3-Bromoanisole
- CAS No.
- 2398-37-0
- Chemical Name:
- 3-Bromoanisole
- Synonyms
- 1-BROMO-3-METHOXYBENZENE;META BROMO ANISOLE;M-BROMOANISOLE;3-Methoxybromobenzene;3-Methoxyphenyl bromide;M-Bro;NSC 82293;3-BROMOANISOLE;3-BROMO ANISOL;5-bromoanisole
- CBNumber:
- CB4384971
- Molecular Formula:
- C7H7BrO
- Molecular Weight:
- 187.03
- MDL Number:
- MFCD00000081
- MOL File:
- 2398-37-0.mol
- MSDS File:
- SDS
| Melting point | 2 °C |
|---|---|
| Boiling point | 210-211 °C(lit.) |
| Density | 1.490 g/mL at 20 °C |
| vapor pressure | 38.39Pa at 25℃ |
| refractive index |
n |
| Flash point | 200 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | DMSO (Sparingly), Methanol (Slightly) |
| form | Liquid |
| Specific Gravity | 1.477 |
| color | Clear colorless to slightly yellow-brown |
| PH | 5.5 (H2O, 20℃) |
| Water Solubility | Miscible in methanol, benzene, hexane, toluene and dichloromethane. Practically insoluble in water. |
| BRN | 1524687 |
| Stability | Stable. Combustible. Incompatible with strong oxidising agents, strong acids reducing agents. |
| InChIKey | PLDWAJLZAAHOGG-UHFFFAOYSA-N |
| LogP | 3.03 |
| CAS DataBase Reference | 2398-37-0(CAS DataBase Reference) |
| FDA UNII | 7ZO6TY38WY |
| NIST Chemistry Reference | Benzene, 1-bromo-3-methoxy-(2398-37-0) |
| EPA Substance Registry System | m-Bromoanisole (2398-37-0) |
3-Bromoanisole price More Price(32)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B56498 | 3-Bromoanisole ≥98% | 2398-37-0 | 25g | $54.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | B56498 | 3-Bromoanisole ≥98% | 2398-37-0 | 100g | $130 | 2024-03-01 | Buy |
| TCI Chemical | B0545 | 3-Bromoanisole >98.0%(GC) | 2398-37-0 | 25g | $33 | 2024-03-01 | Buy |
| TCI Chemical | B0545 | 3-Bromoanisole >98.0%(GC) | 2398-37-0 | 250g | $100 | 2024-03-01 | Buy |
| Alfa Aesar | A15625 | 3-Bromoanisole, 98+% | 2398-37-0 | 25g | $37.65 | 2024-03-01 | Buy |
3-Bromoanisole Chemical Properties,Uses,Production
Chemical Properties
3-Bromoanisole, also known as m-Bromoanisole, is a clear colorless to pale yellow oily liquid. The boiling point is 210-211°C (100kPa), 105°C (2.13kPa), the relative density is 1.477, the refractive index is 1.5635, and the flash point is 93°C. It is soluble in alcohol, ether, benzene, and carbon disulfide, but insoluble in water. It is commonly used as a raw material for organic synthesis.
Uses
3-Bromoanisole used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.
Preparation
3-Bromoanisole is synthesized through a reaction between m-bromophenol and dimethyl sulfate. The synthesis method involves the following steps:
Dissolve m-bromophenol in a sodium hydroxide solution.
Slowly add dimethyl sulfate dropwise to the solution while stirring.
Heat the mixture and allow it to react for 1 hour.
Cool the reaction mixture to separate the colorless oil formed.
Extract the water layer with ether.
Dry the ether extract and then distill it to recover the ether.
Distill the residue obtained after recovering the ether, along with the colorless oil, under reduced pressure.
This distillation process results in the production of m-bromoanisole as the final product.
The overall yield of m-bromoanisole achieved through this process is 90%.
References
Application of Anisole, 2-Bromoanisole and 3-Bromoanisole as Overcharge Protection Additives in Lithium-Ion Batteries DOI:10.6023/A12110964
S. Ramalingam; S. Periandy. Spectroscopic investigation, computed IR intensity, Raman activity and vibrational frequency analysis on 3-bromoanisole using HF and DFT (LSDA/MPW1PW91) calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2011, 78 (2), 835-843. DOI:10.1016/j.saa.2010.12.043
Bobby Glover; Kimberly A. Harvey; Bing Liu; Matthew J. Sharp; and Maria F. Tymoschenko. Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene. Org. Lett. 2003, 5 (3), 301-304. DOI:10.1021/ol027266q
3-Bromoanisole Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Beijing Wisdom Chemicals Co., Ltd. | +8613701363759 | market@wisdomchem.com | China | 254 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| NINGBO INNO PHARMCHEM CO., LTD. | 13867897135 | sales@nbinno.com | CHINA | 925 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2966 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
View Lastest Price from 3-Bromoanisole manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-09-07 | 3-Bromoanisole
2398-37-0
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-06-17 | 3-Bromoanisole
2398-37-0
|
US $10.00 / KG | 1KG | 99.% | 10 ton | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2023-06-15 | 3-Bromoanisole
2398-37-0
|
US $128.00 / KG | 1KG | 98% | 1-20mt | Baoji Guokang Bio-Technology Co., Ltd. |
-
- 3-Bromoanisole
2398-37-0
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- 3-Bromoanisole
2398-37-0
- US $10.00 / KG
- 99.%
- Hebei Guanlang Biotechnology Co,.LTD
-
- 3-Bromoanisole
2398-37-0
- US $128.00 / KG
- 98%
- Baoji Guokang Bio-Technology Co., Ltd.