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Trimethyl(phenoxy)silane

CAS No.
1529-17-5
Chemical Name:
Trimethyl(phenoxy)silane
Synonyms
DK553;Phenol, TMS ether;Trimethylphenoxysilane;trimethylphenoxy-silan;PHENOXYTRIMETHYLSILANE;TRIMETHYLSILYLPHENOXIDE;trimethylphenoxy-Silane;O-(Trimethylsilyl)phenol;(Trimethylsiloxy)benzene;trimethyl-phenoxy-silane
CBNumber:
CB4402745
Molecular Formula:
C9H14OSi
Molecular Weight:
166.29
MDL Number:
MFCD00053666
MOL File:
1529-17-5.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Trimethyl(phenoxy)silane Properties

Melting point -55 °C
Boiling point 81 °C23 mm Hg(lit.)
Density 0.92 g/mL at 25 °C(lit.)
refractive index n20/D 1.478
Flash point 127 °F
storage temp. Sealed in dry,Room Temperature
form liquid
Specific Gravity 0.92
color Colorless to Light orange to Yellow
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
λmax 274nm(Heptane)(lit.)
BRN 1905943
InChIKey OJAJJFGMKAZGRZ-UHFFFAOYSA-N
FDA UNII 85E4MFC32D
EPA Substance Registry System Silane, trimethylphenoxy- (1529-17-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-36
RIDADR  UN 1993 3/PG 3
WGK Germany  3
10-21
TSCA  Yes
HazardClass  3.2
PackingGroup  III
HS Code  29319090
NFPA 704
2
2 1

Trimethyl(phenoxy)silane price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 380415 Trimethyl(phenoxy)silane 97% 1529-17-5 10ml $73.5 2023-06-20 Buy
TCI Chemical T3222 Trimethyl(phenoxy)silane >97.0%(GC) 1529-17-5 5mL $49 2024-03-01 Buy
TCI Chemical T3222 Trimethyl(phenoxy)silane >97.0%(GC) 1529-17-5 25mL $140 2024-03-01 Buy
Frontier Specialty Chemicals JK494677 Phenoxytrimethylsilane 97% 1529-17-5 25g $143 2021-12-16 Buy
AK Scientific 9306AL Trimethyl(phenoxy)silane 1529-17-5 25g $168 2021-12-16 Buy
Product number Packaging Price Buy
380415 10ml $73.5 Buy
T3222 5mL $49 Buy
T3222 25mL $140 Buy
JK494677 25g $143 Buy
9306AL 25g $168 Buy

Trimethyl(phenoxy)silane Chemical Properties,Uses,Production

Chemical Properties

Clear colorless liquid

Uses

Trimethyl(phenoxy)silane can be used as a catalyst for the Friedel-Crafts reaction, which is an organic reaction that converts alkenes into alcohols or epoxides. It can also reacts with hydrochloric acid to give phenol and chloroform. Trimethyl(phenoxy)silane has been shown to have chemical properties similar to those of phenol, such as viscosity, chemical species and resonance spectroscopy properties. It can react with oxygen in the air to form peroxides, so it should be stored in a cool, dry place away from light.

General Description

Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.

Synthesis

General procedure for trimethylsilylation of alcohols with HMDS catalyzed by P2O5/Al2O3. P2O5/Al2O3 (0.1 g) was added to a stirred solution of the alcohol (10 mmol) and HMDS (7.5 mmol) and the mixture was stirred at room temperature for the time specified in Table 2. The reaction was followed by TLC (n-hexane-EtOAc, 9:1). After completion of the reaction, ethyl acetate was added to the reaction mixture and the catalyst was isolated by filtration. It was washed well with ethyl acetate (2 9 5 ml) and then dried at 100°C for 2 h before being used again. The filtered solution was evaporated and purified by passage through a short column of silica gel with n-hexane as eluent (2 x 20 ml). Evaporation of the solvent under reduced pressure gave the pure product Trimethyl(phenoxy)silane, Yield; 89%.
syn.jpg

4648-54-8
108-95-2
1529-17-5
Synthesis of Trimethyl(phenoxy)silane from Azidotrimethylsilane and Phenol
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View Lastest Price from Trimethyl(phenoxy)silane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Phenoxytrimethylsilane pictures 2023-01-31 Phenoxytrimethylsilane
1529-17-5
US $50.00 / KG 25KG 99% 200ton Hebei Mojin Biotechnology Co., Ltd
Trimethylphenoxysilane pictures 2022-09-20 Trimethylphenoxysilane
1529-17-5
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
PHENOXYTRIMETHYLSILANE pictures 2019-07-06 PHENOXYTRIMETHYLSILANE
1529-17-5
US $2.00 / KG 1KG 99% customsie Career Henan Chemical Co
PHENYL TRIMETHYLSILYL ETHER PHENOXYTRIMETHYLSILANE TRIMETHYLSILYLPHENOXIDE (Trimethylsiloxy)benzene O-(Trimethylsilyl)phenol Phenol trimethylsilyl ether Phenol, TMS ether Silane, trimethylphenoxy- Phenoxy(trimethyl)silane, Phenyl trimethylsilyl ether trimethylphenoxy-silan Trimethylphenoxysilane trimethyl-phenoxy-silane trimethylphenoxy-Silane Trimethylsilyl phenyl ether PHENOXYTRIMETHYLSILANE, 97+% (Trimethylsilyl)oxybenzene Trimethyl(Phenoxy)Silane,>94% Benzene, [(trimethylsilyl)oxy]- DK553 1529-17-5 C6H5OSiCH33 Building Blocks Protected Alcohols/Phenols Oxygen Compounds Organic Building Blocks Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Protected Alcohols/Phenols