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1,3-Dichloropropene

1,3-Dichloropropene
1,3-Dichloropropene structure
CAS No.
542-75-6
Chemical Name:
1,3-Dichloropropene
Synonyms
D-D;dd95;D-D92;D-D95;Nemex;1,3-D;Anema;TELONE;NEMATOX;Dedisol
CBNumber:
CB4324650
Molecular Formula:
C3H4Cl2
Formula Weight:
110.97
MOL File:
542-75-6.mol

1,3-Dichloropropene Properties

Melting point:
-60 °C
Boiling point:
97-112 °C(lit.)
Density 
1.2
vapor pressure 
E-isomer 3700 Pa, Z-isomer 3500 Pa at 25 °C
refractive index 
n20/D 1.472(lit.)
Flash point:
78 °F
storage temp. 
2-8°C
form 
neat
Water Solubility 
<0.01 g/100 mL at 16.5 ºC
Merck 
14,3075
BRN 
1719556
InChIKey
UOORRWUZONOOLO-OWOJBTEDSA-N
CAS DataBase Reference
542-75-6(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
9H780918D0
IARC
2B (Vol. 41, Sup 7, 71) 1999
NIST Chemistry Reference
1-Propene, 1,3-dichloro-(542-75-6)
Proposition 65 List
1,3-Dichloropropene
EPA Substance Registry System
1,3-Dichloropropene (542-75-6)
SAFETY
  • Risk and Safety Statements

1,3-Dichloropropene price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 48530-U 1,3-Dichloropropene cis + trans, analytical standard 542-75-6 u $47.2 2020-08-18 Buy
Sigma-Aldrich 48530-U 1,3-Dichloropropene cis + trans, analytical standard 2000 mg $48.7 2021-03-22 Buy
Sigma-Aldrich 403733 1,3-Dichloropropene 90%, technical grade 542-75-6 250ml $106 2021-03-22 Buy
TCI Chemical D0405 1,3-Dichloropropene (cis- and trans- mixture) >92.0%(GC) 542-75-6 25g $11 2021-03-22 Buy
TCI Chemical D0405 1,3-Dichloropropene (cis- and trans- mixture) >92.0%(GC) 542-75-6 500g $28 2021-03-22 Buy

1,3-Dichloropropene Chemical Properties,Uses,Production

Description

This nematocide is used as a sol fumigant prior to crop cultivation. Mainly farmers and process operators employed at pesticide plants are exposed.

Chemical Properties

clear yellowish to brownish liquid

Chemical Properties

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

Uses

1,3-Dichloropropene (a technical-grade mixture of the cis-and transisomers) is used as a preplanting fumigant, mainly for the control of nematodes affecting the roots of plants, selected plant diseases, garden centipedes, wireworms, and weeds; as a solvent; and as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides. It is registered for use on all vegetable, fruit, and nut crops, all forage crops, tobacco, all fiber crops, and all nursery crops (EPA 1998). In Hawaii, 1,3-dichloropropene is used to control nematodes on pineapples at planting (Albrecht 1987). In 2009, three products containing 1,3-dichloropropene as an active ingredient were registered for restricted, non-residential use in the United States (EPA 2009). No products containing 1,3-dichloropropene are registered for use by homeowners (EPA 1998).

Uses

1,3-Dichloropropene is a soil fumigant /nematicide used mainly for the pre-plant control of most species of nematodes and soil insect pests in citrus, pineapples, deciduous fruits and nuts, grapes, berries and field and nursery crops. The product contains equal amounts of E- and Z-isomer. The Z-isomer is more biologically active than the E-isomer.

Uses

Widely used as a preplanting soil fumigant for the control of nematodes

Production Methods

1,3-DCP is produced either by high-temperature chlorination of propylene or from 1,3-dichloro-2-propanol by dehydration with phosphoryl chloride or phosphorus pentoxide in benzene. All commercial preparations of 1,3-DCP are mixtures of the cis- and trans-isomers.
According to SRI Consulting, Dow AgroSciences LLC (Freeport, Texas) is the only current manufacturer of 1,3- DCP. Active registrants of 1,3-DCP pesticide formulations include Dow AgroSciences LLC (Indianapolis, Indiana),Soil Chemicals Corporation (Hollister, California), and Trical (Hollister, California).

General Description

A clear colorless liquid. Flash point 95°F. Denser (at 10.2 lb / gal) than water and insoluble in water. Vapors are heavier than air. Used to make other chemicals and as soil fumigant.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

1,3-Dichloropropene reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .

Health Hazard

VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.

Fire Hazard

FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated.

Agricultural Uses

Soil fumigant, Nematicide: This chemical is also used in combinations with dichloropropanes as a soil fumigant to kill nematodes, insects and fungus on cotton, potatoes, tobacco, sugar beets, vegetables, grain, citrus planting sites, deciduous fruit and nut-tree planting sites, and ornamental trees and floral sites. Top four applications in California are on sweet potatoes, carrots, wine grapes and outdoor propagation nurseries. It is used on a wide variety of crops. Not approved for use in EU countries. Actively registered in the U.S.

Trade name

DURHAM NEMATOCIDE®[C]; FUMAZONE®[C]; NEMAGON®[C]; NEMEX®; PROKILL NEMATOCIDE®[C]; TELONE®; TELONE II®; TELONE II-B®; TELONE® EC DRIP; VIDDEN D®; VORLEX®

Contact allergens

This nematocide is used as a soil fumigant prior to crop cultivation. Farmers and process operators employed at pesticide plants are mainly exposed

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Mildly toxic by inhalation. A strong irritant. Mutation data reported. A pesticide. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzers. Reacts vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and CHLORIDES.

Potential Exposure

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

Carcinogenicity

Technical-grade 1,3-dichloropropene (co ntaining 1.0% epichlorohydrin as a stabilizer) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. The technical-grade 1,3-dichloropropene used in the cancer studies in experimental animals was a mixture of cis- and trans-isomers and varied in purity and the stabilizer used (see Properties).

Metabolic pathway

Degradation of 14C-1,3-dichloropropene in aerobic soils in the dark at 25℃ at concentration of approximately 100 μg g-1 results in the formation of 3-chloroallyl alchohol, 3-chloroacrylic acid, numerous minor carboxylic acid metabolites, and carbon dioxide. In addition, there is extensive incorporation of 14C labeled material into the soil organic matter in the soils. By a specific bacterium (Pseudomonas cichorii 170) which is isolated from soil, 1,3-dichloropropene is degraded in different pathways from those of soil degradation. The terminal degradate by this bacterium is acetoaldehye which undergoes mineralization.

Shipping

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

Degradation

E-1,3-Dichloropropene (1) and Z-1,3-dichloropropene (2) degraded rapidly in aqueous solution (independent of pH) under both dark and light exposed conditions (25 °C), with DTW values of ca. 1-6 days. Hydrolytic dechlorination reactions yielded E- and Z-3-chloroallyl alcohol (3,4) and hydrochloric acid (5) as the major products. Further oxidation of 3 and 4 yielded E- and Z-3-chloroacrylic acid (6, 7) as minor products (McCall, 1987; Milano et al., 1988; Batzer and Yoder, 1995).
1,3-Dichloropropene degraded in the vapour phase (with ozone and hydroxyl radicals) to yield chloroacetaldehyde (8), formyl chloride (9) and chloroacetic acid (10 (Tuazon et al., 1984). The estimated air photolysis DT50 was ca. 7-12 hours (Roby and Melichar, 1997).

Toxicity evaluation

In water hydrolyzes to 3-chloropropenol and chloride ion. Both isomers of 3-chloropropenol are toxic but less so than the parent compound.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

1,3-Dichloropropene Preparation Products And Raw materials

Raw materials

Preparation Products


1,3-Dichloropropene Suppliers

Global( 159)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21664 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22610 55
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 8863 55
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
+86 0531-67809011 sales@sdzschem.com CHINA 5138 58
Xi'an Kono chem co., Ltd.,
18292830413 029-86107037-8014
sales7@konochemical.com CHINA 3000 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23036 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47492 58
career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29871 58
SIMAGCHEM CORP
13806087780 +86 13806087780
shaobowang@simagchem.com CHINA 17852 58

View Lastest Price from 1,3-Dichloropropene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-12-24 1,3-Dichloropropene
542-75-6
US $1.00 / g 1g 99% 1000KGS Career Henan Chemical Co

1,3-Dichloropropene Spectrum


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