulfonyldiphenol, 99.70% 4,4''-DIHYDROXYDIPHENYLSULFONE(BISPHENOLS) Bis-(4-hydroxyphenyl)-sulfone (Bisphenol S) P-HYDROXYPHENYL SULFONE 4,4''-SULFONYLDIPHENOL 99.7% -Dimethoxybenzhydrol -Dimethoxydibenzoyl -Bisbenzyl alcohol 99+% 4,4'-Sulfonyldiphenol (BPS) -Dinitro-2-biphenylamine 3-dione -bis(trifluoromethyl)biphenyl 6-Pentabromodiphenyl Ether-13C6 Bisphenol S/4,4'-Sulfonyldiphenol/BPS -[1-(2-Chloroethyl)-2-phenyl-1,2-ethenediyl]-4-O-pivaloyl-bisphenol -Bis(isocyanatophenyl)oxide -Methoxyphenoxy)benzaldehyde -Dichlorobenzil 99+% (GC) -Oxydibenzenesulfonyl hydrazide -Isopropoxyphenyl)phenylboronic acid -Bis(methoxycarbonyl)biphenyl -Oxydiphenol -Thiobis(2-tert-butyl-5-methylphenol) -Dibromo-p-terphenyl